PHOTOCATALYTIC DEGRADATION OF PENTACHLOROPHENOL (PCP) USING IMOBILIZED TiO2

https://doi.org/10.22146/ijc.21707

Winarti Andayani(1*), Agustin Sumartono(2)

(1) Centre for the Application Technology of Isotopes and Radiation, National Nuclear Energy Agency, Jl. Cinere, Pasar Jumat, Lebak Bulus, Jakarta Selatan
(2) Centre for the Application Technology of Isotopes and Radiation, National Nuclear Energy Agency, Jl. Cinere, Pasar Jumat, Lebak Bulus, Jakarta Selatan
(*) Corresponding Author

Abstract


Imobilization of titanium plate using titanium diisopropoxide as a precursor, that will be used as a catalyst for degradation of pentachlorophenol (PCP) has been done. In this study 10 ppm of pentachlorophenol (PCP) solution at pH 5 was used as a model of organic polutant. Irradiation was done with and without TiO2 as a catalyst. Sampling was done at interval time  of  15, 30, 45, 60, 75, 90, 105, 120, 135, 150, 165, 180, 195, 210, 225 and 240 minutes. Parameter examined after irradiation were the changes of spectrum and pH, the formation of chloride ions and intermediate compounds. The decreased of pH and PCP concentration and the formation of chloride ions and intermediate compounds showed that PCP has already degraded.


Keywords


PCP; TiO2; photocatalytic

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References

[1] Hoffman, MR., Martin, ST., Choi, W., and Bahnemann, DW, 1995, Chem Rev, 95,1,67-69.

[2] Fujishima, A, and Hashimoto K, 1997, TiO2 Photocayalysis Fundamentals and Applications, BKC, Tokyo, 104

[3] Andayani, W., 2001, Degradasi Pentaklorofenol dalam Air secara Fotokatalitik dengan TiO2 yang Diimobilisasikan pada Logam Titanium Evolusi Senyawa Intermediet, Tesis Magister Ilmu Kimia UI Depok.

[4] Halmann, MM., 1995, Photodegradation of Water Pollutants, CRC Press Inc, Tokyo.

[5] Llinsebigler, AL., Lu, G and Yates, JT Jr., 1995, Chem Rev, 95, 3, 735-738.

[6] Mills, G and Hoffmann, MR., 1993, Environ Sci Technol, 27, 1681-1689.

[7] Larson, RA and Weber EJ., 1994, Reaction Mechanisms in Environmental Organic Chemistry, Lewis Publishers, New York.

[8] Galves, JB and Rodrigues, SM., 1993, Influence of Solar Irradiation over Pentachlorophenol solar photocatalytic decomposition, Photocatalytic Purification and Treatment of Water and Air, Elsevier Science Publishers BV, Tokyo.

[9] Sykes, P., 1989, Penuntun Mekanisme Reaksi Kimia Organik, Gramedia, Jakarta.

[10] Pauling, L., 1967, The Nature of Chemical Bond, 3rd ed, Cornell University Press, New York.

[11] He, Y., Liu J., Lu Y and Wu J, 2002, Rad.Phys.Chem. 65, 565-570.



DOI: https://doi.org/10.22146/ijc.21707

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Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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