Removal of Hazardous Brilliant Cresyl Blue Dye Utilizing Aluminum Oxide as Photocatalyst

https://doi.org/10.22146/ijc.30135

Hazim Yahya Al-Gubury(1*), Hajir S. Alteemi(2), Ali Malik Saad(3), Rafal R. Al-Shamary(4)

(1) Department of chemistry, College of Science for Women, University of Babylon, Iraq
(2) Department of chemistry, College of Science for Women, University of Babylon, Iraq
(3) Department of Biology, College of Science for Women, University of Babylon, Iraq
(4) Department of chemistry, College of Science for Women, University of Babylon, Iraq
(*) Corresponding Author

Abstract


Photocatalytic degradation of brilliant cresyl blue stain has been done by irradiating the solution pigment with a solar light in presence of aluminum oxide. The effect of important reaction has included many parameters such as catalyst mass, the initial concentration of brilliant cresyl blue dye, the effect of temperature, and initial P has been investigated in a batch reactor. All experiments are determined by usage of UV-visible spectrophotometer analyzer. The optimal concentration of catalytic has observed at 0.17 g/100 cm3 while the typical concentration of stain was recorded at 50 mg/cm3. Photocatalytic break down of shining cresyl blue pigment was favorable in the Ph 10 and 8.44 mW/cm2 light intensity. This type of degradation of the present dye study has obeyed the pseudo-first-order reaction. Photocatalytic degradation of brilliant cresyl blue dye has studied by using various concentrations of aluminum oxide. This concentration was suspended in an aqueous solution of dye which has irradiated by solar radiation in a vessel reactor at room temperature with 10 cm3/min air bubble was passed through the solution.

Keywords


photocatalytic; degradation; brilliant cresyl blue; aluminum oxide

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References

[1] Misriyani, Kunarti, E.S., and Yasuda, M., 2015, Synthesis of Mn(II)-Loaded TiXSi1-XO4 Composite acting as a visible light driven photocatalyst, Indones. J. Chem., 15 (1), 43–49.

[2] Gaya, U.I., and Abdullah, A.H., 2008, Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems, J. Photochem. Photobiol., C, 9 (1), 1–12.

[3] Liao, W., Zeng, T., Wang, P., Tu, S., and Pan, W., 2010, Efficient microwave-assisted photocatalytic degradation of endocrine disruptor dimethyl phthalate over composite catalyst ZrOx/ZnO, J. Environ. Sci., 22 (11), 1800–1806.

[4] Pereira, J.H.O.S., Vilar, V.J.P., Borges, M.T., González, O., Esplugas, S., and Boaventura, R.A.R., 2011, Photocatalytic degradation of oxytetracycline using TiO2 under natural and simulated solar radiation, Sol. Energy, 85 (11), 2732–2740.

[5] Yuliati, L., Roslan, N.A., Siah, W.R., and Lintang, H.O., 2017, Cobalt oxide-modified titanium dioxide nanoparticle photocatalyst for degradation of 2,4-dichlorophenoxyacetic acid, Indones. J. Chem., 17 (2), 284–290.

[6] Syafei, D., Sugiarti, S., Darmawan, N., and Khotib, M., 2017, Synthesis of TiO2/carbon nanoparticle (C-dot) composites as active catalysts for photodegradation of persistent organic pollutant, Indones. J. Chem., 17 (1), 37–42.

[7] Mallakpour S., and Khadem, E., 2016, Carbon nanotube-metal oxide nanocomposites: Fabrication, properties and applications, Chem. Eng. J., 302, 344–367.

[8] Zhou W., Zhang L., Denghui J., Zhong, X., and Li, X., 2016, Enhanced photocatalytic degradation of organic dyes by palladium nanocrystals, J. Nanosci. Nanotechnol., 16 (7), 7497–7502.

[9] Chen, Y., Zhang, C., Huang, W., Yang, C., Huang, T., Situ, Y., and Huang, H., 2014, Synthesis of porous ZnO/TiO2 thin films with superhydrophilicity and photocatalytic activity via a template-free sol-gel method, Surf. Coat. Technol., 258, 531–538.

[10] Ackacha, M.A., and Drmoon, M., 2012, Effect of important selected parameters on adsorption capacity of brilliant cresyl blue dye onto novel adsorbent: Tamarix aphylla leaves, IPCBEE, 48, 71–75.

[11] Qin, L., Liu, M., Wu, Y., Xu, Z., Guo, X., and Zhang, G., 2016, Bioinspired hollow and hierarchically porous MOx(M =Ti, Si)/carbon microellipsoids supported with Fe2O3 for heterogeneous photochemical oxidation, Appl. Catal., B, 194, 50–60.

[12] Rattan, V.K., Purai, A., Singh, H., and Manoochehri, M., 2008, Adsorption of dyes from aqueous solution by cow dung ash, Carbon Lett., 9 (1), 1–7.

[13] Al-Gubury, H.A., and Mohammed, Q.Y., 2016, Prepared coupled ZnO-Co2O3 then study the photocatalytic activities using crystal violet dye, JCHPS, 9 (3), 1161–1165.

[14] Pei, C.C., and Leung, W.W.F., 2013, Photocatalytic degradation of Rhodamine B by TiO2/ZnO nanofibers under visible-light irradiation, Sep. Purif. Technol., 114, 108–116.

[15] Subramonian, W., Wu, T.Y., and Chai, S.P., 2017, Photocatalytic degradation of industrial pulp and paper mill effluent using synthesized magnetic Fe2O3-TiO2: Treatment efficiency and characterizations of reused photocatalyst, J. Environ. Manage., 187, 298–310.

[16] Purnawan, C., Wahyuningsih, S., and Kusuma, P.P., 2016, Photocatalytic and photoelectrocatalytic degradation of methyl orange using graphite/PbTiO3 composite, Indones. J. Chem., 16 (3), 347–352.

[17] Patil, P.N., Bote, S.D., and Gogate, P.R., 2014, Degradation of imidacloprid using combined advanced oxidation processes based on hydrodynamic cavitation, Ultrason. Sonochem., 21 (5), 1770–1777.

[18] Gosu, V., Gurjar, B.R., Surampalli, R.Y., and Zhang, T.C., 2014, nFe0/GAC-mediated advanced catalytic per-oxidation for pharmaceutical wastewater treatment, J. Environ. Chem. Eng., 2 (4), 1996–2004.

[19] Al-Gubury, H.A., Study the activity of titanium dioxide nanoparticle using orange G dye, 2016, MJS, 35 (2), 319–330.



DOI: https://doi.org/10.22146/ijc.30135

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