* Corresponding Author
Removal of Methyl Orange Using Nanocomposites Based on Polyaniline/Nb2O5/MnO2 and Polyaniline/Nb2O5/Cr2O3 as New Adsorbents
https://doi.org/10.22146/ijc.82417 Karrar Majeed Obaid(1), Ahmed Saadoon Abbas(2), Yahya Fahim Al-Khafaji(3*)
(1) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(2) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(3) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(*) Corresponding Author
Abstract
Dyes are the most widely employed materials for coloring applications, especially for industrial purposes; thus, dyes are applied in the textile, cosmetics and foodstuffs. Dyes are very important owing to their applications in all aspects of human life. Accordingly, the production volume of dyes around the world is increasing. In this study, a new type of multifunctional material: polyaniline/Nb2O5/MnO2 and polyaniline/Nb2O5/Cr2O3 nanocomposites, was prepared by chemical polymerization from aniline monomer in the presence of metal oxides (Nb2O5, Cr2O3, and MnO2) and an oxidant (ammonium persulfate) in acidic aqueous solution for the elimination of dye from water. Herein, the nanocomposite was found to be a favorable adsorbent for wastewater treatment due to its high adsorption and efficiency, self-regeneration quality, low cost and easy synthesis. Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy and UV-visible spectroscopy were used to assess the synthesized nanocomposites' characteristics. From the results, we discovered that polyaniline nanocomposites doped with Nb2O5 and MnO2 nanoparticles had a higher adsorption efficiency (~97.37%) than those found in polyaniline with Cr2O3 and MnO2 (~94.3%). We looked at the adsorption conditions, including the medium's pH, the initial dye concentration, the dosage of the adsorbent, and the adsorption time.
Keywords
References
[1] Merdan, M., Jalal Al-den Fakar Al-den, D., Al-khafaji, Y., and Abbas, A.S., 2019, Theoretical study for chromen azodyes derivative compounds as anti-corrosive, J. Phys.: Conf. Ser., 1234, 012054.
[2] Xiao, Y., and Hill, J.M., 2018, Benefit of hydrophilicity for adsorption of methyl orange and electro-Fenton regeneration of activated carbon-polytetrafluoroethylene electrodes, Environ. Sci. Technol., 52 (20), 11760–11768.
[3] Sánchez-Sánchez, Á., Suárez-García, F., Martínez-Alonso, A., and Tascón, J.M.D., 2015, Synthesis, characterization and dye removal capacities of N-doped mesoporous carbons, J. Colloid Interface Sci., 450, 91–100.
[4] Huang, R., Liu, Q., Huo, J., and Yang, B., 2017, Adsorption of methyl orange onto protonated cross-linked chitosan, Arabian J. Chem., 10 (1), 24–32.
[5] Serban, G.V., Iancu, V.I., Dinu, C., Tenea, A., Vasilache, N., Cristea, I., Niculescu, M., Ionescu, I., and Chiriac, F.L., 2023, Removal efficiency and adsorption kinetics of methyl orange from wastewater by commercial activated carbon, Sustainability, 15 (17), 12939.
[6] Gapusan, R.B., and Balela, M.D.L., 2020, Adsorption of anionic methyl orange dye and lead(II) heavy metal ion by polyaniline-kapok fiber nanocomposite, Mater. Chem. Phys., 243, 122682.
[7] Jianjun, H., Yuping, D., Jia, Z., Hui, J., Shunhua, L., and Weiping, L., 2011, γ-MnO2/polyaniline composites: Preparation, characterization, and applications in microwave absorption, Phys. B, 406, 1950–1955.
[8] Shahabuddin, S., Sarih, N.M., Mohamad, S., and Atika Baharin, S.N., 2016, Synthesis and characterization of Co3O4 nanocube-doped polyaniline nanocomposites with enhanced methyl orange adsorption from aqueous solution, RSC Adv., 6 (49), 43388–43400.
[9] Zhao, Y., Chen, H., Li, J., and Chen, C., 2015, Hierarchical MWCNTs/Fe3O4/PANI magnetic composite as adsorbent for methyl orange removal, J. Colloid Interface Sci., 450, 189–195.
[10] Asuha, S., Zhou, X., and Zhao, S., 2010, Adsorption of methyl orange and Cr(VI) on mesoporous TiO2 prepared by hydrothermal method, J. Hazard. Mater., 181 (1), 204–210.
[11] Mohammadi, N., Khani, H., Gupta, V.K., Amereh, E., and Agarwal, S., 2011, Adsorption process of methyl orange dye onto mesoporous carbon material–kinetic and thermodynamic studies, J. Colloid Interface Sci., 362 (2), 457–462.
[12] Zeng, A., and Zeng, A., 2017, Synthesis of a quaternized beta cyclodextrin-montmorillonite composite and its adsorption capacity for Cr(VI), methyl orange, and p-nitrophenol, Water, Air, Soil Pollut., 228 (8), 278.
[13] Llorens, E., Armelin, E., Del Mar Pérez-Madrigal, M., Del Valle, L.J., Alemán, C., and Puiggalí, J., 2013, Nanomembranes and nanofibers from biodegradable conducting polymers, Polymers, 5 (3), 1115–1157.
[14] Alesary, H.F., Ismail, H.K., Khudhair, A.F., and Mohammed, M.Q., 2018, Effects of dopant ions on the properties of polyaniline conducting polymer, Orient. J. Chem., 34 (5), 2525.
[15] Ismail, H.K., Alesary, H.F., Al-Murshedi, A.Y.M., and Kareem, J.H., 2019, Ion and solvent transfer of polyaniline films electrodeposited from deep eutectic solvents via EQCM, J. Solid State Electrochem., 23 (11), 3107–3121.
[16] Bian, L.J., He, H.L., and Liu, X.X., 2015, Self-doped polyaniline/molybdenum oxide composite nanorods for supercapacitors, RSC Adv., 5 (92), 75374–75379.
[17] Bakhtiarian, E., Foot, P.J., and Tate, P.C.M., 2016, Conductive poly(epichlorhydrin)–polyaniline dodecylbenzenesulfonate [PECH-PAni.DBSA] rubber blends prepared in solution, Prog. Rubber Plast. Recycl. Technol., 32 (4), 183–200.
[18] Shahabuddin, S., Muhamad Sarih, N., Mohamad, S., and Joon Ching, J., 2016, SrtiO3 nanocube-doped polyaniline nanocomposites with enhanced photocatalytic degradation of methylene blue under visible light, Polymers, 8 (2), 27.
[19] Cai, X., Cui, X., Zu, L., Zhang, Y., Gao, X., Lian, H., Liu, Y., and Wang, X., 2017, Ultra high electrical performance of nano nickel oxide and polyaniline composite materials, Polymers, 9 (7), 288.
[20] Wu, T.M., Lin, Y.W., and Liao, C.S., 2005, Preparation and characterization of polyaniline/multi-walled carbon nanotube composites, Carbon, 43 (4), 734–740.
[21] Inzelt, G., 2012, Conducting Polymers: A New Era in Electrochemistry, Springer Berlin, Heidelberg.
[22] Abd Ali, L., Ismail, H.K., Alesary, H.F., and Aboul-Enein, H., 2021, A nanocomposite based on polyaniline, nickel and manganese oxides for dye removal from aqueous solutions, Int. J. Environ. Sci. Technol., 18 (7), 2031–2050.
[23] Mylarappa, M., Chandruvasan, S., Kantharaju, S., and Rekha, S., 2022, Synthesis and characterization of Rgo doped Nb2O5 nano composite for chemical sensor studies, ECS Trans., 107, 269.
[24] Dessie, Y., Tadesse, S., and Eswaramoorthy, R., 2021, Surface roughness and electrochemical performance properties of biosynthesized α-MnO2/NiO-based polyaniline ternary composites as efficient catalysts in microbial fuel cells, J. Nanomater., 2021, 7475902.
[25] Taş, R., Can, M., and Sönmezoğlu, S., 2015, Preparation and characterization of polyaniline microrods synthesized by using dodecylbenzene sulfonic acid and periodic acid, Turk. J. Chem., 39 (3), 589–599.
[26] Djara, R., Holade, Y., Merzouki, A., Masquelez, N., Cot, D., Rebière, B., Petit, E., Huguet, P., Canaff, C., Morisset, S., Napporn, T.W., Cornu, D., and Tingry, S., 2020, Insights from the physicochemical and electrochemical screening of the potentiality of the chemically synthesized polyaniline, J. Electrochem. Soc., 167 (6), 066503.
[27] Fuseini, M., El Shazly, A.H., and El-Kady, M.F., 2020, Effects of doping on zeta potential and pH of polyaniline colloidal suspension, Mater. Sci. Forum, 1008, 114–120.
[28] Nawrocki, J., 1997, The silanol group and its role in liquid chromatography, J. Chromatogr. A, 779 (1), 29–71.
[29] Shahabuddin, S., Gaur, R., Mukherjee, N., Chandra, P., and Khanam, R., 2022, Conducting polymers-based nanocomposites: Innovative materials for waste water treatment and energy storage, Mater. Today: Proc., 62, 6950–6955.
[30] Ansari, R., and Mosayebzadeh, Z., 2011, Application of polyaniline as an efficient and novel adsorbent for azo dyes removal from textile wastewaters, Chem. Pap., 65 (1), 1–8.
[31] Nasar, A., and Mashkoor, F., 2019, Application of polyaniline-based adsorbents for dye removal from water and wastewater—A review, Environ. Sci. Pollut. Res., 26 (6), 5333–5356.
[32] Harimu, L., Wahyuni, S., Nasrudin, N., Baari, M.J., and Permana, D., 2022, Fabrication of chitosan/Fe3O4 nanocomposite as adsorbent for reduction methylene blue contents, Indones. J. Chem., 22 (3), 878–886.
[33] Karri, R.R., Tanzifi, M., Tavakkoli Yaraki, M., and Sahu, J., 2018, Optimization and modeling of methyl orange adsorption onto polyaniline nano-adsorbent through response surface methodology and differential evolution embedded neural network, J. Environ. Manage., 223, 517–529.
[34] Al-Ghouti, M.A., and Da'ana, D.A., 2020, Guidelines for the use and interpretation of adsorption isotherm models: A review, J. Hazard. Mater., 393, 122383.
[35] Ibrahim, R.K., El-Shafie, A., Hin, L.S., Mohd, N.S., Aljumaily, M.M., Ibraim, S., and AlSaadi, M.A., 2019, A clean approach for functionalized carbon nanotubes by deep eutectic solvents and their performance in the adsorption of methyl orange from aqueous solution, J. Environ. Manage., 235, 521–534.
[36] Elwakeel, K., El-Bindary, A., Ismail, A., and Morshidy, A., 2017, Magnetic chitosan grafted with polymerized thiourea for remazol brilliant blue R recovery: Effects of uptake conditions J. Dispersion Sci. Technol., 38 (7), 943–952.
[37] Manzar, M.S., Waheed, A., Qazi, I.W., Blaisi, N.I., and Ullah, N., 2019, Synthesis of a novel epibromohydrin modified crosslinked polyamine resin for highly efficient removal of methyl orange and eriochrome black T, J. Taiwan Inst. Chem. Eng., 97, 424–432.
[38] Elwakeel, K.Z., El-Bindary, A., El-Sonbati, A., and Hawas, A.R., 2017, Magnetic alginate beads with high basic dye removal potential and excellent regeneration ability, Can. J. Chem., 95 (8), 807–815.
[39] Sharifpour, E., Alipanahpour Dil, E., Asfaram, A., Ghaedi, M., and Goudarzi, A., 2019, Optimizing adsorptive removal of malachite green and methyl orange dyes from simulated wastewater by Mn‐doped CuO‐nanoparticles loaded on activated carbon using CCD‐RSM: Mechanism, regeneration, isotherm, kinetic, and thermodynamic studies, Appl. Organomet. Chem., 33 (3), e4768.
[40] Pete, S., Kattil, R.A., and Thomas, L., 2021, Polyaniline-multiwalled carbon nanotubes (PANI-MWCNTs) composite revisited: An efficient and reusable material for methyl orange dye removal, Diamond Relat. Mater., 117, 108455.
[41] Bekhoukh, A., Moulefera, I., Zeggai, F.Z., Benyoucef, A., and Bachari, K., 2022, Anionic methyl orange removal from aqueous solutions by activated carbon reinforced conducting polyaniline as adsorbent: synthesis, characterization, adsorption behavior, regeneration and kinetics study, J. Polym. Environ., 30 (3), 886–895.
[42] Tran, K.N.T., Phan, C.P.K., Ho, V.T., Chau, H.D., and Nguyen, T.N.D., 2023, Adsorption of methyl orange dyes on oriented Co/Fe-MOF bimetallic organic framework in wastewater treatment, Indones. J. Chem., 23 (2), 533–541.
[43] Mohammadi, R., Massoumi, B., and Galandar, F., 2019, Polyaniline-TiO2/graphene nanocomposite: An efficient catalyst for the removal of anionic dyes, Desalin. Water Treat., 142, 321–330.
DOI: https://doi.org/10.22146/ijc.82417
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