The Effect of Salinity on the Release of Copper (Cu), Lead (Pb) And Zinc (Zn) from Tailing

https://doi.org/10.22146/ijc.21956

Apriani Sulu Parubak(1*), Eko Sugiharto(2), Mudjiran Mudjiran(3)

(1) Faculty of Agriculture, Cendrawasih University, Manokwari, Irian Jaya
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(*) Corresponding Author

Abstract


The effects of salinity on the release of copper (Cu), lead (Pb) and zinc (Zn) in tailing sediment have been studied by stripping voltammetry. The purpose of the research is to know the effect of salinity on the release of metals with certain pH, conductivity and variety of metals. Simultaneous determination of copper, lead and zinc in tailing was done by Differential Pulse Anodic Stripping Voltammetry (DPASV) onto hanging mercury drop electrode (HMDE) and nitric acid 65% as support electrolyte. The limit of detection for this method 0.60 µg/L, 0.150 µg/L and 0.238 µg/L for copper, lead and iMc respectively. The stripping solution of 300/00 salinity with pH= 7.85, conductivity= 46.62 mS/cm gives the amounts of released metals as follows :14.867 µg/L Cu, 0.976 µg/L Pb and 6.224 µg/L Zn. These results are higher as compared with the results from 15 0/00 salinity with pH= 7.66, conductivity= 23.22 mS/cm that give released metals of Cu= 7.988 µg/L, Pb= 0.311 µg/L and Zn= 4.699 µg/L. the results from ANOVA suggest that this is due to different in salinity of the solution. It also found that the conductivity does not give any effect. It can be concluded that the higher salinity will that give higher concentration or released metals.

Keywords


tailing; salinity; voltammetry

Full Text:

Full Text Pdf


References

[1] Anderson, R., 1987, “Sample Pretreatment and Separation”, John Wiley & Son.

[2] Donat, J.R., and K.W. Bruland., 1995, "Trace Elements in the Oceans" in Trace Element in Natural Water, Chapter 11, CRC Press, Boca Raton, London.

[3] Florence, T.M., and Batley, G.E., 1980, "Chemical Speciation in Natural Water", CRC, Crit. Rev. Anal. Chem., 9, 219.

[4] Manahan, E.S., 1994, "Environmental Chemistry", 6th edition, Lew1si Publisher, CRC Press Inc.

[5] Miller, J.C., dan Miller, J.N., 1991, "Statistika untuk Kimia Analitik", Edisi Kedua, Penerbit ITB, Bandung.

[6] Moore, J.W., and S. Ramammoorty., 1989, "Heavy Metal in Natural Water, Applied Monitoring and Impact Assesment', Springer-Verlag, New York.

[7] Nurnberg, H.W., and L. Mart., 1988, "The Determination of Trace Metals in natural Water", Blackwell Scientific Publication, Oxford, London.

[8] Osptapczuk, P., P. Valenta., and H.W. Nurnberg., 1986, "Square Wave Voltammetry-A Rapid Realiable Determination Method of Zn, Cd, Cu, Ni and Co in Biological and Environment Samples", J. Electroanal. Chem., 214, 51­64.

[9] Van der Weijden, 0.H., M.J.H.L. Arnoldos., and C.J. Meurs., 1977, "Desorption of Metal from Suspended Material in the Rhine Estuary", Netherlands Journal of Sea Research, 11, 130-145.

[10] Wang, J., 1985, Stripping Analysis, Principles, Instrumentation and Application, VCH Publishers, Deerfield Beach, FL.



DOI: https://doi.org/10.22146/ijc.21956

Article Metrics

Abstract views : 1497 | views : 1950


Copyright (c) 2010 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 

Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web Analytics View The Statistics of Indones. J. Chem.