Nano Titanium(IV) Oxide Modified Carbon Paste Electrode for Analysis of Butylated Hydroxytoluene Concentration in Lotion by Cyclic Voltammetry

Nur Anisa Rosyiidah; Pirim Setiarso

doi:10.22146/ijc.87398

Nano Titanium(IV) Oxide Modified Carbon Paste Electrode for Analysis of Butylated Hydroxytoluene Concentration in Lotion by Cyclic Voltammetry

https://doi.org/10.22146/ijc.87398

Nur Anisa Rosyiidah⁽¹⁾, Pirim Setiarso^(2*)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Surabaya, Jl. Ketintang, Surabaya 60231, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Surabaya, Jl. Ketintang, Surabaya 60231, Indonesia
(*) Corresponding Author

Abstract

This research focuses on the manufacture and application of TiO₂ NPs modified carbon paste electrodes (TiO₂ NPs-CPE) to analyze butylated hydroxytoluene (BHT) concentration in lotions by cyclic voltammetry. This study aimed to determine the best composition of TiO₂ NPs-CPE, optimal addition of phosphate buffer pH, application of deposition time, and optimal scan rate by cyclic voltammetry. BHT solution was used to determine the electrode with the best conditions so that an optimal voltammogram was obtained at a composition of 3:5:2 electrode (carbon:TiO₂ NPs:paraffin oil), phosphate buffer pH 8, deposition time of 25 s, and scan rate of 100 mV s⁻¹. Obtaining BHT levels of samples A, B, and C with TiO₂ NPs-CPE by cyclic voltammetry were 0.4686, 0.48029, and 0.39044%, while the concentration of samples in HPLC were 0.46873, 0.48111, and 0.39191%. A significance value of 0.985 (> 0.05) was obtained, meaning there was no significant difference in the results of measuring the concentration of BHT in the lotion samples.

Keywords

CPE; TiO2 NPs; butylated hydroxytoluene; cyclic voltammetry

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DOI: https://doi.org/10.22146/ijc.87398