Ozone Plasma Nanobubble (OPN) Reactor Combined with Coagulation-Flocculation Process: A Promising Technology for Leachate Treatment

https://doi.org/10.22146/ijc.94559

Habiibatuz Zahra(1), Ken Azzahra(2), Azizka Inneke Putri(3), Veny Luvita(4), Setijo Bismo(5*)

(1) Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Jl. Dr. Indro S, Depok 16424, Indonesia
(2) Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Jl. Dr. Indro S, Depok 16424, Indonesia
(3) Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Jl. Dr. Indro S, Depok 16424, Indonesia
(4) Research Center for Environment and Clean Technology, National Research and Innovation Agency (BRIN), Jl. Raya Puspitek Serpong, Tangerang Selatan 15314, Indonesia
(5) Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Jl. Dr. Indro S, Depok 16424, Indonesia
(*) Corresponding Author

Abstract


According to World Bank data, approximately 2.01 billion tons of urban waste is produced annually, with approximately 33% of waste being improperly managed, leading to concentrated and toxic leachate. This poses a global challenge due to its varied characteristics influenced by climate, landfill age, and waste composition, resulting in groundwater and surface water pollution with severe impacts on human health, ecosystems, and biodiversity, necessitating stringent treatment measures. To address this, a study integrated coagulation-flocculation and advanced oxidation processes (AOPs) using a dielectric barrier discharge (DBD) ozone plasma nanobubble (OPN) reactor to degrade leachate. Gas flow rate, plasma voltage, and gas sources are variated. This research uses O2 or air as a gas source that produces plasma. The leachate is fed into the DBD reactor, so the bubble will burst and produce further ROS. Optimal results were observed after 60 min, with oxygen gas feed reducing total suspended solids (TSS), chemical oxygen demand (COD), and biological oxygen demand (BOD) by 100, 93.93, and 74.12%, respectively, alongside a decrease in pH. This study indicates the promising potential of this technology for leachate treatment and demonstrates the potential for nitrate production using both types of gas feed.


Keywords


AOPs; plasma technology; DBD; ozone; leachate

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References

[1] Kundariya, N., Mohanty, S.S., Varjani, S., Hao Ngo, H., Wong, J.W.C., Taherzadeh, M.J., Chang, J.S., Yong Ng, H., Kim, S.H., and Bui, X.T., 2021, A review on integrated approaches for municipal solid waste for environmental and economical relevance: Monitoring tools, technologies, and strategic innovations, Bioresour. Technol., 342, 125982.

[2] Peng, Y., 2017, Perspectives on technology for landfill leachate treatment, Arabian J. Chem., 10, S2567–S2574.

[3] Costa, A.M., Alfaia, R.G.S.M., and Campos, J.C., 2019, Landfill leachate treatment in Brazil–An overview, J. Environ. Manage., 232, 110–116.

[4] Koda, E., Miszkowska, A., and Sieczka, A., 2017, Levels of organic pollution indicators in groundwater at the old landfill and waste management site, Appl. Sci., 7 (6), 638.

[5] Wdowczyk, A., and Szymańska-Pulikowska, A., 2021, Comparison of landfill leachate properties by LPI and phytotoxicity-a case study, Front. Environ. Sci., 9, 693112

[6] Oladoja, N.A., 2015, Headway on natural polymeric coagulants in water and wastewater treatment operations, J. Water Process Eng., 6, 174–192.

[7] Isnadina, D.R.M., Adi, M.P., and Ardiyanto, I., 2019, Technical evaluation of leachate treatment plant at Klotok Landfill Kediri in 2017, IOP Conf. Ser.: Earth Environ. Sci., 245 (1), 012016.

[8] Irianti, L.A., and Wardani, R., 2020, Evaluate of Lindi Processing Technology in TPA Pojok Kota Kediri, J. Qual. Public Health, 4 (1), 59–63.

[9] Apriana, E., Supraba, I., and Kim, W., 2023, Constructed wetland at Galuga landfill for leachate treatment: A sustainable approach, Indones. J. Urban Environ. Technol., 6 (1), 75–89.

[10] Dhamayanthie, I., Bimantara, E., and Asminah, N., 2021, Analysing the management of waste and leachate in the final disposal site of Indramayu, Indones. J. Multidiscip. Sci., 1 (1), 28–39.

[11] Hussein, O.A., and Ibrahim, J.A.A., 2023, Leachates recirculation impact on the stabilization of the solid wastes–A review, J. Ecol. Eng., 24 (4), 172–183.

[12] Semblante, G.U., Hai, F.I., Dionysiou, D.D., Fukushi, K., Price, W.E., and Nghiem, L.D., 2017, Holistic sludge management through ozonation: A critical review, J. Environ. Manage., 185, 79–95.

[13] Lin, C., Liao, J., Wu, H., and Wei, C., 2016, Mechanism of ozone oxidation of polycyclic aromatic hydrocarbons during the reduction of coking wastewater sludge, Clean: Soil, Air, Water, 44 (11), 1499–1507.

[14] Kwarciak-Kozłowska, A., 2018, Pretreatment of stabilized landfill leachate using ozone, J. Ecol. Eng., 19 (5), 186–193.

[15] Rahmayanti, A., Faradila, R.S., Masrufah, A., and Sari, P.A.P., 2022, Pengolahan lindi menggunakan Advanced Oxidation Process (AOPs) berbasis ozon, JRT, 8 (1), 141–148

[16] Luvita, V., Sugiarto, A.T., and Bismo, S., 2022, Characterization of dielectric barrier discharge reactor with nanobubble application for industrial water treatment and depollution, S. Afr. J. Chem. Eng., 40, 246–257.

[17] Batagoda, J.H., Hewage, S.D.A., and Meegoda, J.N., 2019, Nano-ozone bubbles for drinking water treatment, J. Environ. Eng. Sci., 14 (2), 57–66.

[18] Tekile, A., Kim, I., and Lee, J.Y., 2017, Applications of ozone micro-and nanobubble technologies in water and wastewater treatment, J. Korean Soc. Water Wastewater, 31 (6), 481–490.

[19] Tampieri, F., Ginebra, M.P., and Canal, C., 2021, Quantification of plasma-produced hydroxyl radicals in solution and their dependence on the pH, Anal. Chem., 93 (8), 3666–3670.

[20] Cuong, L.C., Nghi, N.H., Dieu, T.V., Oanh, D.T.Y., and Vuong, D.D., 2019, Influence of oxygen concentration, feed gas flow rate and air humidity on the output of ozone produced by corona discharge: Frailty and Life Satisfaction in Elderly, Vietnam J. Chem., 57 (5), 604–608.

[21] Sahni, M., and Locke, B.R., 2006, Quantification of hydroxyl radicals produced in aqueous phase pulsed electrical discharge reactors, Ind. Eng. Chem. Res., 45 (17), 5819–5825.

[22] Prasetyaningrum, A., Kusumaningtyas, D.A., Suseno, P., Jos, B., and Ratnawati, R., 2018, Effect of pH and gas flow rate on ozone mass transfer of K-carrageenan solution in bubble column reactor, Reaktor, 18 (4), 177-182.

[23] Hoffmann, L.T., Jorge, M.C.B., do Amaral, A.G., Bongiovani, M.C., and Schneider, R.M., 2020, Ozonation as a pre-treatment of landfill leachate, Rev. Ambiente Agua, 15 (6), e2592.

[24] Rekhate, C.V., and Srivastava, J.K., 2020, Recent advances in ozone-based advanced oxidation processes for treatment of wastewater-A review, Chem. Eng. J. Adv., 3, 100031.

[25] Galdeano, M.C., Wilhelm, A.E., Goulart, I.B., Tonon, R.V., Freitas-Silva, O., Germani, R., and Chávez, D.W.H., 2018, Effect of water temperature and pH on the concentration and time of ozone saturation, Braz. J. Food Technol., 21, e2017156.

[26] Batakliev, T., Georgiev, V., Anachkov, M., Rakovsky, S., and Zaikov, G.E., 2014, Ozone decomposition, Interdiscip. Toxicol., 7 (2), 47–59.

[27] Kweinor Tetteh, E., Rathilal, S., and Robinson, K., 2017, Treatment of industrial mineral oil wastewater–effects of coagulant type and dosage, Water Pract. Technol., 12 (1), 139–145

[28] Tahraoui, H., Toumi, S., Boudoukhani, M., Touzout, N., Sid, A.N.H., Amrane, A., Belhadj, A.E., Hadjadj, M., Laichi, Y., Aboumustapha, M., Kebir, M., Bouguettoucha, A., Chebli, D., Assadi, A.A., and Zhang, J., 2024, Evaluating the effectiveness of coagulation–flocculation treatment using aluminum sulfate on a polluted surface water source: A year-long study, Water, 16 (3), 400.

[29] Irfan, M., Butt, T., Imtiaz, N., Abbas, N., Khan, R.A., and Shafique, A., 2017, The removal of COD, TSS and colour of black liquor by coagulation–flocculation process at optimized pH, settling and dosing rate, Arabian J. Chem., 10, S2307–S2318

[30] Dharini, M., Jaspin, S., and Mahendran, R., 2023, Cold plasma reactive species: Generation, properties, and interaction with food biomolecules, Food Chem., 405, 134746.

[31] Kumar, P.G., Kanmani, S., Kumar, P.S., and Rangabhashiyam, S., 2022, Treatability studies on the optimization of ozone and carbon dosages for the effective removal of contaminants from secondary treated effluent, Adsorpt. Sci. Technol., 2022, 1998549.

[32] Keris-Sen, U.D., and Yonar, T., 2023, Nitrate and/or nitric acid formation in the presence of different radical scavengers during ozonation of water samples; Are scavengers effective? Water, 15 (10), 1840.

[33] Kumari, P., and Kumar, A., 2023, Advanced oxidation process: A remediation technique for organic and non-biodegradable pollutant, Results Surf. Interfaces, 11, 100122.

[34] Schiavon, M., Scapinello, M., Tosi, P., Ragazzi, M., Torretta, V., and Rada, E.C., 2015, Potential of non-thermal plasmas for helping the biodegradation of volatile organic compounds (VOCs) released by waste management plants, J. Cleaner Prod., 104, 211–219.

[35] Wang, C., Sun, X., Shan, H., Zhang, H., and Xi, B., 2021, Degradation of landfill leachate using UV-TiO2 photocatalysis combination with aged waste reactors, Processes, 9 (6), 946.

[36] Hassan, H.M.A., Alsohaimi, I.H., Essawy, A.A., El-Aassar, M.R., Betiha, M.A., Alshammari, A.H., and Mohamed, S.K., 2023, Controllable fabrication of Zn2+ self-doped TiO2 tubular nanocomposite for highly efficient water treatment, Molecules, 28 (7), 3072.

[37] Oturan, M.A., and Aaron, J.J., 2014, Advanced oxidation processes in water/wastewater treatment: Principles and applications. A review, Crit. Rev. Environ. Sci. Technol., 44 (23), 2577–2641.

[38] Ghuge, S.P., and Saroha, A.K., 2018, Catalytic ozonation for the treatment of synthetic and industrial effluents - Application of mesoporous materials: A review, J. Environ. Manage., 211, 83–102.

[39] Phan, L.T., Schaar, H., Saracevic, E., Krampe, J., and Kreuzinger, N., 2022, Effect of ozonation on the biodegradability of urban wastewater treatment plant effluent, Sci. Total Environ., 812, 152466.

[40] Babu Ponnusami, A., Sinha, S., Ashokan, H., Paul, M.V., Hariharan, S.P., Arun, J., Gopinath, K.P., Hoang Le, Q., and Pugazhendhi, A., 2023, Advanced oxidation process (AOP) combined biological process for wastewater treatment: A review on advancements, feasibility and practicability of combined techniques, Environ. Res., 237, 116944.

[41] Mouele, E.S.M., Tijani, J.O., Badmus, K.O., Pereao, O., Babajide, O., Fatoba, O.O., Zhang, C., Shao, T., Sosnin, E., Tarasenko, V., Laatikainen, K., and Petrik, L.F., 2021, A critical review on ozone and co-species, generation and reaction mechanisms in plasma induced by dielectric barrier discharge technologies for wastewater remediation, J. Environ. Chem. Eng., 9 (5), 105758.

[42] Burlica, R., Kirkpatrick, M.J., and Locke, B.R., 2006, Formation of reactive species in gliding arc discharges with liquid water, J. Electrost., 64 (1), 35–43.

[43] Saksono, N., Harianingsih, H., Farawan, B., Luvita, V., and Zakaria, Z., 2023, Reaction pathway of nitrate and ammonia formation in the plasma electrolysis process with nitrogen and oxygen gas injection, J. Appl. Electrochem., 53 (6), 1183–1191.



DOI: https://doi.org/10.22146/ijc.94559

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