ADSORPTION KINETICS OF Pb(II), Cd(II) AND Cr(III) ON ADSORBENT PRODUCED BY PROTECTED-CROSSLINKING OF HUMIC ACID-CHITOSAN

https://doi.org/10.22146/ijc.21484

Dewi Umaningrum(1*), Uripto Trisno Santoso(2), Radna Nurmasari(3), Rahmat Yunus(4)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lambung Mangkurat University, Jl. A. Yani Km 35,8 Banjarbaru, Kalimantan Selatan, 70714
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lambung Mangkurat University, Jl. A. Yani Km 35,8 Banjarbaru, Kalimantan Selatan, 70714
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lambung Mangkurat University, Jl. A. Yani Km 35,8 Banjarbaru, Kalimantan Selatan, 70714
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Lambung Mangkurat University, Jl. A. Yani Km 35,8 Banjarbaru, Kalimantan Selatan, 70714
(*) Corresponding Author

Abstract


Study on adsorption kinetics of of Pb(II), Cd(II) and Cr(III) on adsorbent which was produced by protected-crosslinking of humic acid-chitosan has been done. The Langmuir-Hinshelwood, pseudo first- and second-order kinetics models were used to describe the kinetic data, and the rate constants of adsorption were also evaluated. The experimental data fitted well the second-order kinetics model, indicating that the chemical sorption is the rate-limiting step, instead of mass transfer. The initial metal ion concentration significantly affects the adsorption rate. An increase in initial metal ion concentration results in the decrease in adsorption rate of the metals.


Keywords


kinetics; adsorption; crosslinking; humic acid; chitosan

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References

[1]   Mahajan, S.P., 2002, Pollution Control in Process Industries, Tata McGraw-Hill Pub. Co. Ltd., New Delhi.

[2]   Santoso, U.T., Herdiansyah, and Mikrianto, E., 2004, Isolasi Asam Humat dari Tanah Gambut dan Batubara serta Interaksinya dengan Krom(III), Timbal(II) dan Kadmium(II), Laporan Hibah Penelitian Program Peningkatan Kualitas ISS dan Jurusan, Universitas Lambung Mangkurat, Banjarbaru.

[3]   Santoso, U.T., Irawati, U., Umaningrum, D., Nurmasari, R., Santosa, S.J., Siswanta, D., and Rusdiarso, B., 2009, Proceeding of International Seminar on Sains and Technology: 706-712.

[4]   Santoso, U.T., Irawati, U., Umaningrum, D., and Nurmasari, R., 2008, Indo. J. Chem., 8, 2, 177-183.

[5]   Tarchitzky, J., Chen, Y., and Banin, A., 1993, Soil Sci. Soc. Am. J., 57, 367-372.

[6]   Santoso, U.T., and Herdiansyah, 2004, Indo. J. Chem., 4, 1, 12-25.

[7]   No, H.K., and Meyer, S.P., 1989, J. Agric. Food Chem., 37, 3, 580-583.

[8]   Santoso, U.T., Irawati, U., Umaningrum, D., and Utami, U.B.L., 2007, Imobilisasi Asam Humat pada Kitosan Menggunakan Metode Pengikatan-Silang dan Aplikasinya sebagai Adsorben Pb(II) dan Cd(II), Seminar Nasional Kimia, Yogyakarta, 17 November 2007.

[9]   Santoso, U.T., Irawati, U., Umaningrum, D., and Komari, N., 2007, Pengaruh Pengikatan-Silang Antarmolekul Asam Humat terhadap Kelarutan dan Kemampuannya Mengadsorpsi Pb(II) dan Cd(II), Seminar Nasional Kimia dan Pendidikan Kimia, Semarang, 22 November 2007.

[10] Jin, X., Bailey, G.W., Yu, Y.S., dan Lynch, A.T., 1996, Soil Sci., 161, 8, 509-520.

[11] Azizian, S., 2004, J. Colloid Interface Sci., 276, 1, 47-52.

[12] McKay, G., and Ho, Y.S., 1999, Process Biochem., 34, 5, 451-465.

[13] de la Rosa, G., Gardea-Torresdey, J.L., Peralta-Videa, J.R., Herrera, I., and Contreras, C., 2003, Bioresour. Technol., 90, 1, 11-17.

[14] Ho, Y.S., and McKay, G., 2000, Water Res., 34, 3, 735-742.



DOI: https://doi.org/10.22146/ijc.21484

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