Influence of Calcination Temperatures on Gunningite-Based Gelatin Template and Its Application as Ibuprofen Adsorption

Maria Ulfa; Muhammad Ari Purnama Ali

doi:10.22146/ijc.77004

Influence of Calcination Temperatures on Gunningite-Based Gelatin Template and Its Application as Ibuprofen Adsorption

https://doi.org/10.22146/ijc.77004

Maria Ulfa^(1*), Muhammad Ari Purnama Ali⁽²⁾

(1) Study Program of Chemistry Education, Faculty of Teacher Training and Education, Sebelas Maret University, Jl. Ir. Sutami 36A, 57126 Surakarta, Central Java, Indonesia
(2) Study Program of Chemistry Education, Faculty of Teacher Training and Education, Sebelas Maret University, Jl. Ir. Sutami 36A, 57126 Surakarta, Central Java, Indonesia
(*) Corresponding Author

Abstract

Gunningite has been successfully synthesized using the soft template method with the Pluronic F127-gelatin template. Gunningite was calcined at diverse temperatures of 500, 600, and 700 °C for 12 h and characterized by XRD, SEM, and FTIR. A UV-Vis Spectrophotometer measured the adsorption capacity of Gunningite against ibuprofen. The XRD results showed that the crystal sizes of Gunningite decreased from 35.41 to 28.31 nm with the increasing calcination temperature from 500 to 700 °C. Besides, the crystallinity degrees also increased from 49.94% to 56.13% as calcination temperature increased from 500 to 700 °C. The Gunningite formed aggregates in the form of tiny particles that merge and experience agglomeration. The FTIR spectra of the Gunningite samples demonstrated the functional groups –OH, Zn-OH, Zn-O-Zn, and gunningite vibrations. The maximum adsorption capacities of Gunningite to adsorb ibuprofen were 233.161 mg g⁻¹ (500 °C), 219.543 mg g⁻¹ (600 °C), and 227.033 mg g^-1 (700 °C). The kinetic model of Gunningite on the ibuprofen adsorption followed the kinetic model of Ho and McKay.

Keywords

zinc sulfate (Gunningite); gelatin; temperature calcination; characterization; adsorption ibuprofen

Full Text:

Full Text PDF

References

[1] Höffler, F., Müller, I., and Steiger, M., 2018, Thermodynamic properties of ZnSO₄(aq) and phase equilibria in the ZnSO₄–H₂O system from 268 K to 373 K, J. Chem. Thermodyn., 116, 279–288.

[2] Wang, X., Wan, X., Hu, W., Chou, I.M., Cao, J., Wang, X., Wang, M., and Li, Z., 2016, In situ observations of liquid–liquid phase separation in aqueous ZnSO₄ solutions at temperatures up to 400 °C: Implications for Zn²⁺–SO₄²⁻ association and evolution of submarine hydrothermal fluids, Geochim. Cosmochim. Acta, 181, 126–143.

[3] Buzatu, A., Dill, H.G., Buzgar, N., Damian, G., Elena, A.E., and Apopei, A.I., 2016, Efflorescent sulfates from Baia Sprie mining area (Romania) — Acid mine drainage and climatological approach, Sci. Total Environ., 542, 629–641.

[4] Ulfa, M., Prasetyoko, D., Mahadi, A.H., and Bahruji, H., 2020, Size tunable mesoporous carbon microspheres using Pluronic F127 and gelatin as co-template for removal of ibuprofen, Sci. Total Environ., 711, 135066.

[5] Dziadkowiec, J., Mansa, R., Quintela, A, Rocha, F., and Detellier, C., 2017, Preparation, characterization and application in controlled release of Ibuprofen-loaded guar gum/montmorillonite bionanocomposites, Appl. Clay Sci., 135, 52–63.

[6] Ulfa, M., Aristia, K.S., and Prasetyoko, D., 2018, Synthesis of mesoporous silica materials via dual templating method from starch of waste rice and their application for drug delivery system, AIP Conf. Proc., 2049, 020002.

[7] Rehman, F., Ahmed, K., Rahim, A., Muhammad, N., Tariq, S., Azhar, U., Khan, A.J., Sama, Z., Volpe, P.L.O., and Airoldi, C., 2018, Organo-bridged silsesquioxane incorporated mesoporous silica as a carrier for the controlled delivery of ibuprofen and fluorouracil, J. Mol. Liq., 258, 319–326.

[8] Albayati, T.M., Salih, I.K., and Alazzawi, H.F., 2019, Synthesis and characterization of a modified surface of SBA-15 mesoporous silica for a chloramphenicol drug delivery system, Heliyon, 5 (10), e02539.

[9] Reino Olegário da Silva, D.A., Bosmuler Zuge, L.C., and de Paula Scheer, A., 2020, Preparation and characterization of a novel green silica/PVA membrane for water desalination by pervaporation, Sep. Purif. Technol., 247, 116852.

[10] Northrop, R.H.J., and Kusitz, M., 1931, Swelling and hydration of gelatin, J. Phys. Chem., 35 (1), 162–184.

[11] Elzoghby, A.O., 2013, Gelatin-based nanoparticles as drug and gene delivery systems: Reviewing three decades of research, J. Controlled Release, 172 (3), 1075–1091.

[12] Li, D., Li, S., Liu, J., Zhan, L., Wang, P., Zhu, H., and Wei, J., 2020, Surface modification of carbon nanotube with gelatin via mussel inspired method, Mater. Sci. Eng., C, 112, 110887.

[13] Petkova-Olsson, Y., Oelschlaeger, C., Ullsten, H., and Järnström, L., 2018, Structural, microrheological and kinetic properties of a ternary silica-Pluronic F127-starch thermosensitive system, J. Colloid Interface Sci., 514, 459–467.

[14] Chatterji, S., 2000, A discussion of the paper' Crystallisation in pores' by G.W. Scherer, Cem. Concr. Res., 30 (4), 669–671.

[15] Frolova, L., and Sukhyy, K., 2022, The effect of the cation in spinel ferrite MeFe₂O₄ (Me = Co, Ni, Mn) on the photocatalytic properties in the degradation of methylene blue, Mater. Today: Proc., 62, 7726–7730.

[16] Muda, Z., Hashim, N., Isa, I.M., Abu Bakar, S., Mohd Ali, N., Hussein, M.Z., Mamat, M., and Sidik, S.M., 2019, Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocomposite, J. Saudi Chem. Soc., 23 (4), 486–493.

[17] Ulfa, M., Prasetyoko, D., Bahruji, H., and Nugraha, R.E., 2021, Green synthesis of hexagonal hematite (α-Fe₂O₃) flakes using pluronic F127-gelatin template for adsorption and photodegradation of ibuprofen, Materials, 14 (22), 6779.

[18] Farzin Nejad, N., Shams, E., Amini, M.K., and Bennett, J.C., 2013, Ordered mesoporous carbon CMK-5 as a potential sorbent for fuel desulfurization: Application to the removal of dibenzothiophene and comparison with CMK-3. Microporous Mesoporous Mater., 168, 239–246.

[19] Ulfa, M., Nisa, D., Muhammad, F.P., and Prasetyoko, D., 2021, Investigating the hydrophilicity of zinc oxide nanoparticles using xylene and water for ibuprofen adsorption, J. Chem. Technol. Metall., 56 (4), 761–768.

[20] Lestari, W.W., Arvinawati, M., Martien, R., and Kusumaningsih, T., 2018, Green and facile synthesis of MOF and nano MOF containing zinc(II) and benzen 1,3,5-tricarboxylate and its study in ibuprofen, Mater. Chem. Phys., 204, 141–146.

DOI: https://doi.org/10.22146/ijc.77004