Enhanced Capacity and Easily Separable Adsorbent of Dithizone-immobilized Magnetite Zeolite for Pb(II) Adsorption

https://doi.org/10.22146/ijc.90914

Carissa Ayu Susiana(1), Bambang Rusdiarso(2), Mudasir Mudasir(3*)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia
(*) Corresponding Author

Abstract


In this study, magnetic natural zeolite (ZTM) was prepared using the coprecipitation method and dithizone was then immobilized on its surface in less toxic medium of alkaline to yield dithizone-immobilized magnetic zeolite (ZTM-Dtz). The synthesized ZTM-Dtz was characterized by FTIR and XRD, indicating that dithizone was successfully immobilized on the surface of ZTM. Vibrating sample magnetometer measurements showed superparamagnetic properties of either ZTM or ZTM-Dtz with magnetization values of 7.35 and 11.49 emu g−1, respectively. The adsorption kinetics of Pb(II) on both adsorbents followed a pseudo-second-order and their adsorption isotherms were properly described by the Langmuir model. The adsorption capacity of ZTM and ZTM-Dtz were 6.94 and 38.46 mg g−1, respectively, suggesting that dithizone immobilization enhanced the adsorbent capacity more than 5 times. The interaction mechanism between Pb(II) metal ion and ZTM was dominated by ion exchange, whereas that of ZTM-Dtz was mostly hydrogen bonds and complexation. The synthesized material is promising to be developed for the adsorption of heavy metal ions such as Pb(II) because it provides a high adsorption capacity and the adsorbents can be easily separated magnetically after application.

Keywords


magnetic zeolite; dithizone; Pb(II) ions; adsorption; desorption

Full Text:

Full Text PDF


References

[1] Kumar, A., Kumar, A., Cabral-Pinto, M., Chaturvedi, A.K., Shabnam, A.A., Subrahmanyam, G., Mondal, R., Gupta, D.K., Malyan, S.K., Kumar, S.S., Khan, S.A., and Yadav, K.K., 2020, Lead toxicity: Health hazards, influence on food chain, and sustainable remediation approaches, Int. J. Environ. Res. Public Health, 17 (7), 2179.

[2] Balali-Mood, M., Naseri, K., Tahergorabi, Z., Khazdair, M.R., and Sadeghi, M., 2021, Toxic mechanisms of five heavy metals: Mercury, lead, chromium, cadmium, and arsenic, Front. Pharmacol., 12, 643972.

[3] Gazwi, H.S.S., Yassien, E.E., and Hassan, H.M., 2020, Mitigation of lead neurotoxicity by the ethanolic extract of Laurus leaf in rats, Ecotoxicol. Environ. Saf., 192, 110297.

[4] Renu, R., Agarwal, M., and Singh, K., 2017, Methodologies for removal of heavy metal ions from wastewater: An overview, Interdiscip. Environ. Rev., 18 (2), 124–142.

[5] Türkmen, D., Bakhshpour, M., Akgönüllü, S., Aşır, S., and Denizli, A., 2022, Heavy metal ions removal from wastewater using cryogels: A review, Front. Sustainability, 3, 765592.

[6] Kozlenko, D.P., Dubrovinsky, L.S., Kichanov, S.E., Lukin, E.V., Cerantola, V., Chumakov, A.I., and Savenko, B.N., 2019, Magnetic and electronic properties of magnetite across the high pressure anomaly, Sci. Rep., 9 (1), 4464.

[7] Wang, C., Leng, S., Guo, H., Cao, L., and Huang, J., 2019, Acid and alkali treatments for regulation of hydrophilicity/hydrophobicity of natural zeolite, Appl. Surf. Sci., 478, 319–326.

[8] Pambudi, T., Wahyuni, E.T., and Mudasir, M., 2020, Recoverable adsorbent of natural zeolite/Fe3O4 for removal of Pb(II) in water, J. Mater. Environ. Sci., 11 (1), 69–78.

[9] Huda, B.N., Wahyuni, E.T., and Mudasir, M., 2023, Simultaneous adsorption of Pb(II) and Cd(II) in the presence of Mg(II) ion using eco-friendly immobilized dithizone on coal bottom ash, S. Afr. J. Chem. Eng., 45, 315–327.

[10] Gaffer, A., Al Kahlawy, A.A., and Aman, D., 2017, Magnetic zeolite-natural polymer composite for adsorption of chromium(VI), Egypt. J. Pet., 26 (4), 995–999.

[11] Ntoi, L.L.A., Buitendach, B.E., and von Eschwege, K.G., 2017, Seven chromisms associated with dithizone, J. Phys. Chem. A, 121 (48), 9243–9251.

[12] Gogoi, A., Navgire, M., Sarma, K.C., and Gogoi, P., 2017, Novel highly stable β-cyclodextrin fullerene mixed valent Fe-metal framework for quick Fenton degradation of alizarin, RSC Adv., 7 (64), 40371–40382.

[13] Ivanković, A., Dronjić, A., Bevanda, A.M., and Talić, S., 2017, Review of 12 principles of green chemistry in practice, Int. J. Sustainable Green Energy, 6 (3), 39–48.

[14] Triyono, T., Trisunaryanti, W., Putri, Y.W., Fatmawati, D.A., and Chasanah, U., 2021, Modification of mordenite characters by H2C2O4 and/or NaOH treatments and its catalytic activity test in hydrotreating of pyrolyzed α-cellulose, Bull. Chem. React. Eng. Catal., 16 (1), 9–21.

[15] Rendo, D., 2021, Adsorption of methylene blue dye using Fe3O4 magnetized natural zeolite adsorbent, J. Kim. Sains Apl., 24 (2), 51–57.

[16] Buzukashvili, S., Hu, W., Sommerville, R., Brooks, O., Kökkılıç, O., Rowson, N.A., Ouzilleau, P., and Waters, K.E., 2023, Magnetic zeolite: Synthesis and copper adsorption followed by magnetic separation from treated water, Crystals, 13 (9), 1369.

[17] Cashmore, A., Miller, R., Jolliffe, H., Brown, C.J., Lee, M., Haw, M.D., and Sefcik, J., 2023, Rapid assessment of crystal nucleation and growth kinetics: comparison of seeded and unseeded experiments, Cryst. Growth Des., 23 (7), 4779–4790.

[18] Sun, S.N., Wei, C., Zhu, Z.Z., Hou, Y.L., Venkatraman, S.S., and Xu, Z.C., 2014, Magnetic iron oxide nanoparticles: Synthesis and surface coating techniques for biomedical applications, Chin. Phys. B, 23 (3), 037503.

[19] Storozhuk, L., and Iukhymenko, N., 2019, Iron oxide nanoparticles modified with silanes for hyperthermia applications, Appl. Nanosci., 9 (5), 889–898.

[20] Elwakeel, K.Z., Hamza, M.F., and Guibal, E., 2021, Effect of agitation mode (mechanical, ultrasound and microwave) on uranium sorption using amine-and dithizone-functionalized magnetic chitosan hybrid materials, Chem. Eng. J., 411, 128553.

[21] Dhahawi Ahmad, A.R., Imam, S.S., Oh, W.D., and Adnan, R., 2020, Fe3O4-zeolite hybrid material as hetero-Fenton catalyst for enhanced degradation of aqueous ofloxacin solution, Catalysts, 10 (11), 1241.

[22] Rampengan, A.M., and Tengker, S.M.T., 2021, Analisa sifat kemagnetan polimer poliethylen glycol (PEG-4000)-coated nanopartikel magnetite Fe3O4 menggunakan vibrating sample magnetometer (VSM), Fullerene J. Chem., 6 (2), 161–164.

[23] Prasetyowati, R., Widiawati, D., Swastika, E., and Ariswan, W., 2021, Sintesis dan karakterisasi nanopartikel magnetit (Fe3O4) berbasis pasir besi pantai Glagah Kulon Progo dengan metode kopresipitasi pada berbagai variasi konsentrasi NH4OH, J. Sains Dasar, 10 (2), 57–61.

[24] Caccin, M., Giorgi, M., Giacobbo, F., Da Ros, M., Besozzi, L., and Mariani, M., 2016, Removal of lead (II) from aqueous solutions by adsorption onto activated carbons prepared from coconut shell, Desalin. Water Treat., 57 (10), 4557–4575.

[25] Huang, J., Yuan, F., Zeng, G., Li, X., Gu, Y., Shi, L., Liu, W., and Shi, Y., 2017, Influence of pH on heavy metal speciation and removal from wastewater using micellar-enhanced ultrafiltration, Chemosphere, 173, 199–206.

[26] Asanu, M., Beyene, D., and Befekadu, A., 2022, Removal of hexavalent chromium from aqueous solutions using natural zeolite coated with magnetic nanoparticles: Optimization, kinetics, and equilibrium studies, Adsorpt. Sci. Technol., 2022, 8625489.

[27] Gracias, W., Huda, B.N., Suratman, A., and Mudasir, M., 2022, Immobilization of dithizone on magnetic zeolite in less toxic medium and its application as adsorbent Cd(II) ion in water, Mater. Sci. Forum, 1076, 133–142.

[28] Aminy, D.E., Rusdiarso, B., and Mudasir, M., 2022, Adsorption of Cd(II) ion from the solution using selective adsorbent of dithizone-modified commercial bentonite, Int. J. Environ. Sci. Technol., 19 (7), 6399–6410.

[29] Huda, B.N., Wahyuni, E.T., Kamiya, Y., and Mudasir, M., 2022, Kinetic and thermodynamic study on adsorption of lead(II) ions in water over dithizone-immobilized coal bottom ash, Mater. Chem. Phys., 282, 126005.

[30] Neolaka, Y.A.B., Lawa, Y., Naat, J., Riwu, A.A.P., Mango, A.W., Darmokoesoemo, H., Widyaningrum, B.A., Iqbal, M., and Kusuma, H.S., 2022, Efficiency of activated natural zeolite-based magnetic composite (ANZ-Fe3O4) as a novel adsorbent for removal of Cr(VI) from wastewater, J. Mater. Res. Technol., 18, 2896–2909.

[31] Adamson, A.W., 1990, Physical Chemistry of Surfaces, John Wiley & Sons, New York, US.

[32] Kaur, M., Kumari, S., and Sharma, P., 2020, Removal of Pb(II) from aqueous solution using nanoadsorbent of Oryza sativa husk: Isotherm, kinetic and thermodynamic studies, Biotechnol. Rep., 25, e00410.

[33] Zulfiqar, M., Lee, S.Y., Mafize, A.A., Abdul Kahar, N.A.M., Johari, K., and Rabat, N.E., 2020, Efficient removal of Pb(II) from aqueous solutions by using oil palm bio-waste/MWCNTs reinforced PVA hydrogel composites: Kinetic, isotherm and thermodynamic modeling, Polymers, 12 (2), 430.

[34] Fitriana, D., Mudasir, M., and Siswanta, D., 2020, Adsorption of Pb(II) from aqueous solutions on dithizone-immobilized coal fly ash, Key Eng. Mater., 840, 57–63.

[35] Li, J., Hu, Z., Chen, Y., and Deng, R., 2023, Removal of Pb(II) by adsorption of HCO–(Fe3O4)x composite adsorbent: Efficacy and mechanism, Water, 15 (10), 1857.

[36] Sočo, E., and Kalembkiewicz, J., 2013, Adsorption of nickel(II) and copper(II) ions from aqueous solution by coal fly ash, J. Environ. Chem. Eng., 1 (3), 581–588.



DOI: https://doi.org/10.22146/ijc.90914

Article Metrics

Abstract views : 1693 | views : 719


Copyright (c) 2024 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.