Improving the Performance of Transparent Conducting Electrodes Based on Cu Nanowires

https://doi.org/10.22146/ijc.85156

Dedi Mardiansyah(1*), Sri Rahayu Alfitri Usna(2), Suratun Nafisah(3), Harsojo Harsojo(4), Rindi Genesa Hatika(5)

(1) Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Andalas, Limau Manis, Padang 25163, Indonesia
(2) Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Andalas, Limau Manis, Padang 25163, Indonesia
(3) Department of Electrical Engineering, Institut Teknologi Sumatera, Jl. Terusan Ryacudu, Jati Agung, Lampung 35365, Indonesia
(4) Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara BLS 21, Yogyakarta 55281, Indonesia
(5) Department of Physics Education, Universitas Pasir Pengaraian, Jl. Tuanku Tambusai, Riau 28558, Indonesia
(*) Corresponding Author

Abstract


The fabrication of transparent conducting electrodes (TCEs) is dominated by indium tin oxide (ITO). Some efforts are being made to find alternative materials as a substitute for ITO. Cu nanowire (CuNWs) is an equivalent candidate as a replacement for ITO but has a weakness that is easily oxidized. In this contribution, we report an increase in the performance of CuNWs, which can reduce the effect of oxidation. In this study, we provide a coating of CuNWs using PVP, PVA, and silver nanoparticles (AgNPs). The morphology, formation structure, and conductivity of CuNWs have been investigated by scanning electron microscope (SEM), X-ray diffraction (XRD), and IV meter. The average length and diameter of the CuNWs were 5.5 μm and 120 nm, respectively. The transparent conducting has a stable conductivity after coating with PVP, PVA and AgNPs. The application of transparent conducting electrodes are sensors, electronic devices, solar cells, and organic light-emitting diodes (OLEDs).

Keywords


Cu nanowires; oxidation; coating; transparent conducting electrodes

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References

[1] Yokoyama, S., Nozaki, J., Umemoto, Y., Motomiya, K., Itoh, T., and Takahashi, H., 2021, Flexible and adhesive sintered Cu nanomaterials on polyimide substrates prepared by combining Cu nanoparticles and nanowires with polyvinylpyrrolidone, Colloids Surf., A, 625, 126907.

[2] Kim, M.J., 2023, A study on optimal indium tin oxide thickness as transparent conductive electrodes for near-ultraviolet light-emitting diodes, Materials, 16 (13), 4718.

[3] Mardiansyah, D., Khasanah, D.U., Triyana, K., and Harsojo, H., 2019, Fabrication of copper nanowire coated by silver nanocrystal for protection of oxidation transparent conductive electrode, Mater. Sci. Forum, 948, 243–248.

[4] Ye, S., Rathmell, A.R., Chen, Z., Stewart, I.E., and Wiley, B.J., 2014, Metal nanowire networks: The next generation of transparent conductors, Adv. Mater., 26 (39), 6670–6687.

[5] Li, W., Li, L., Li, F., Kawakami, K., Sun, Q., Nakayama, T., Liu, X., Kanehara, M., Zhang, J., and Minari, T., 2022, Self-organizing, environmentally stable, and low-cost copper-nickel complex inks for printed flexible electronics, ACS Appl. Mater. Interfaces, 14 (6), 8146–8156.

[6] Badawi, A., Alharthi, S.S., Althobaiti, M.G., and Alharbi, A.N., 2021, Structure investigation and optical bandgap tuning of La-doped CuO nanostructured films prepared by spray pyrolysis technique, Appl. Phys. A, 127 (4), 235.

[7] Song, S.M., and Cho, S.M., 2022, Copper ion inks capable of screen printing and intense pulsed-light sintering on PET substrates, ACS Appl. Electron. Mater., 4 (4), 1882–1890.

[8] Yang, L., Xu, X., Yuan, Y., Li, Z., and He, S., 2019, Meter-scale transparent conductive circuits based on silver nanowire networks for rigid and flexible transparent light-emitting diode screens, Opt. Mater. Express, 9 (12), 4483–4496.

[9] Gerlein, L.F., Benavides-Guerrero, J.A., and Cloutier, S.G., 2021, High-performance silver nanowires transparent conductive electrodes fabricated using manufacturing-ready high-speed photonic sinterization solutions, Sci. Rep., 11 (1), 24156.

[10] Chen, G., Bi, L., Yang, Z., Chen, L., Wang, G., and Ye, C., 2019, Water-based purification of ultrathin silver nanowires toward transparent conductive films with a transmittance higher than 99%, ACS Appl. Mater. Interfaces, 11, (25), 22648–22654.

[11] Wang, P., Jian, M., Wu, M., Zhang, C., Zhou, C., Ling, X., Zhang, J., and Yang, L., 2022, Highly sandwich-structured silver nanowire hybrid transparent conductive films for flexible transparent heater applications, Composites, Part A, 159, 106998.

[12] Pham, S.H., Ferri, A., Da Costa, A., Mohan, M.M.S., Tran, V.D., Nguyen, D.C., Viville, P., Lazzaroni, R., Desfeux, R., and Leclère, P., 2022, Nanoscale electrical investigation of transparent conductive electrodes based on silver nanowire network, Adv. Mater. Interfaces, 9 (18), 2200019.

[13] Tokura, R., Tsukamoto, H., Tokunaga, T., Nguyen, M.T., and Yonezawa, T., 2022, The role of surface oxides and stabilising carboxylic acids of copper nanoparticles during low-temperature sintering, Mater. Adv., 3 (12), 4802–4812.

[14] Mardiansyah, D., Triyana, K., Sosiati, H., and Harsojo, H., 2016, Synthesis of copper nanorods by aqueous solution method without heating external, AIP Conf. Proc., 1755 (1), 150019.

[15] Mardiansyah, D., Triyana, K., and Harsojo, H., 2016, Effect of precursor molar ratio on the yield of Cu nanowires synthesized using aqueous solution method, Int. J. Adv. Sci. Eng. Inf., 6 (4), 447–450.

[16] Song, Y., Qu, X., Li, X., Huang, F., Li, S., Duan, Y., Dong, X., and Li, P., 2022, Structural regulation of carbon-coated Cu nanocapsules as thermally stable microwave absorbers, J. Mater. Sci., 57 (25), 11735–11747.

[17] Pinto, R.J.B., Martins, M.A., Lucas, J.M.F., Vilela, C., Sales, A.J.M., Costa, L.C., Marques, P.A.A.P., and Freire, C.S.R., 2020, Highly electroconductive nanopapers based on nanocellulose and copper nanowires: A new generation of flexible and sustainable electrical materials, ACS Appl. Mater. Interfaces, 12 (30), 34208–34216.

[18] Mardiansyah, D., Badloe, T., Triyana, K., Mehmood, M.Q., Raeis-Hosseini, N., Lee, Y., Sabarman, H., Kim, K., and Rho, J., 2018, Effect of temperature on the oxidation of Cu nanowires and development of an easy to produce, oxidation-resistant transparent conducting electrode using a PEDOT:PSS coating, Sci. Rep., 8 (1), 10639.

[19] Claros, M., Gràcia, I., Figueras, E., and Vallejos, S., 2022, Hydrothermal synthesis and annealing effect on the properties of gas-sensitive copper oxide nanowires, Chemosensors, 10 (9), 353.

[20] Mardiansyah, D., Triyana, K., and Harsojo, H., 2019, Study on growth mechanism of cu nanowires and its application as transparent conducting electrode, Indones. J. Chem., 19 (1), 160–165.

[21] Wang, R., and Ruan, H., 2016, Synthesis of copper nanowires and its application to flexible transparent electrode, J. Alloys Compd., 656, 936–943.

[22] Lah, N.A.C., and Trigueros, S., 2019, Synthesis and modelling of the mechanical properties of Ag, Au and Cu nanowires, Sci. Technol. Adv. Mater., 20 (1), 225–261.

[23] Mock, J., Bobinger, M., Bogner, C., Lugli, P., and Becherer, M., 2018, Aqueous synthesis, degradation, and encapsulation of copper nanowires for transparent electrodes, Nanomaterials, 8 (10), 767.

[24] Wang, X., Wang, R., Shi, L., and Sun, J., 2018, Kinetically controlled synthesis of Cu nanowires with tunable diameters and their applications in transparent electrodes, J. Mater. Chem. C, 6, 1048–1056.

[25] Sun, Y., Du, C., Wu, M., Zhao, L., Yu, S., Gong, B., and Ding, Q., 2020, Synchronously improved reliability, figure of merit and adhesion of flexible copper nanowire networks by chitosan transition, Nanotechnology, 31 (37), 375303.

[26] Tran, N.H., Tran, P., and Lee, J.H., 2022, Copper nanowire-sealed titanium dioxide/poly (dimethylsiloxane) electrode with an in-plane wavy structure for a stretchable capacitive strain sensor, ACS Appl. Nano Mater., 5 (5), 7150–7160.

[27] Li, X., Wang, Y., Yin, C., and Yin, Z., 2020, Copper nanowires in recent electronic applications: Progress and perspectives, J. Mater. Chem. C, 8 (3), 849–872.

[28] Tong, X., Hu, H., Zhao, X., and Tai, Q., 2022, In situ carbon coating for enhanced chemical stability of copper nanowires, Int. J. Miner., Metall. Mater., 29 (3), 557–562.

[29] Lin, Y.T., Huang, D.W., Huang, P.F., Chang, L.C., Lai, Y.T., and Tai, N.H., 2022, A green approach for high oxidation resistance, flexible transparent conductive films based on reduced graphene oxide and copper nanowires, Nanoscale Res. Lett., 17 (1), 79.

[30] Thekkekara, L.V., Jason, N.N., Cheng, W., and Gu, M., 2019, Stable copper nanowire-graphene oxide thin films for nonlinear photonics, OSA Continuum, 2 (4), 1455–1467.



DOI: https://doi.org/10.22146/ijc.85156

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