SILVER RECYCLING FROM PHOTO-PROCESSING WASTE USING ELECTRODEPOSITION METHOD
Mochammad Feri Hadiyanto(1*), Agus Kuncaka(2)
(1) Chemistry Department, Faculty of Mathematics and Natural Sciences Gadjah Mada University, Yogyakarta
(2) Chemistry Department, Faculty of Mathematics and Natural Sciences Gadjah Mada University, Yogyakarta
(*) Corresponding Author
Abstract
Silver electrodeposition of photo-processing waste and without addition of KCN 1,0 M has been studied for silver recycling. Photo procesing waste containing silver in form of [Ag(S2O3)2]3- was electrolysed at constant potential and faradic efficiency was determined at various of electrolysis times. Electrolysis of 100 mL photo processing waste without addition of KCN 1,0 M was carried out at constant potential 1.20 Volt, while electrolysis 100 mL photo procesing waste with addition of 10 mL KCN 1,0 M electrolysis was done at 1.30 Volt.The results showed that for silver electrodeposition from photo processing waste with addition of KCN 1,0 M was more favorable with faradic efficiency respectively were 93,16; 87,02; 74,74 and 78,35% for 30; 60; 90 and 120 minutes of electrolysis.
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[1] Mees, C.E.K, and James, T.H., 1966, “The Theory of the Photographic Process”, 3rd edition, The Macmillan Co., New York.
[2] Bard, A.J., Faulkner, L.R., 1991, “Electrochemical Methods : Fundamental and Applications”, John Wiley and Sons, New York.
[3] Bochris, J.O.M., Drazic, D.M., 1972, “Electrochemicalcal Science“ Edisi ke-1, Taylor and Francis Ltd., London.
[4] Nebblette, C. B., 1970, “Fundamental of Photography”, Van Norstrand Reinhold Co., Princeton, New Jersey.
DOI: https://doi.org/10.22146/ijc.21921
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