Synthesis, Characterization and Catalytic Activity of NiO-CoO-MgO Nano-Composite Catalyst

https://doi.org/10.22146/ijc.38119

Salih Hadi Kadhim(1*), Tariq Hussein Mgheer(2), Hussein Idrees Ismael(3), Khudheyer Jawad Kadem(4), Ahmed Saadon Abbas(5), Abbas Jasim Atiyah(6), Iman Jassim Mohamad(7)

(1) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(2) College of Medicine, University of Babylon, Iraq
(3) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(4) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(5) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(6) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(7) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(*) Corresponding Author

Abstract


The ternary NiO-CoO-MgO catalyst in three ratios 20:20:60, 25:25:50, and 30:30:40 for these component oxides respectively, were synthesized by co-precipitation method of their carbonates by addition of a precipitate agent in basic media, and then calcinated these carbonate to obtain of mixed oxides. The prepared catalysts were characterized by using Powder X-Ray Diffraction (PXRD), Fourier Infrared spectroscopy (FT-IR), and Atomic Force Microscopy techniques (AFM) were used for identification of the prepared catalysts. The result showed that the particle size of these catalyst ratios, were in the nano range and the smallest size was 25:25:50. The investigation of catalytic activity of prepared catalysts was done by photo decolorization of Celestine blue B dye from simulated industrial wastewaters in aqueous solution. The decolorization efficiency of dye reached 99.9% after irradiation time for 1 h. Study the effect of different reaction conditions such as the pH of the medium, the weight of semiconductor and temperature of mixture reaction were shown that the maximum degradation was observed in conditions at pH = 4, catalyst dosage = 0.08 g, and temperature = 303 K.

Keywords


decolorization of Celestine blue B dye; NiO-CoO- supported oxides; cobalt oxides

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References

[1] Hutchings, G.J., 2009, Heterogeneous catalyst-discovery and design, J. Mater. Chem., 19 (9), 1222–1235.

[2] Xie, Z., Liu, Z., Wang, Y., Yang, Q., Xu, L., and Ding, W., 2010, An overview of recent development in composite catalyst from porous materials for various reactions and processes, Int. J. Mol. Sci., 11 (5), 2152–2187.

[3] Sevcik, P., Cik, G., Vlna, T. and Mackul’ak, T, 2009, Preparation and properties of a new composite photocatalyst based on nanosized titanium dioxide, Chem. Pap., 63 (2), 249–254.

[4] Fatma, F., Hariani, P.L., Riyanti, F., and Sepriani, W., 2017, Desorption and re-adsorption of procion red MX-5B dye on alumina-activated carbon composite, Indones. J. Chem., 18 (2), 222–228.

[5] Ahmed, L.M., Saaed, S.I., and Marhoon, A.A., 2018, Effect of oxidation agents on photo-decolorization of vitamin B12 in the presence of ZnO/UV-A system, Indones. J. Chem., 18 (2), 272–278.

[6] Petitto, S.C., Marsh, E.M., Carson, G.A., and Langell, M.A., 2008, Cobalt oxide surface chemistry: The interaction of CoO(1 0 0), Co2O3(1 1 0) and Co3O4(1 1 1) with oxygen and water, J. Mol. Catal. A: Chem., 281 (1-2), 49–58.

[7] Mathew, J., and Shetty, N., 2017, Treatment of wastewater using synthesized photocatalyst cobalt oxide CO3O4, Int. J. Civil Eng. Technol., 8 (4), 1840–1844.

[8] Helmes, C.T., Sigman, C.C., Fung, V.A., Thompson, K., Doeltz, M.K., Mackie, M., Klein, T.E., and Lent, D., 1984, A study of azo and nitro dyes for the selection of candidates for carcinogen bioassay, J. Environ. Sci. Health, Part A, 19 (2), 97–231.

[9] Julkapli, N.M., and Bagheri, S., 2015, Magnesium oxide as a heterogeneous catalyst support, Rev. Inorg. Chem., 36 (1), 1–41.

[10] Roxon, J.J., Ryan, A.J., and Wright, S.E., 1967, Reduction of water-soluble azo dyes by intestinal bacteria, Food Cosmet. Toxicol., 5 (3), 367–369.

[11] Corro, G., Fierro, J.L.G., and Odilón Vázquez, C., 2005, Strong improvement on CH4 oxidation over Pt/γ-Al2O3 catalysts, Catal. Commun., 6 (4), 287–292.

[12] Nazarkovsky, M.A., Gun’ko, V.M., Wójcik, G., Czech, B., Sobieszek, A., Skubiszewska-Zięba J., Janusz, W., and Skwarek, E., 2014, Band-gap change and photocatalytic activity of silica/titania composite associated with incorporation of CuO and NiO, Chem. Phys. Technol. Surf., 5 (4), 421–437.

[13] Vázquez-Cuchillo, O., Cruz-López, A., Bautista-Carrillo, L.M, Bautista-Hernández, A., Martínez, L.M.T., and Lee, S.W., 2010, Synthesis of TiO2 using different hydrolysis catalysts and doped with Zn for efficient degradation of aqueous phase pollutants under UV light, Res. Chem. Intermed., 36 (1), 103–113.

[14] Song, Y.L., Li, J.T., and Bai, B., 2010, TiO2-assisted photodegradation of direct blue 78 in aqueous solution in sunlight, Water Air Soil. Pollut., 213 (1-4), 311–317.

[15] Halbus, A.F., Lafta, A.J., Athab, Z.H. and Hussein, F.H., 2014, Adsorption of reactive yellow dye 145 from wastewater onto Iraqi Zahdy and Khestawy date palm seeds activated carbons, Asian J. Chem., 26, S167–S172.

[16] Wanke, S.E., and Flynn, P.C., 1975, The sintering of supported metal catalysts, Catal. Rev. Sci. Eng., 12 (1), 93–135.

[17] Attia, A.J, Kahdim, S.H., and Hussein, F.H., 2008, Photocatalytic degradation of textile dyeing wastewater using titanium dioxide and zinc oxide, E-J. Chem., 5 (2), 219–223.

[18] Mora, M., López, M.I., Jiménez-Sanchidrián, C., and Ruiz, J.R., 2010, Ca/Al mixed oxides as catalysts for the Meerwein–Ponndorf–Verley reaction, Catal. Lett., 136 (3-4), 192–198.

[19] Mohammad, E.J., Kathim, S.H., and Attia, A.J., 2015, Removal of reactive yellow 145 dye from simulated industrial waste waters over prepared supported (Co, Ni) 3O4/Al2O3 spinel catalyst, Res. J. Pharm. Biol. Chem. Sci., 6 (4), 717–726.

[20] Yuliati, L., Roslan, N.A., Siah, W.R., and Lintang, H.O., 2017, Cobalt oxide-modified titanium dioxide nanoparticle photocatalyst for degradation of 2,4-dichlorophenoxyacetic acid, Indones. J. Chem., 17 (2), 284–290.

[21] Ge, X., Liu, Y., Goh, F.W.T., Hor, T.S.A., Zong, Y., Xiao, P., Zhang, Z., Lim, S.H., Li, B., Wang, X., and Liu, Z., 2014, Dual-phase spinel MnCo2O4 and spinel MnCo2O4/nanocarbon hybrids for electrocatalytic oxygen reduction and evolution, ACS Appl. Mater. Interfaces, 6 (15), 12684–12691.

[22] Sharifi, S.L., Shakur, H.R., Mirzaei, A., Salmani, A., and Hosseini, M.H., 2013, Characterization of cobalt oxide Co3O4 nanoparticles prepared by various methods: effect of calcination temperatures on size, dimension and catalytic decomposition of hydrogen peroxide, Int. J. Nanosci. Nanotechnol., 9 (1), 51–58.

[23] Selvam, N.C.S., Kumar, R.T., Kennedy, L.J., and Vijaya, J.J., 2011, Comparative study of microwave and conventional methods for the preparation and optical properties of novel MgO-micro and nano-structures, J. Alloys Compd., 509 (41), 9809–9815.

[24] Purnawan, C., Wahyuningsih, S., and Kusuma, P.P., 2016, Photocatalytic and photoelectrocatalytic degradation of methyl orange using graphite/PbTiO3 composite, Indones. J. Chem., 16 (3), 347–352.

[25] Galván-Ruiz, M., Hernández, J., Baños, L., Noriega-Montes, J., and Rodríguez-García, M.E., 2009, Characterization of calcium carbonate, calcium oxide, and calcium hydroxide as starting point to the improvement of lime for their use in construction, J. Mater. Civ. Eng., 21 (11), 694–698.

[26] Singh, J., Hudson, M.S.L., Pandey, S.K., Tiwari, R.S., and Srivastava, O.N., 2012, Structural and hydrogenation studies of ZnO and Mg doped ZnO nanowires, Int. J. Hydrogen Energy, 37 (4), 3748–3754.

[27] Ni, Y., Ge, X., Zhang, Z., Liu, H., Zhu, Z., and Ye, Q., 2001, A simple reduction-oxidation route to prepare Co3O4 nanocrystals, Mater. Res. Bull., 36 (13-14), 2383–2387.

[28] Wilson, S.J., 1979, The dehydration of boehmite, γ-AlOOH, to γ-Al2O3, J. Solid State Chem., 30 (2), 247–255.

[29] Gassim, F.A.Z.G., Alkhateeb, A.N., and, Hussein, F.H., 2007, Photocatalytic oxidation of benzyl alcohol using pure and sensitized anatase, Desalination, 209 (1-3), 342–349.

[30] Ahmed, L.M., and Hussein, F.H., 2014, Roles of Photocatalytic Reactions of Platinized TiO2 Nanoparticles, LAP Lambert Academia Published, Germany.

[31] Zuafuani, S.I., and Ahmed, L.M., 2015, Photocatalytic decolourization of direct orange dye by zinc oxide under UV irradiation, Int. J. Chem. Sci., 13 (1), 187–196.



DOI: https://doi.org/10.22146/ijc.38119

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