Effect of Activated Carbon Particle Size on Methylene Blue Adsorption Process in Textile Wastewater


Akhmad Masykur Hadi Musthofa(1*), Mindriany Syafila(2), Qomarudin Helmy(3)

(1) Department of Environmental Engineering, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung 40132, West Java, Indonesia
(2) Water and Wastewater Engineering Research Group, Faculty of Civil and Environmental Engineering, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung 40132, West Java, Indonesia
(3) Water and Wastewater Engineering Research Group, Faculty of Civil and Environmental Engineering, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung 40132, West Java, Indonesia
(*) Corresponding Author


Up to 60–70% of the total textile dyes produced are azo dyes. An example of azo dye is methylene blue, which is commonly used in dyeing wool, silk, and cotton. This substance possessed harmful effects on the environment. Therefore, the removal process is mandatory. The adsorption process is a common method for dye removal in wastewater. One innovation to increase adsorption efficiency even further is by reducing adsorbent particle size. To understand the effect of adsorbent particle size on the adsorption process, in this study, granular activated carbon (GAC) was pulverized into powder (PAC) and superfine powder (SPAC). Adsorbent characterizations, isotherm, kinetics, and thermodynamics tests were conducted. Based on this study, surface area, pore volume, and adsorption capacity were increased for smaller adsorbent particle sizes. Isotherm and kinetic analysis showed that there was no difference in the isotherm and kinetic models that applied to each activated carbon, but there was an increase in the isotherm and kinetic coefficient values at smaller particle sizes. Meanwhile, based on the thermodynamic test, there were differences in the dominant adsorption mechanism for each activated carbon. In GAC and SPAC, the dominant adsorption mechanism was electrostatic interactions, while in PAC was van der Waals forces.


activated carbon; adsorption; methylene blue; superfine powdered activated carbon

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[1] Kant, R., 2012, Textile dyeing industry an environmental hazard, Nat. Sci., 4 (1), 22–26.

[2] Ghaly, A.E., Ananthashankar, R., Alhattab, M., and Ramakrishna, V.V., 2013, Production, characterization and treatment of textile effluents: A critical review, J. Chem. Eng. Process Technol., 5 (1), 1000182.

[3] Velusamy, S., Roy, A., Sundaram, S., and Kumar Mallick, T., 2021, A review on heavy metal ions and containing dyes removal through graphene oxide-based adsorption strategies for textile wastewater treatment, Chem. Rec., 21 (7), 1570–1610.

[4] Balapure, K., Bhatt, N., and Madamwar, D., 2015, Mineralization of reactive azo dyes present in simulated textile waste water using down flow microaerophilic fixed film bioreactor, Bioresour. Technol., 175, 1–7.

[5] Fatkhasari, Y., Rouf, N.A., Ermadayanti, W.A., Kurniawan, R.Y., and Bagastyo, A.Y., 2019, Synthesis of TiO2/zeolite-A composite for the removal of methylene blue on direct sunlight, Jurnal Teknik ITS, 8 (2), 115–120.

[6] Giraldo, S., Robles, I., Godínez, L.A., Acelas, N., and Flórez, E., 2021, Experimental and theoretical insights on methylene blue removal from wastewater using an adsorbent obtained from the residues of the orange industry, Molecules, 26 (15), 4555.

[7] Saratale, R.G., Saratale, G.D., Chang, J.S., and Govindwar, S.P., 2011, Bacterial decolorization and degradation of azo dyes: A review, J. Taiwan Inst. Chem. Eng., 42 (1), 138–157.

[8] Dutta, S., Gupta, B., Srivastava, S.K., and Gupta, A.K., 2021, Recent advances on the removal of dyes from wastewater using various adsorbents: A critical review, Mater. Adv., 2 (14), 4497–4531.

[9] Sultana, M., Rownok, M.H., Sabrin, M., Rahaman, M.H., and Alam, S.M.N., 2022, A review on experimental chemically modified activated carbon to enhance dye and heavy metals adsorption, Cleaner Eng. Technol., 6, 100382.

[10] Zhang, Z., Xu, L., Liu, Y., Feng, R., Zou, T., Zhang, Y., Kang, Y., and Zhou, P., 2021, Efficient removal of methylene blue using the mesoporous activated carbon obtained from mangosteen peel wastes: Kinetic, equilibrium, and thermodynamic studies, Microporous Mesoporous Mater., 315, 110904.

[11] Sun, X., Ma, L., Ye, G., Wu, L., Li, J., Xu, H., and Huang, G., 2021, Phenol adsorption kinetics and isotherms on coal: Effect of particle size, Energy Sources, Part A, 43 (4), 461–474.

[12] Partlan, E., 2017, Superfine Powdered Activated Carbon (S-PAC) Coupled with Microfiltration for the Removal of Trace Organics in Drinking Water Treatment, Dissertation, Clemson University, South Carolina.

[13] Takaesu, H., Matsui, Y., Nishimura, Y., Matsushita, T., and Shirasaki, N., 2019, Micro-milling super-fine powdered activated carbon decreases adsorption capacity by introducing oxygen/hydrogen-containing functional groups on carbon surface from water, Water Res., 155, 66–75.

[14] Pan, L., Nishimura, Y., Takaesu, H., Matsui, Y., Matsushita, T., and Shirasaki, N., 2017, Effects of decreasing activated carbon particle diameter from 30 μm to 140 nm on equilibrium adsorption capacity, Water Res., 124, 425–434.

[15] Matsui, Y., Nakao, S., Sakamoto, A., Taniguchi, T., Pan, L., Matsushita, T., and Shirasaki, N., 2015, Adsorption capacities of activated carbons for geosmin and 2-methylisoborneol vary with activated carbon particle size: Effects of adsorbent and adsorbate characteristics, Water Res., 85, 95–102.

[16] Shi, B., Fang, L., Li, Z., and Wang, D., 2014, Adsorption behavior of DOM by PACs with different particle sizes, CLEAN – Soil, Air, Water, 42 (10), 1363–1369.

[17] Partlan, E., Ren, Y., Apul, O.G., Ladner, D.A., and Karanfil, T., 2020, Adsorption kinetics of synthetic organic contaminants onto superfine powdered activated carbon, Chemosphere, 253, 126628.

[18] Matsui, Y., Ando, N., Yoshida, T., Kurotobi, R., Matsushita, T., and Ohno, K., 2011, Modeling high adsorption capacity and kinetics of organic macromolecules on super-powdered activated carbon, Water Res., 45 (4), 1720–1728.

[19] Bonvin, F., Jost, L., Randin, L., Bonvin, E., and Kohn, T., 2016, Super-fine powdered activated carbon (SPAC) for efficient removal of micropollutants from wastewater treatment plant effluent, Water Res., 90, 90–99.

[20] Khalil, K.M.S., Elhamdy, W.A., Mohammed, K.M.H., and Said, A.E.A.A., 2022, Nanostructured P-doped activated carbon with improved mesoporous texture derived from biomass for enhanced adsorption of industrial cationic dye contaminants, Mater. Chem. Phys., 282, 125881.

[21] Aljeboree, A.M., Alshirifi, A.N., and Alkaim, A.F., 2017, Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon, Arabian J. Chem., 10, S3381–S3393.

[22] Medhat, A., El-Maghrabi, H.H., Abdelghany, A., Abdel Menem, N.M., Raynaud, P., Moustafa, Y.M., Elsayed, M.A., and Nada, A.A., 2021, Efficiently activated carbons from corn cob for methylene blue adsorption, Appl. Surf. Sci. Adv., 3, 100037.

[23] Hajialigol, S., and Masoum, S., 2019, Optimization of biosorption potential of nano biomass derived from walnut shell for the removal of Malachite Green from liquids solution: Experimental design approaches, J. Mol. Liq., 286, 110904.

[24] Subramanyam, B., and Das, A., 2014, Linearised and non-linearised isotherm models optimization analysis by error functions and statistical means, J. Environ. Health Sci. Eng., 12 (1), 92.

[25] Bonilla-Petriciolet, A., Mendoza-Castillo, D.I., and Reynel-Ávila, H.E., 2017, Adsorption Processes for Water Treatment and Purification, Springer Cham, Switzerland.

[26] Prasad, A.L., Santhi, T., and Manonmani, S., 2015, Recent developments in preparation of activated carbons by microwave: Study of residual errors, Arabian J. Chem., 8 (3), 343–354.

[27] Soldatkina, L., and Yanar, M., 2021, Equilibrium, kinetic, and thermodynamic studies of cationic dyes adsorption on corn stalks modified by citric acid, Colloids Interfaces, 5 (4), 52.

[28] Hien Tran, T., Le, A.H., Pham, T.H., Duong, L.D., Nguyen, X.C., Nadda, A.K., Chang, S.W., Chung, W.J., Nguyen, D.D., and Nguyen, D.T., 2022, A sustainable, low-cost carbonaceous hydrochar adsorbent for methylene blue adsorption derived from corncobs, Environ. Res., 212, 113178.

[29] Ellerie, J.R., Apul, O.G., Karanfil, T., and Ladner, D.A., 2013, Comparing graphene, carbon nanotubes, and superfine powdered activated carbon as adsorptive coating materials for microfiltration membranes, J. Hazard. Mater., 261, 91–98.

[30] Partlan, E., Davis, K., Ren, Y., Apul, O.G., Mefford, O.T., Karanfil, T., and Ladner, D.A., 2016, Effect of bead milling on chemical and physical characteristics of activated carbons pulverized to superfine sizes, Water Res., 89, 161–170.

[31] Ando, N., Matsui, Y., Kurotobi, R., Nakano, Y., Matsushita, T., and Ohno, K., 2010, Comparison of natural organic matter adsorption capacities of super-powdered activated carbon and powdered activated carbon, Water Res., 44 (14), 4127–4136.

[32] Ragadhita, R., and Nandiyanto, A.B.D., 2021, How to calculate adsorption isotherms of particles using two-parameter monolayer adsorption models and equations, Indones. J. Sci. Technol., 6 (1), 205–234.

[33] Agbovi, H.K., and Wilson, L.D., 2021, “Adsorption Processes in Biopolymer Systems: Fundamentals to Practical Applications” in Natural Polymers-Based Green Adsorbents for Water Treatment, Eds. Kalia, S., Elsevier, Cambridge, US, 1–51.

[34] Yao, C., and Chen, T., 2017, A film-diffusion-based adsorption kinetic equation and its application, Chem. Eng. Res. Des., 119, 87–92.

[35] Sreńscek-Nazzal, J., Narkiewicz, U., Morawski, A.W., Wróbel, R.J., and Michalkiewicz, B., 2015, Comparison of optimized isotherm models and error functions for carbon dioxide adsorption on activated carbon, J. Chem. Eng. Data, 60 (11), 3148–3158.

[36] Nandiyanto, A.B.D., Oktiani, R., and Ragadhita, R., 2019, How to read and interpret FTIR spectroscope of organic material, Indones. J. Sci. Technol., 4 (1), 97–118.

[37] Jawad, A.H., Saud Abdulhameed, A., Wilson, L.D., Syed-Hassan, S.S.A., ALOthman, Z.A., and Rizwan Khan, M., 2021, High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study, Chin. J. Chem. Eng., 32, 281–290.

DOI: https://doi.org/10.22146/ijc.79784

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