Electrochemical Removal of Copper Ions Using Coconut Shell Activated Carbon

https://doi.org/10.22146/ijc.43077

Nur Azza Azyan Muin(1), Hawaiah Imam Maarof(2*), Nur Alwani Ali Bashah(3), Nor Aida Zubir(4), Rasyidah Alrozi(5), Norhaslinda Nasuha(6)

(1) Faculty of Chemical Engineering, Universiti Teknologi MARA, Cawangan, 13500 Pulau Pinang, Malaysia
(2) Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
(3) Faculty of Chemical Engineering, Universiti Teknologi MARA, Cawangan, 13500 Pulau Pinang, Malaysia
(4) Faculty of Chemical Engineering, Universiti Teknologi MARA, Cawangan, 13500 Pulau Pinang, Malaysia
(5) Faculty of Chemical Engineering, Universiti Teknologi MARA, Cawangan, 13500 Pulau Pinang, Malaysia
(6) Faculty of Chemical Engineering, Universiti Teknologi MARA, Cawangan, 13500 Pulau Pinang, Malaysia
(*) Corresponding Author

Abstract


In this work, coconut shell activated carbon (CSAC) electrode was evaluated to remove copper ion via electrochemical processes. CSAC electrode and graphite were applied as the cathode and the anode, respectively. The reusability of the electrode, the effects of initial pH, applied voltage and initial concentration were studied. The electrochemical process was carried out for 3 h of treatment time, and the electrodes (anode and cathode) were separated by 1 cm. The results revealed that CSAC is proven as a reusable electrode to remove copper ion, up to 99% of removal efficiency from an initial concentration of 50 ppm after it had been used three times. From the observation, the removal efficiency was optimum at an initial pH of 4.33 (without any initial pH adjustment). The applied voltage at 8 V showed a higher removal efficiency of copper ion compared to at 5 V.


Keywords


activated carbon; copper; electrosorption; coconut shell; wastewater

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References

[1] Maarof, H.I., Ajeel, M.A., Daud, W.M.A.W., and Aroua, M.K., 2017, Electrochemical properties and electrode reversibility studies of palm shell activated carbon for heavy metal removal, Electrochim. Acta, 249, 96–103.

[2] Friedrich, J.M., Ponce-de-León, C., Reade, G.W., and Walsh, F.C., 2004, Reticulated vitreous carbon as an electrode material, J. Electroanal. Chem., 561, 203–217.

[3] Huang, C.C., and Su, Y.J., 2010, Removal of copper ions from wastewater by adsorption/electrosorption on modified activated carbon cloths, J. Hazard. Mater., 175 (1-3), 477–483.

[4] Peng, W., Li, H., Liu, Y., and Song, S., 2017, A review on heavy metal ions adsorption from water by graphene oxide and its composites, J. Mol. Liq., 230, 496–504.

[5] Fu, F., and Wang, Q., 2011, Removal of heavy metal ions from wastewaters: A review, J. Environ. Manage., 92 (3), 407–418.

[6] Barakat, M.A., 2011, New trends in removing heavy metals from industrial wastewater, Arab. J. Chem., 4 (4), 361-377.

[7] Tran, T.K., Chiu, K.F., Lin, C.Y., and Leu, H.J., 2017, Electrochemical treatment of wastewater: Selectivity of the heavy metals removal process, Int. J. Hydrogen Energy, 42 (45), 27741–27748.

[8] Zhang, L.L., and Zhao, X.S., 2009, Carbon-based materials as supercapacitor electrodes, Chem. Soc. Rev., 38 (9), 2520–2531.

[9] Iqbaldin, M.N.M., Khudzir, I., Azlan, M.I.M., Zaidi, A.G., Surani, B., and Zubri, Z., 2013, Properties of coconut shell activated carbon, J. Trop. For. Sci., 25 (4), 497–503.

[10] Hussin, F., Abnisa, F., Issabayeva, G., and Aroua, M.K., 2017, Removal of lead by solar-photovoltaic electrocoagulation using novel perforated zinc electrode, J. Cleaner Prod., 147, 206–216.

[11] Tramontina, J., Azambuja, D.S., and Piatnicki, C.M.S., 2002, Removal of Cd2+ ion from diluted aqueous solutions by electrodeposition on reticulated vitreous carbon electrodes, J. Braz. Chem. Soc., 13 (4), 469–473.

[12] Alebrahim, M.F., Khattab, I.A., and Sharif, A.O., 2015, Electrodeposition of copper from a copper sulfate solution using a packed-bed continuous-recirculation flow reactor at high applied electric current, Egypt. J. Pet., 24 (3), 325–331.

[13] Chen, X., Lin, H., Ren, H., and Xing, J., 2013, Experimental study on wastewater treatment containing copper with electrodeposition method, Adv. Mater. Res., 779-780, 1670–1673.

[14] Marmanis, D.I., Dermentzis, K.I., Christoforidis, A.K., and Ouzounis, K.G., 2013, Cadmium removal from aqueous solution by capacitive deionization with nano-porous carbon electrodes, J. Eng. Sci. Technol. Rev., 6 (5), 165–166.

[15] Elsherief, A.E., 2003, Removal of cadmium from simulated wastewaters by electrodeposition on spiral wound steel electrode, Electrochim. Acta, 48 (18), 2667–2673.

[16] Duan, W., Chen, G., Chen, C., Sanghvi, R., Iddya, A., Walker, S., Liu, H., Ronen, A., and Jassby, D., 2017, Electrochemical removal of hexavalent chromium using electrically conducting carbon nanotube/polymer composite ultrafiltration membranes, J. Membr. Sci., 531, 160–171.

[17] Khattab, I.A., Shaffei, M.F., Shaaban, N.A., Hussein, H.S., and Abd El-Rehim, S.S., 2013, Electrochemical removal of copper ions from dilute solutions using packed bed electrode. Part І, Egypt. J. Pet., 22 (1), 199–203.



DOI: https://doi.org/10.22146/ijc.43077

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