Adsorption of Fe(II) by Layered Double Hydroxide Composite with Carbon-Based Material (Biochar and Graphite): Reusability and Thermodynamic Properties

Neza Rahayu Palapa(1), Alfan Wijaya(2), Patimah Mega Syah Bahar Nur Siregar(3), Amri Amri(4), Nur Ahmad(5), Tarmizi Taher(6), Aldes Lesbani(7*)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang-Prabumulih, Km. 90-32, Ogan Ilir 30862, South Sumatra, Indonesia
(2) Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa Bukit Besar, Palembang 30139, South Sumatera, Indonesia
(3) Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa Bukit Besar, Palembang 30139, South Sumatera, Indonesia
(4) Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa Bukit Besar, Palembang 30139, South Sumatera, Indonesia
(5) Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa Bukit Besar, Palembang 30139, South Sumatera, Indonesia
(6) Department of Environmental Engineering, Institut Teknologi Sumatera, Jl. Terusan Ryacudu, Way Hui, Lampung Selatan 35365, Indonesia
(7) Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang-Prabumulih, Km. 90-32, Ogan Ilir 30862, South Sumatra, Indonesia
(*) Corresponding Author


Layered double hydroxide (LDH) of Ni/Al was synthesized by coprecipitation method at pH 10 followed by the formation of composite with carbon-based material i.e., biochar (B) and graphite (G) to form Ni/Al-B and Ni/Al-G. Materials were characterized by XRD powder, FTIR, BET surface area, thermal analyses, and SEM analysis. The regeneration process and adsorption evaluated the performance of materials toward iron(II) [Fe(II)] from an aqueous solution. The results showed that the surface area of Ni/Al-B (428.94 m2/g) was increased mainly up to twenty-nine-fold than Ni/Al LDH (15.11 m2/g), while Ni/Al-G (21.59 m2/g) had slightly increased than pristine LDH. Composite of Ni/Al-B had reusability properties for Fe(II) adsorption up to five cycles and showed higher structural stability. The adsorption capacity of Ni/Al-B was 104.167 mg/g and can be a potential adsorbent to remove Fe(II) from an aqueous solution.


layered double hydroxide; graphite; biochar; Ni/Al; structural stability

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[1] Zubair, M., Daud, M., McKay, G., Shehzad, F., and Al-Harthi, M.A., 2017, Recent progress in layered double hydroxides (LDH)-containing hybrids as adsorbents for water remediation, Appl. Clay Sci., 143, 279–292.

[2] Esan, O.S., Kolawole, A.O., and Olumuyiwa, A.C., 2019, The removal of single and binary basic dyes from synthetic wastewater using bentonite clay adsorbent, Am. J. Polym. Sci. Technol., 5 (1), 16–28.

[3] Ouassif, H., Moujahid, E.M., Lahkale, R., Sadik, R., Bouragba, F.Z., Sabbar, E., and Diouri, M., 2020, Zinc-aluminum layered double hydroxide: High efficient removal by adsorption of tartrazine dye from aqueous solution. Surf. Interfaces, 18, 100401.

[4] Jitianu, M., Gunness, D.C., Aboagye, D.E., Zaharescu, M., and Jitianu, A., 2013, Nanosized Ni–Al layered double hydroxides—Structural characterization, Mater. Res. Bull., 48 (5), 1864–1873.

[5] Cheng, S.Y., Show, P.L., Lau, B.F., Chang, J.S., and Ling, T.C., 2019, New prospects for modified algae in heavy metal adsorption, Trends Biotechnol., 37 (11), 1255–1268.

[6] Yagub, M.T., Sen, T.K., Afroze, S., and Ang, H.M., 2014, Dye and its removal from aqueous solution by adsorption: A review, Adv. Colloid Interface Sci., 209, 172–184.

[7] Boulaiche, W., Hamdi, B., and Trari, M., 2019, Removal of heavy metals by chitin: Equilibrium, kinetic and thermodynamic studies, Appl. Water Sci., 9 (2), 39.

[8] Okon, A.N., Udoh, F.D., and Bassey, P.G., 2014, Evaluation of Rice Husk as Fluid Loss Control Additive in Water-Based Drilling Mud, SPE Nigeria Annual International Conference and Exhibition, August 5–7, 2014, Lagos, Nigeria.

[9] Patil, N.P., Bholay, A.D., Kapadnis, B.P., and Gaikwad, V.B., 2016, Biodegradation of model azo dye methyl red and other textile dyes by isolate Bacillus circulans NPP1, J. Pure Appl. Microbiol., 10 (4), 2793–2800.

[10] Vimonses, V., Lei, S., Jin, B., Chow, C.W.K., and Saint, C., 2009, Kinetic study and equilibrium isotherm analysis of Congo Red adsorption by clay materials, Chem. Eng. J., 148 (2–3), 354–364.

[11] Ravi, R., and Pandey, L.M., 2019, Enhanced adsorption capacity of designed bentonite and alginate beads for the effective removal of methylene blue, Appl. Clay Sci., 169, 102–111.

[12] Taher, T., Rohendi, D., Mohadi, R., and Lesbani, A., 2019, Congo red dye removal from aqueous solution by acid-activated bentonite from sarolangun: kinetic, equilibrium, and thermodynamic studies, Arab J. Basic Appl. Sci., 26 (1), 125–136.

[13] Palapa, N.R., Taher, T., Rahayu, B.R., Mohadi, R., Rachmat, A., and Lesbani, A., 2020, CuAl LDH/rice husk biochar composite for enhanced adsorptive removal of cationic dye from aqueous solution, Bull. Chem. React. Eng. Catal., 15 (2), 525–537.

[14] Chakraborty, C., Dana, K., and Malik, S., 2011, Intercalation of perylenediimide dye into LDH clays: Enhancement of photostability, J. Phys. Chem. C, 115 (5), 1996–2004.

[15] Bessaies, H., Iftekhar, S., Doshi, B., Kheriji, J., Ncibi, M.C., Srivastava, V., Sillanpää, M., and Hamrouni, B., 2020, Synthesis of novel adsorbent by intercalation of biopolymer in LDH for the Removal of arsenic from synthetic and natural water, J. Environ. Sci., 91, 246–261.

[16] Rahmadan, J., Parhusip, V., Palapa, N.R., Taher, T., Mohadi, R., and Lesbani, A., 2021, ZnAl-humic acid composite as adsorbent of cadmium(II) from aqueous solution, Sci. Technol. Indones., 6 (4), 247–255.

[17] Starukh, H., and Levytska, S., 2019, The simultaneous anionic and cationic dyes removal with Zn–Al layered double hydroxides, Appl. Clay Sci., 180, 105183.

[18] Palapa, N.R., Juleanti, N., Normah, N., Taher, T., and Lesbani, A., 2020, Unique adsorption properties of malachite green on interlayer space of Cu-Al and Cu-Al-SiW12O40 layered double hydroxides, Bull. Chem. React. Eng. Catal., 15 (3), 653–661.

[19] Siregar, P.M.S.B.N., Wijaya, A., Amri, A., Nduru, J.P., Hidayati, N., Lesbani, A., and Mohadi, R., 2022, Layered double hydroxide/C (C=humic acid;hydrochar) as adsorbents of Cr(VI), Sci. Technol. Indones., 7 (1), 41–48.

[20] Choong, C.E., Wong, K.T., Jang, S.B., Saravanan, P., Park, C., Kim, S.H., Jeon, B.H., Choi, J., Yoon, Y., and Jang, M., 2021, Granular Mg-Fe layered double hydroxide prepared using dual polymers: Insights into synergistic removal of As(III) and As(V), J. Hazard. Mater., 403, 123883.

[21] Lv, X., Qin, X., Wang, K., Peng, Y., Wang, P., and Jiang, G., 2019, Nanoscale zero valent iron supported on MgAl-LDH-decorated reduced graphene oxide: Enhanced performance in Cr(VI) removal, mechanism and regeneration, J. Hazard. Mater., 373 (6), 176–186.

[22] Lesbani, A., Normah, N., Palapa, N.R., Taher, T., Andreas, R., and Mohadi, R., 2020, Removal of iron(II) using Ni/Al layered double hydroxide intercalated with Keggin ion, Molekul, 15 (3), 149–157.

[23] Palapa, N.R., Juleanti, N., Mohadi, R., Taher, T., and Rachmat, A., 2020, Copper aluminum layered double hydroxide modified by biochar and its application as an adsorbent for procion red, J. Water Environ. Technol., 18 (6), 359–371.

[24] Zhu, X., Liu, Y., Qian, F., Zhou, C., Zhang, S., and Chen, J., 2014, Preparation of magnetic porous carbon from waste hydrochar by simultaneous activation and magnetization for tetracycline removal, Bioresour. Technol., 154, 209–214.

[25] Li, R., Wang, J.J., Zhou, B., Awasthi, M.K., Ali, A., Zhang, Z., Gaston, L.A., Lahori, A.H., and Mahar, A., 2016, Enhancing phosphate adsorption by Mg/Al layered double hydroxide functionalized biochar with different Mg/Al ratios, Sci. Total Environ., 559, 121–129.

[26] Modwi, A., Abbo, M.A., Hassan, E.A., Al-Duaij, O.K., and Houas, A., 2017, Adsorption kinetics and photocatalytic degradation of malachite green (MG) via Cu/ZnO nanocomposites, J. Environ. Chem. Eng., 5 (6), 5954–5960.

[27] Luo, X., Wang, C., Wang, L., Deng, F., Luo, S., Tu, X., and Au, C., 2013, Nanocomposites of graphene oxide-hydrated zirconium oxide for simultaneous removal of As(III) and As(V) from water, Chem. Eng. J., 220, 98–106.

[28] Ribas, M.C., de Franco, M.A.E., Adebayo, M.A., Lima, E.C., Parkes, G.M.B., and Feris, L.A., 2020, Adsorption of Procion Red MX-5B dye from aqueous solution using homemade peach and commercial activated carbons, Appl. Water Sci., 10 (6), 154.

[29] Hu, F., Wang, M., Peng, X., Qiu, F., Zhang, T., Dai, H., Liu, Z., and Cao, Z., 2018, High-efficient adsorption of phosphates from water by hierarchical CuAl/biomass carbon fiber layered double hydroxide, Colloids Surf., A, 555, 314–323.

[30] Sharifpour, E., Alipanahpour Dil, E., Asfaram, A., Ghaedi, M., and Goudarzi, A., 2019, Optimizing adsorptive removal of malachite green and methyl orange dyes from simulated wastewater by Mn-doped CuO-nanoparticles loaded on activated carbon using CCD-RSM: Mechanism, regeneration, isotherm, kinetic, and thermodynamic studies, Appl. Organomet. Chem., 33 (3), e4768.

[31] Mostafa, M.S., Bakr, A.A., Eshaq, G., and Kamel, M.M., 2015, Novel Co/Mo layered double hydroxide: Synthesis and uptake of Fe(II) from aqueous solutions (Part 1), Desalin. Water Treat., 56 (1), 239–247.

[32] Taher, T., Christina, M.M., Said, M., Hidayati, N., Ferlinahayati, F., and Lesbani, A., 2019, Removal of iron(II) using intercalated Ca/Al layered double hydroxides with [α-SiW12O40]4-, Bull. Chem. React. Eng. Catal., 14 (2), 260–267.

[33] Shrestha, S.L., 2018, Study of the adsorption kinetics of iron ion from wastewater using banana peel, Int. J. Adv. Res. Chem. Sci., 5 (3), 1–8.

[34] Ain, Q.U., Zhang, H., Yaseen, M., Rasheed, U., Liu, K., Subhan, S., and Tong, Z., 2020, Facile fabrication of hydroxyapatite-magnetite-bentonite composite for efficient adsorption of Pb(II), Cd(II), and crystal violet from aqueous solution, J. Cleaner Prod., 247, 119088.

[35] Wan Ngah, W.S., Ab Ghani, S., and Kamari, A., 2005, Adsorption behaviour of Fe(II) and Fe(III) ions in aqueous solution on chitosan and cross-linked chitosan beads, Bioresour. Technol., 96 (4), 443–450.

[36] El-Sherif, I.Y., Fathy, N.A., and Hanna, A.A., 2013, Removal of Mn(II) and Fe(II) ions from aqueous solution using precipitation and adsorption methods, J. Appl. Sci. Res., 9 (1), 233–239.

[37] Zhang, Y., Zhao, J., Jiang, Z., Shan, D., and Lu, Y., 2014, Biosorption of Fe(II) and Mn(II) ions from aqueous solution by rice husk ash, Biomed Res. Int., 2014, 973095.

[38] Moghadam, M.R., Nasirizadeh, N., Dashti, Z., and Babanezhad, E., 2013, Removal of Fe(II) from aqueous solution using pomegranate peel carbon: Equilibrium and kinetic studies, Int. J. Ind. Chem., 4 (1), 19.

[39] Bakr, A.A., Mostafa, M.S., Eshaq, G., and Kamel, M.M., 2015, Kinetics of uptake of Fe(II) from aqueous solutions by Co/Mo layered double hydroxide (Part 2), Desalin. Water Treat., 56 (1), 248–255.


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