* Corresponding Author
Adsorption of Malachite Green Oxalate Dye by CuCo2O4/MgO Spinel Oxide Nanocomposite
https://doi.org/10.22146/ijc.83850 Tariq Hussein Mgheer(1), Ali Abdulraheem Kadhim(2*), Zainab Abdalameer Hussein(3), Zaid Kaheel Kadhim(4), Muneer Abdul Aly Al-Da’amy(5), Abbas Jassim Atiyah(6), Salih Hadi Kadhim(7), Suma Jaafar Abbas(8)
(1) Department of Chemistry and Biochemistry, College of Medicine, University of Babylon, Hilla 51002, Iraq
(2) Department of Animal Production, College of Agriculture, University of Kerbala, Karbala 56001, Iraq
(3) Department of Plant Protection, College of Agriculture, University of Kerbala, Karbala 56001, Iraq
(4) Department of Horticulture and Landscape, College of Agriculture, University of Kerbala, Karbala 56001, Iraq
(5) Department of Chemistry, College of Pure Science for Education, University of Kerbala, Karbala 56001, Iraq
(6) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(7) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(8) Department of Plant Protection, College of Agriculture, University of Kerbala, Karbala 56001, Iraq
(*) Corresponding Author
Abstract
The current study involves a synthesis of a composite of copper oxide and cobalt oxide as a spinel oxide load over magnesium oxide. This synthesis of nanocomposite material was from nitrate salts of the corresponding metals by co-precipitation method, while it was investigated by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction techniques (XRD), field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), and the activity of these materials was estimated by appreciated adsorption of malachite green oxalate (MGO) dye from its aqueous solution. Adsorption isotherm was investigated using both Freundlich and Langmuir adsorption isotherms. While the results of the spectrophotometric studies showed that the composition of synthesized supported oxides at 450 °C was spinel type with nanoparticle size, and the optimum removal efficiency was around 98% for the adsorption of MGO dye over spinel nanocomposite surface achieved by using a dye concentration of 5 ppm, a mass of adsorbent surface of 5 mg, in terms of the adsorption model's isotherms the obtained results showed that the removal of MGO dye by the surface of this material was more fitted with the Freundlich models' adsorption.
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[1] Farag, N.M., Deyab, M.A., El-naggar, A.M., Aldhafiri, A.M., Mohamed, M.B., and Heiba, Z.K., 2021, Exploring the functional properties of CuCo2O4/CuS nanocomposite as improved material for supercapacitor electrode, J. Mater. Res. Technol., 10, 1415–1426.
[2] Qiao, X., Geng, W., Sun, Y., Zheng, D., Yang, Y., Meng, J., He, J., Bi, K., Cui, M., and Chou, X., 2021, Robust in-plane polarization switching in epitaxial BiFeO3 films, J. Alloys Compd., 852, 156988.
[3] Mohamad, E.J., 2015, Comparative Study to Synthesis and Characterization the Catalyst Ni3O4-Co3O4-Al2O3 and Usage in Photooxidation and Adsorption of Removal of Reactive Yellow145 and Bismarck Brown G Dyes, Thesis, University of Babylon, Iraq.
[4] Sun, J., Xu, C., and Chen, H., 2021, A review on the synthesis of CuCo2O4-based electrode materials and their applications in supercapacitors, J. Materiomics, 7 (1), 98–126.
[5] Al-samaray, H.S., 2018, Study the Removal of Celestine Blue Dye from Their Aqueous Solutions by Adsorption over the Mixed Oxide NiO-MgO Pure and Doped, Thesis, University of Babylon, Iraq.
[6] Dhara, K., and Debiprosad, R.M., 2019, Review on nanomaterials-enabled electrochemical sensors for ascorbic acid detection, Anal. Biochem., 586, 113415.
[7] Ismael, H.A., Mohammad, E.J., Atiyah, A.J., Kadhim, S.H., and Kahdum, K.J., 2021, Synthesis and characteristic study of composite zinc oxide and functionalized activated carbon with investigation of its adsorption ability: A kinetic study, IOP Conf. Ser.: Earth Environ. Sci., 722, 012007.
[8] Ahmadian, A., Bilal, M., Khan, M.A., and Asjad, M.I., 2020, Numerical analysis of thermal conductive hybrid nanofluid flow over the surface of a wavy spinning disk, Sci. Rep., 10 (1), 18776.
[9] Kadhim, N.J., Mousa, S.A., Muhammed, E.A., and Farhan, A.M., 2020, A comparative study of the adsorption of crystal violet dye from aqueous solution on rice husk and charcoal, Baghdad Sci. J., 17 (1), 295–304.
[10] Hussein, Z.A., Alazawy, R.A., and Haddawi, S.M., 2020, Adsorption of 2,6-dichlorophenol-indophenol sodium dihydrate salt from aqueous solutions using nano magnesium oxide; A thermodynamic study, Egypt. J. Chem., 63 (10), 4157–4161.
[11] Al-Abadi, S.I., Al-Da’Amy, M.A., and Kareem, E.T., 2021, Thermodynamic study for removing of crystal violet dye on Iraqi porcelanite rocks powder, IOP Conf. Ser.: Earth Environ. Sci., 790, 012055.
[12] Arora, C., Kumar, P., Soni, S., Mittal, J., Mittal, A., and Singh, B., 2020, Efficient removal of malachite green dye from aqueous solution using curcuma caesia based activated carbon, Desalin. Water Treat., 195, 341–352.
[13] Sharma, G., ALOthman, Z.A., Kumar, A., Sharma, S., Ponnusamy, S.K., and Naushad, M., 2017, Fabrication and characterization of a nanocomposite hydrogel for combined photocatalytic degradation of a mixture of malachite green and fast green dye, Nanotechnol. Environ. Eng., 2 (1), 4.
[14] Ali, L.A.M., Farhood, A.S., and Ali, F.F., 2017, Technique of batch adsorption for the elimination of (malachite green) dye from industrial waste water by exploitation walnut shells as sorbent, Indones. J. Chem., 17 (2), 211–218.
[15] Janjua, M.R.S.A., 2019, Synthesis of Co3O4 nano aggregates by co-precipitation method and its catalytic and fuel additive applications, Open Chem., 17 (1), 865–873.
[16] Thahy, R.R.A., 2018, Synthesis and Identification of Co3O4·Fe3O4/MxOx,MxOx+1 where (M= Ca, Mg, Al, Ce) Spinel Supported Catalyst and Using It Removal of Bismarck Brown G Dye, Thesis, University of Babylon, Iraq.
[17] Kadhim, S.H., Kadhim, A.A., Al-Da’amy, M.A., and Kadhim, S.H., 2023, Synthesis of CuCo2O4-MgO spinel composite as an adsorbent surface for removal of celestine blue B dye, AIP Conf. Proc., 2830 (1), 70034.
[18] Hicham, A., Hussein, J., and Siba, H., 2022, Kinetic, isotherm and thermodynamic studies on the ciprofloxacin adsorption from aqueous solution using Aleppo bentonite, Baghdad Sci. J., 19 (3), 680–692.
[19] AL-Khazali, N.A.Y., 2017, Study Removal Remazol Brilliant Blue and Malachite Green Dyes from Aqueous Solutions Using Iraqi Porcelanite Rocks and Modified, Thesis, University of Kerbala, Iraq.
[20] Farhan, A.M., Zaghair, A.M., and Abdullah, H.I., 2022, Adsorption study of Rhodamine–B dye on plant (citrus leaves), Baghdad Sci. J., 19 (4), 838–847.
[21] Das, A.K., Kim, N.H., Lee, S.H., Sohn, Y., and Lee, J.H., 2018, Facile synthesis of CuCo2O4 composite octahedrons for high performance supercapacitor application, Composites, Part B, 150, 269–276.
[22] Devaraja, P.B., Avadhani, D.N., Prashantha, S.C., Nagabhushana, H., Sharma, S.C., Nagabhushana, B.M., and Nagaswarupa, H.P., 2014, Synthesis, structural and luminescence studies of magnesium oxide nanopowder, Spectrochim. Acta, Part A, 118, 847–851.
[23] Sudha, V., Annadurai, K., Kumar, S.M.S., and Thangamuthu, R., 2019, CuCo2O4 Nanobricks as electrode for enhanced electrochemical determination of hydroxylamine, Ionics, 25 (10), 5023–5034.
[24] Petrov, K., Krezhov, K., and Konstantinov, P., 1989, Neutron diffraction study of the cationic distribution in CuxCo3–xO4 (0<x⩽1.0) spinels prepared by thermal decomposition of layered hydroxide nitrate precursors, J. Phys. Chem. Solids, 50 (6), 577–581.
[25] Dana, J.D., 2022, A System of Mineralogy, Wiley, New Jersey, US.
[26] Helmy, Q., Notodarmojo, S., Aruan, I.A., and Apriliawati, R., 2017, Removal of color and chemical oxygen demand from textile wastewater using advanced oxydation process (AOPs), IPTEK J. Proc. Ser., 3 (6), 474–481.
[27] Bonilla-Petriciolet, A., Mendoza-Castillo, D.I., and Reynel-Ávila, H.E., 2017, Adsorption Processes for Water Treatment and Purification, Springer, Cham, Switzerland.
[28] Abdul-aziz Umar, S., and Gaya, U.I., 2019, Optimised photocatalytic degradation of crystal violet over 1wt% MgO-ZnO composite catalyst, J. Sci. Technol., 11 (1), 25–33.
[29] Obaid, S.A., 2020, Langmuir, Freundlich and Tamkin adsorption isotherms and kinetics for the removal Aartichoke Tournefortii straw from agricultural waste, J Phys Conf Ser, 1664, 012011.
[30] Chafat, A.H., Al-Da’amy, M.A., and Kareem, E.T., 2023, Iraqi porcelanite rocks for efficient removal of safranin dye from aqueous solution, Baghdad Sci. J., 20 (2), 434–441.
[31] Shamsizadeh, A., Ghaedi, M., Ansari, A., Azizian, S., and Purkait, M.K., 2014, Tin oxide nanoparticle loaded on activated carbon as new adsorbent for efficient removal of malachite green-oxalate: Non-linear kinetics and isotherm study, J. Mol. Liq., 195, 212–218.
[32] Mohamad Zaidi, N.A.H., Lim, L.B.L., and Usman, A., 2019, Enhancing adsorption of malachite green dye using base-modified Artocarpus odoratissimus leaves as adsorbents, Environ. Technol. Innovation, 13, 211–223.
[33] Brião, G.V., Jahn, S.L., Foletto, E.L., and Dotto, G.L., 2018, Highly efficient and reusable mesoporous zeolite synthetized from a biopolymer for cationic dyes adsorption, Colloids Surf., A, 556, 43–50.
[34] Hussein, Z.A., Haddawi, S.M., and Kadhim, A.A., 2019, Study of thermodynamic variables to adsorption of aldomete drug (methyldopa) from its water solution on the nano zinc oxide surface, Int. J. Pharm. Qual. Assur., 10 (2), 315–321.
[35] Fouda, A., Hassan, S.E.D., Abdel-Rahman, M.A., Farag, M.M.S., Shehal-deen, A., Mohamed, A.A., Alsharif, S.M., Saied, E., Moghanim, S.A., and Azab, M.S., 2021, Catalytic degradation of wastewater from the textile and tannery industries by green synthesized hematite (α-Fe2O3) and magnesium oxide (MgO) nanoparticles, Curr. Res. Biotechnol., 3, 29–41.
[36] Kadhim, S.H., Mgheer, T.H., Ismael, H.I., Kadem, K.J., Abbas, A.S., Atiyah, A.J., and Mohamad, I.J., 2019, Synthesis, characterization and catalytic activity of NiO-CoO-MgO nano-composite catalyst, Indones. J. Chem., 19 (3), 675–683.
[37] Mustikaningrum, M., Cahyono, R.B., and Yuliansyah, A.T., 2022, Adsorption of methylene blue on nano-crystal cellulose of oil palm trunk: Kinetic and thermodynamic studies, Indones. J. Chem., 22 (4), 953–964.
DOI: https://doi.org/10.22146/ijc.83850
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