Cadmium Adsorption on Chitosan/Chlorella Biomass Sorbent Prepared by Ionic-Imprinting Technique

https://doi.org/10.22146/ijc.21210

Anis Shofiyani(1*), Narsito Narsito(2), Sri Juari Santosa(3), Sri Noegrohati(4), Titin Anita Zahara(5), Endah Sayekti(6)

(1) Department of Chemistry, Tanjungpura, University, Jl. A. Yani Pontianak 78124
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(4) Faculty of Pharmacy, Universitas Gadjah Mada, Jl. Sekip Utara Yogyakarta 55281
(5) Department of Chemistry, Tanjungpura, University, Jl. A. Yani Pontianak 78124
(6) Department of Chemistry, Tanjungpura, University, Jl. A. Yani Pontianak 78124
(*) Corresponding Author

Abstract


Ionic-Imprinted Chitosan/Chlorella biomass sorbent (IICCb) has been synthesized for selective adsorption of Cd(II) adsorption. IICCb was prepared by coating Cd(II)-complexed-chitosan hydrogel on the biomass surface followed by cross-linking procedure. Cd(II)-imprinting ions were then eluted using Na2EDTA solution to provide a specific template for binding sites of Cd(II). Batch adsorption was carried out as function of initial pH, contact time, and initial concentration of the Cd(II) solution. Result showed that the optimum adsorption of Cd(II) was found at pH 4-6. Study of pseudo-second order kinetic showed that the adsorption of Cd(II) on IICCb went faster than that on Ionic-Imprinted Chitosan (IIC) or Non-Imprinted Ionic Chitosan/Chlorella sorbent (NIICCb). The maximum Cd(II) adsorption capacity as obtained from Langmuir adsorption isotherm was found to be 53.76 mg/g on IICCb, that was comparatively higher than that on IIC (44.44 mg/g) or on NIICCb (51.02 mg/g) adsorbent.

Keywords


Ionic-Imprinted Chitosan/Chlorella biomass sorbent; adsorption; Cd(II)

Full Text:

Full Text Pdf


References

[1] Jha, I.N., Iyenger, L., and Rao, A.V.S.P., 1988, J. Environ. Eng., 114(4), 964–974.

[2] Debbaudt, A.L., Ferreira, M.L., and Gschaider, M.E., 2004, Carbohdr. Polym., 56(3), 321–332.

[3] Beigi, S.M., Babapoor, A., Maghsoodi, V., Mousavi, S.M., and Rajabi, N., 2009, Iran. J. Chem. Chem. Eng., 28(3), 81–89.

[4] Guangyu, Y., and Viraraghavan, T., 2000, Water. SA, 26(1), 119–123.

[5] Bayramoğlu, G., Bektaş, S., and Arica, M.Y., 2003, J. Hazard. Mater., 101(3), 285–300.

[6] Chen, J.P., Lie, D., Wang, L., Wu, S., and Zhang, B., 2002, J. Chem. Technol. Biotechnol., 77(6), 657–662.

[7] Hussein, H., Ibrahim, S.F., Kandeel, K., and Moawad, H., 2004, Electron. J. Biotechnol., 7(1), 38–46.

[8] Dönmez, G.Ç., Aksu, Z., Öztürk, A., and Kutsal, T., 1999, Process Biochem., 34(9), 885–892.

[9] Dönmez, G.Ç., and Aksu, Z., 2002, Process Biochem., 38(5), 751–762.

[10] Chen, J.P., and Yang, L., 2006, Langmuir, 22(21), 8906–8914.

[11] Domard, A., 1996, Proceedings of the 2nd Asia Pacific Symposium on Chitin and Chitosan, 21-23 November 1996, Bangkok, 3–11.

[12] Guibal, E., 2004, Sep. Purif. Technol., 38(1), 43–74.

[13] Rinaudo, M., 2006, Prog. Polym. Sci., 31(7), 603–632.

[14]Hsien, T.Y., and Rorrer, G.L., 1997, Ind. Eng. Chem. Res., 36(9), 3631–3638.

[15] Guibal, E., Milot, C., and Tobin, J.M., 1998, Ind. Eng. Chem. Res., 37(4), 1454–1463.

[16] Gao, Y., Lee, K.H., Oshima, M., and Motomizu, S., 2000, Anal. Sci., 16(12), 1303–1308.

[17] Yan, Z., Haijia, S., and Tianwei, T., 2007, Korean J. Chem. Eng., 24(6), 1047–1052.

[18] Tianwei, T., Xiaojing, H., and Weixia, D., 2001, J. Chem. Technol. Biotechnol., 76(2), 191–195.

[19] Wan Ngah, C.S., Endud, C.S., and Mayanar, R., 2002, React. Funct. Polym., 50(2), 181–190.

[20] Chen, A-H., Liu, S-C., Chen, C-Y., and Chen, C-Y., 2008, J. Hazard. Mater., 154(1-3), 184–191.

[21] Li, N., and Bai, R., 2006, Water Sci. Technol., 54, 103–111.

[22] Li, N., and Bai, R., 2005, Sep. Purif. Technol., 42(3), 237–247.

[23] Cui, Z., Xiang, Y., Si, J., Yang, M., and Zhang, T., 2008, Carbohydr. Polym., 73(1), 111–116.

[24] Chen, A-H., Yang, C-Y., Chen, C-Y., Chen, C-Y., and Chen, C-W., 2009, J. Hazard. Mater., 163(2-3), 1068–1075.

[25] Chen, C-Y., Yang, C-Y., and Chen, A-H., 2011, J. Environ. Manage., 92(3), 796–802.

[26] Nishad, P.A., Bhaskarapillai, A., Vemurugan, S., and Narasimhan, S.V., 2012, Carbohydr. Polym., 87(4), 2690–2696.

[27] Haijia, S., Zhixing, W., and Tianwei, T., 2005, J. Chem. Technol .Biotechnol., 4(80), 439–444.

[28] Haijia, S., Ying, Z., Jia, Li., and Tianwei, T., 2006, Process Biochem., 41(6), 1422–1426.

[29] Xiang, L., Haijia, S., and Tianwei, T., 2007, J. Environ. Manage., 85(4), 900–907.

[30] Aksu, Z., and Dönmez, G.Ç., 2006, Process Biochem., 41(4), 860–868.

[31] Doshi, H., Ray, A., Kothari, I.L., and Gami, B., 2006, Curr. Microbiol., 53(2), 148–157.

[32] Ho, Y.S., and McKay, G., 2000, Water Res., 34(3), 735–742.

[33] Srivastava, V.C., Mall, I.D., and Mishra, M., 2009, Chem. Eng. Process. Process Intensif., 48, 370–379.

[34] Liu, H., Yang, F., Zheng, Y., Kang, J., Qu, J., and Chen, J.P., 2011, Water Res., 45(1), 145–154.

[35] Fan, W., and Xu, Z., 2011, Chem. Biochem. Eng. Q., 25(2), 247–254.

[36] Ramesh, A., Hasegawa, H., Sugimoto, W., Maki, T., and Ueda, K., 2008, Bioresour.Technol., 99(9), 3801–3809.

[37] Vijaya, Y., Popuri, S.R., Boddu, V.M., and Krishnaiah, A., 2008, Carbohdr. Polym., 72(2), 261–271.

[38] Hasan, S., Ghosh, T.K., Viswanath, D.S., and Boddu, V.M., 2008, J. Hazard. Mater., 152(2), 826–837.

[39] Boddu, V.M., Abburi, K., Talbott, J.L., and Smith, E.D., 2003, Environ. Sci. Technol., 37(19), 4449–4456.

[40] Li, C.X., Pan, J.M., Gao, J., Yan, Y.S., and Zhao, G.Q., 2009, Chin. Chem. Lett., 20(8), 985–989.

[41] Huheey, J.E., Keiter, E.A., and Keiter, R.L., 1993, Inorganic Chemistry: Principles of Structure and Reactivity, 4th ed., Harper Collins College Publishers, New York.



DOI: https://doi.org/10.22146/ijc.21210

Article Metrics

Abstract views : 843 | views : 953


Copyright (c) 2015 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 / 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.