Synthesis, Characterization, and Control Release of Zinc Layered Nitrate Intercalated with Beta-Napthoxyacetic Acid (BNOA) Nanocomposite

https://doi.org/10.22146/ijc.88459

Hasnatul Fitriah Abd Rahim(1), Mohammad Nor Jalil(2), Siti Halimah Sarijo(3), Faeiza Buyong(4), Hamizah Mohd Zaki(5*)

(1) School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, Selangor 40450, Malaysia
(2) School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, Selangor 40450, Malaysia
(3) School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, Selangor 40450, Malaysia
(4) School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, Selangor 40450, Malaysia
(5) School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, Selangor 40450, Malaysia
(*) Corresponding Author

Abstract


In this research, the synthesis of the host using zinc nitrate-hexahydrate as a precursor to form zinc layered nitrate (ZLN) and the guest anion which is beta-napthoxyacetic acid (BNOA) will be intercalated with the ZLN to produce nanocomposites called ZLN/beta-napthoxyacetic acid (ZLNB). The method used for the synthesis of the host was self-assembly and ion exchange. The nanocomposites were confirmed with the basal spacing increases from 9.8 to 28.2 Å by using powder X-ray diffraction (PXRD). Therefore, proved the bigger basal spacing compared to the layered double hydroxide of MgAl and ZnAl. The appearance of the FTIR shift band at 1603 cm−1 of C=C aromatic ring indicates that the anions have been successfully incorporated into the interlayers of ZLNB. Moreover, the loading percentage estimated by the carbon content from the ZLNB determined by CHNS analyzer was 41.8% (w/w). The morphology analysis confirmed the plate-like structure for ZLN into flaky-like with irregular, porous and unambiguous structure for ZLNB by field emission scanning electron microscopy (FESEM). The controlled release property showed that the release of BNOA in the various aqueous solutions is in the order of Na3PO4 > Na2SO4 > NaCl and fitted into pseudo-second-order kinetic models.


Keywords


beta-napthoxyacetic acid (BNOA); control release; zinc layered nitrate



References

[1] Benício, L.P.F., Silva, R.A., Lopes, R.A., Eulálio, D., dos Santos, R.M.M., de Aquino, L.A., Vergütz, L., Novais, R.F., da Costa, L.M., Pinto, F.G., and Tronto, J., 2015, Layered double hydroxides: nanomaterials for applications in agriculture, Rev. Bras. Cienc. Solo, 39 (1), 1–13.

[2] Mallakpour, S., Hatami, M., and Hussain, C.M., 2020, Recent innovations in functionalized layered double hydroxides: Fabrication, characterization, and industrial applications, Adv. Colloid Interface Sci., 283, 102216.

[3] Forano, C., Costantino, U., Prévot, V., and Gueho, C.T., 2013, Layered double hydroxides (LDH), Dev. Clay Sci., 5, 745–782.

[4] Ahmad, R., Hussein, M.Z., Wan Abdul Kadir, W.R., Sarijo, S.H., and Yun Hin, T.Y., 2015, Evaluation of controlled-release property and phytotoxicity effect of insect pheromone zinc-layered hydroxide nanohybrid intercalated with hexenoic acid, J. Agric. Food Chem., 63 (51), 10893–10902.

[5] Bratovcic, A., Hikal, W.M., Said-Al Ahl, H.A.H., Tkachenko, K.G., Baeshen, R.S., Sabra, A.S., and Sany, H., 2021, Nanopesticides and nanofertilizers and agricultural development: Scopes, advances and applications, Open J. Ecol., 11 (4), 301–316.

[6] Muharam, S., Fitri, A., Yuningsih, L.M., Putri, Y.M.T.A., and Rahmawati, I., 2020, Synthesis and characterization of controlled-release urea fertilizer from superabsorbent hydrogels, Indones. J. Chem., 20 (3), 616–625.

[7] Dong, Y., Kong, X., Lou, X., and Wang H., 2022, Adsorptive removal of heavy metal anions from water by layered double hydroxide: A review, Chemosphere, 303, 134685.

[8] Zobir, S.A., Ali, A., Adzmi, F., Sulaiman, M.R., and Ahmad, K., 2021, A review on nanopesticides for plant protection synthesized using the supramolecular chemistry of layered hydroxide hosts, Biology, 10 (11), 1077.

[9] Hashim, N., Muda, Z., Md Isa, I., Mohd Ali, N., Abu Bakar, S., and Hussein, M.Z., 2017, The effect of ion exchange and co-precipitation methods on the intercalation of 3-(4-methoxyphenyl)propionic acid into layered zinc hydroxide nitrate, J. Porous Mater., 25 (1), 249–258.

[10] Abd Rahim, H.F., Mohd Zaki, H., Jalil, M.N., and Sarijo, S.H., 2023, Synthesis of zinc layered hydroxide with 2-napthoxyacetic acid (BNOA) with chloride as counter ions via ion exchange method, J. Mater. Phys. Chem., 11 (2), 29–37.

[11] Mohd Sharif, S.N., Hashim, N., Md Isa, I., Mohd Ali, N., Abu Bakar, S., Hussein, M.Z., Mamat, M., Abu Bakar, N., and Wan Mahamod, W.R., 2018, Preparation and characterisation of novel paddy cultivation herbicide nanocomposite from zinc/aluminium layered double hydroxide and quinclorac anion, Mater. Res. Innovations, 23 (5), 260–265.

[12] Khadiran, N.F., Hussein, M.Z., Ahmad, R., Khadiran, T., Zainal, Z., Wan Abdul Kadir, W.R., and Hashim, S.S., 2021, Preparation and properties of zinc layered hydroxide with nitrate and phosphate as the counter anion, a novel control release fertilizer formulation, J. Porous Mater., 28 (6), 1797–1811.

[13] Li, S., Shen, Y., Xiao, M., Liu, D., and Fan, L., 2019, Synthesis and controlled release properties of β-naphthoxyacetic acid intercalated Mg–Al layered double hydroxides nanohybrids, Arabian J. Chem., 12 (8), 2563–2571.

[14] Jubri, Z., Mohd Yusoff, N.Z.A., Sarijo, S.H., Marsom, E.S., and Hussein, M.Z., 2017, Synthesis, characterization and controlled release properties of zinc–aluminium-beta-naphthoxyacetate nanocomposite, J. Porous Mater., 24 (3), 573–582.

[15] Zhu, J., Zhu, Z., Zhang, H., Lu, H., Zhang, W., Qiu, Y., Zhu, L., and Küppers, S., 2018, Calcined layered double hydroxides/reduced graphene oxide composites with improved photocatalytic degradation of paracetamol and efficient oxidation-adsorption of As(III), Appl. Catal., B, 225, 550–562.

[16] Adam, N., Sheikh Mohd Ghazali, S.A.I., Dzulkifli, N.N., and Che Hak, C.R., 2021, Characterization, physiochemical, controlled release studies of zinc–aluminium layered double hydroxide and zinc layered hydroxide intercalated with salicylic acid, Bull. Mater. Sci., 44 (2), 155.

[17] Stepanova, L.N., Belskaya, O.B., Vasilevich, A.V., Gulyaeva, T.I., Leont'eva, N.N., Serkova, A.N., Salanov, A.N., and Likholobov, V.A., 2020, The study of structural, textural and basic properties of MgAl-and LiAl-LDH prepared by mechanochemical method, Catal. Today, 357, 638–645.

[18] Mohd Sharif, S.N., Hashim, N., Md Isa, I., Abu Bakar, S., Saidin, M.I., Ahmad, M.S., Mamat, M., and Hussein, M.Z., 2020, Controlled release formulation of zinc hydroxide nitrate intercalated with sodium dodecylsulphate and bispyribac anions: A novel herbicide nanocomposite for paddy cultivation, Arabian J. Chem., 13 (3), 4513–4527.

[19] Jubri, Z., Yusoff, N.Z.A., Marsom, E.S., and Sarijo, S.H., 2009, Controlled release of herbicide into water from Beta-naphtoxyacetic acid-layered double hydroxide nanohybrid formulation, 2009 3rd International Conference on Energy and Environment (ICEE), Malacca, Malaysia, 7-8 December 2009.

[20] Sarijo, S.H., Hussein, M.Z, Yahaya, A.H.J., and Zainal, Z., 2010, Effect of incoming and outgoing exchangeable anions on the release kinetics of phenoxyherbicides nanohybrids, J. Hazard. Mater., 182 (1-3), 563–569.

[21] Jensen, L.C., Neira-Albornoz, A., and Escudey, M., 2019, “Herbicides Mechanisms Involved in the Sorption Kinetic of Ionisable and Non Ionisable Herbicides: Impact of Physical/Chemical Properties of Soils and Experimental Conditions” in Kinetic Modeling for Environmental Systems, Eds. Abdel Rahman, R.O., IntechOpen, Rijeka, Croatia.

[22] Timóteo, T.R.R., de Melo, C.G., Danda, L.J.A., Silva, L.C.P.B.B., Fontes, D.A.F., Silva, P.C.D., Aguilera, C.S.G., Siqueira, L.P., Rolim, L.S., and Rolim Neto, P.J., 2019, Layered double hydroxides of CaAl: A promising drug delivery system for increased dissolution rate and thermal stability of praziquantel, Appl. Clay Sci., 180, 105197.

[23] Geilfus, C.M., 2019, Chloride in soil: From nutrient to soil pollutant, Environ. Exp. Bot., 157, 299–309.



DOI: https://doi.org/10.22146/ijc.88459

Article Metrics

Abstract views : 1334 | views : 526 | views : 469


Copyright (c) 2024 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.