Peningkatan Kelarutan Glukomanan Porang (Amorphophallus muelleri Blume) dengan Penggilingan Basah dan Kering

https://doi.org/10.22146/agritech.43684

Anny Yanuriati(1*), Dasril Basir(2)

(1) Universitas Sriwijaya
(2) Jurusan Kimia, Fakultas MIPA Universitas Sriwijaya, Jl. Raya Palembang-Prabumulih Km. 32, Indralaya-Ogan Ilir, Sumatera Selatan 30662.
(*) Corresponding Author

Abstract


Despite of hydrophilic, glucomannan solubility is so slow that its solubility increase is required for easier, faster, and wider application. This research objective was to find a milling method which can enhance glucomannan solubility with high sol transparency, WHC and apparent viscosity. Native glucomannan extract from porang corm was classified into 3 treatments, no milling (native), grinding to pass through 80 mesh sieve (dry milling) or before grinding, the glucomannan were dissolved and precipitated using ethanol (wet milling) which then dried and passed through 80 mesh sieve. Compared to dry milling (13%), wet milling could significantly enhance higher glucomannan solubility (18%) with high sol transparency, WHC and apparent viscosity due to its depolymerization, molecular weight reduction, more porous and amorphous morphology as well.


Keywords


Dry; glucomannan; milling; size reduction; wet



References

Alonso-Sande, M., Teijeiro-Osorio, D., Remuñán-López, C., & Alonso, M. J. (2009). Glucomannan, a promising polysaccharide for biopharmaceutical purposes. European Journal of Pharmaceutics and Biopharmaceutics, 72(2), 453–462. https://doi.org/10.1016/j.ejpb.2008.02.005

An, N. T., Dong, N. T., Dung, P. L., & Thien, D. T. (2011)a. Synthesis dan characterization of water-soluble O-carboxymethyl glucomannan derivatives. Carbohydrate Polymers, 83(2), 645–652. https://doi.org/10.1016/j.carbpol.2010.08.034

An, N. T., Thien, D. T., Dong, N. T., Dung, P., Le & Du, N. Van. 2011b. Isolation dan characteristics of polysaccharide from Amorphophallus corrugatus in Vietnam. Carbohydrate Polymers, 84(1), 64–68. https://doi.org/10.1016/j.carbpol.2010.10.074

Behera, S.S., & Ray, R.C. (2016). Konjac glucomannan, a promising polysaccharide of Amorphophallus konjac K.Koch in health care. International Journal of Biological Macromolecules, 92, 942-956. http://dx.doi.org/10.1080/87559129.2015.1137310

Chao, W., Xiao-ling, Chen, Z.M., Li, D., & Lv, W. P. (2011). Structure dan Properties of Konjac Glucomannan Solved in Alcohol/Water. Advanced Materials Research, 198, 1310–1314. https://doi.org/10.4028/www.scientific.net/AMR.197-198.1310

Chao, W., Mei, X., Wen-ping, L., Pei, Q., Yuan-yuan, G., & Dong-sheng, L. (2012). Study on Rheological Behavior of Konjac Glucomannan. Physics Procedia, 33, 25–30. https://doi.org/10.4028/www.scientific.net/AMM.52-54.1344

Chua, M., Baldwin, T.C., Hocking, T.J., & Chan, K. (2010). Traditional uses dan potential health benefits of Amorphophallus konjac K. Koch ex N.E. Br. Journal of Ethnopharmacology, 128, 268-278. https://doi.org/10.1016/j.jep.2010.01.021

Du, X., Li, J., Chen, J., & Li, B. (2012). Effect of degree of deacetylation on physicochemical dan gelation properties of konjac glucomannan. Food Research International, 46(1), 270–278. https://doi.org/10.1016/j.jep.2010.01.021

Enomoto-rogers, Y., Ohmomo, Y., Takemura, A., & Iwata, T. (2014). Syntheses of glucomannan esters dan their thermal dan mechanical properties. Carbohydrate Polymers, 101, 592–599. http://dx.doi.org/10.1016/j.carbpol.2013.09.103

Gao, S., & Nishinari, K. (2004). Effect of degree of acetylation on gelation of konjac glucomannan. Biomacromolecules, 5, 175-185. https://doi.org/10.1016/j.colsurfb.2004.02.026

Gulseren, I., Yuan, F., & Corredig. (2012). Whey protein nanoparticle prepared with desolvation with ethanol: characterization thermal stability dan interfacial behavior. Food Hydrocolloid, 29, 258-264.

He, P., Luo, X., Lin, X., & Zhang, H. (2012). The rheological properties of konjac glucomannan (KGM) solution. Material Science Forum, 724, 57-60. https://doi.org/10.4028/www.scientific.net/MSF.724.57

Jiang, M., Li, H., Shi, J., & Xu, Z. (2018). Depolymerized konjac glucomannan: preparation dan application in health care. Journal of Zhejiang University-Science B (Biomedicine & Biotechnology), 19(7), 505-514. https://doi.org/10.1631/jzus.B1700310

Koroskenyi, B., & McCharty, S.P. (2001). Synthesis of acetylated konjac glucomannan dan effect of degree of acetylation on water absorbency. Biomacromolecules, 2, 824-826. https://doi.org/10.1021/bm010014c

Li, J., Ye, T., Wu, X., Chen, J., Wang, S., Lin, L., & Li, B. (2014). Preparation dan characterization of heterogeneous deacetylated konjac glucomannan. Food Hydrocolloids, 40, 9–15. http://dx.doi.org/10.1016/j.foodhyd.2014.02.001

Li, B., & Xie, B. (2003). Study on gel formation mechanism of konjac glucomannan. Agricultural Sciences in China, 2(4), 424-428. https://doi.org/10.1021/jf050751q

Li, B., Xie, J., Wang, Y., & Xie, B.J. (2005). Grain-size effect on the structure dan antiobesity activity of konjac flour. Journal of Agriculture dan Food Chemistry, 53, 7404-7407. https://doi.org/10.1021/jf050751q

Li, B., & Xie, B. (2006). Single molecular chain geometry of konjac glucomannan as a high dietary fiber in East Asia. Food Research International, 39, 127-132. https://doi .org/10.1016/j.foodres.2004.12.002

Li, L., Ruan, H., Ma, L., Wang, W., Zhou, P., & He, G. (2009). Study on swelling model dan thermodynamic structure of alami konjac glucomannan. Journal of Zhejiang University, Science. B, 10(4), 273–279. https://doi.org/10.1631/jzus.B0820221

Lee, M.E., Lee, H.D., & Suh, H.H. (2015). Production dan characterization of extracellular polysaccharide produced by Preudomonas sp. GP32. Journal of Life Science, 25, 1027-1035.

Lin-Lin, F., Shu-Hui, P., Cheng-Rong, W., Ming-Xiang, H., Xue-Qi, W., Chun-Hua, W., Min-Na, Y., Rui, F., & Jie, P. (2012). Analysis of influential factors of konjac glucomannan (GMK) molecular structure on its activity. Chinese Journal of Structural Chemistry, 31(4), 605-613. https://doi.org/10.1021/jf050751q

Liu, Jiang-yun, Wang, Hu-cheng, Yin, Y., Li, N., Cai, Pei-lie., & Yang, Shi-lin. (2012). Controlled acetylation of water soluble glucomannan from Bletilla striata. Carbohydrate Polymers, 89, 158-162.

Liu, P., Zhang, S., & Zhang, X. (1998). Research dan utilization of Amorphophallus in China. Acta Botanica Yunnanica, X, 48-61. https://doi.org/10.1016/j.carbpol.2012.02.065

Luo, X., He, P., & Lin, X. (2013). The mechanism of sodium hydroxide solution promoting the gelation of konjac glucomannan (KGM). Food Hydrocolloids, 30(1), 92–99.

Luo, X., Yao, X., Zhang, C., Lin, X., & Han, B. (2012). Preparation of mid-to-high molecular weight konjac glucomannan (MHKGM) using controllable enzyme-catalyzed degradation dan investigation of MHKGM properties. Journal of Polymer Research, 19(4), 9849-9858. https://doi.org/10.1016/j.carbpol.2012.02.065

Long, X., Luo, X., Bai, J., & Zhu, J. (2010). Studies on the molecular chain conformation dan morphology of konjac glucomannan in aqueous solution. Material Science Forum, 658, 388-391. https://doi.org/10.4028/www.scientific.net/MSF.658.388

Ohashi, S., Shelso, G.J., Moirano, D., Arthur, L., & Drinkwater, W.L. (2000). Clarified konjac glucomannan. United States Patent, 6,162,906 (Des 10).

Ojima, R., Makabe, T., Prawitwong, P., Takahashi, R., Takigami, M., & Takigami, S. (2009). Rheological Property of Hydrolyzed Konjac Glucomannan. Transaction of the Materials Research Society of Japan, 34(3), 477-480.

Pan, Z., Meng, J., & Wang, Y. (2011). Effect of alkalis on deacetylation of konjac glucomannan in mechano-chemical treatment. Particulogy, 9, 265-269. doi:10.1016/j.partic.2010.11.003

Pan, T., Peng, S., Xu, Z., Xiong, B., Wen, C., Yao, M., & Pang, J. (2013). Synergetic degradation of konjac glucomannan by γ-ray irradiation dan hydrogen peroxide. Carbohydrate Polymers, 93, 761-767. doi:10.1016/j.carbpol.2012.11.075

Prawitwong, P., Takigami, S., & Phillips, G. O. (2007). Phase transition behaviour of sorbed water in konjac mannan. Food Hydrocolloids, 21(8), 1368–1373. doi:10.1016/j.foodhyd.2006.10.017

Tatirat, O., Charunuch, C., Kerr, W.L., & Charoenrein. (2013). Use of ethanol solution for extruding konjac glucomannan to modify its water absorption dan water solubility. Kasetsart Journal (Natural Science), 47, 132-142.

Tester, R.F., & Al-Ghazzewi, F.H. (2013). Mannans dan health, with a special focus on glucomannans. Food Research International, 50, 384-391. http://dx.doi.org/10.1016/j.foodres.2012.10.037

Wang, C., Zhu, Y., Xu, M., LI, D., & Huang, H. (2011). Study on molecule dimension of different granularity Konjac glucomannan. Applied Mechanics dan Materials, 52-54, 1344-1347. doi:10.4028/www.scientific.net/AMM.52-54.1344

Xiaoyan, L., Qiang, W., Xuegang, L., Feng, L., Xiaoqing, L., & Pan, H. (2010). Effect of degree of acetylation on thermoplastic dan melt rheological properties of acetylated konjac glucomannan. Carbohydrate Polymers, 82, 167-172. doi:10.1016/j.carbpol.2010.04.053

Xing, X., Cui, S.W., Nie, S., Phillips, G.O., Goff, H.D., & Wang, Q. (2015). Study on Dendrobium officinale O-acetyl-glucomannan (Dendronan): Part II. Fine structures of O-acetylated residues. Carbohydrate Polymers, 117, 422-433. http://dx.doi.org/10.1016/j.bcdf.2014.12.005

Xu, W., Wang, Y., Jin, W., Wang, S., Zhou, B., Li, J., Li, B., & Wang, L. 2014. A 0ne-step procedure for elevating the quality of konjac flour: Azeotropy-assisted acidic alcohol. Food Hydrocolloids, 35, 653-660. https://doi.org/10.1016/j.foodhyd.2013.08.014

Ye, T., Wang, L., Xu, W., Liu, J., Wang, Y., Zhu, K., &Wang, C. (2014). An approach for prominent enhancement of the quality of konjac flour: Dimethyl sulfoxide as medium. Carbohydrate Polymers, 99, 173–179. http://dx.doi.org/10.1016/j.carbpol.2013.08.038

Yanuriati, A., Djagal, W.M, Rochmadi, & Harmayani, E. (2017a). Characteristics of glucomannan isolated from fresh tuber of porang (Amorphophallus muelleri Blume). Carbohydrate Polymers, 156, 56-63. http://dx.doi.org/10.1016/j.carbpol.2016.08.080

Yanuriati, A., Djagal, W.M, Rochmad, & Harmayani, E. (2017b). Gel glukomanan porang-xantan dan kestabilannya setelah penyimpanan dingin dan beku. agriTECH, 37(2), 121-131. DOI: http://doi.org/10.22146/agritech.10793

Zhang, C., Chen, J. Da., & Yang, F. Q. (2014). Konjac glucomannan, a promising polysaccharide for OCDDS. Carbohydrate Polymers 104(1), 175–181. http://dx.doi.org/10.1016/j.carbpol.2013.12.081

Zhang, Y. Q., Xie, B. J., & Gan, X. (2005). Advance in the applications of konjac glucomannan dan its derivatives. Carbohydrate Polymers, 60(1), 27–31. doi:10.1016/j.carbpol.2004.11.003

Zhao, J., Zang, D., Srzednicki, G., Kanlayanarat, S., & Borompichaichartkul, C. (2010). Development of a low-cost two-stage technique for production of low-sulphur purified konjac flour. International Food Research Journal, 17, 1113-1124.



DOI: https://doi.org/10.22146/agritech.43684

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