Inhibition of Carbon Steel Corrosion by Some New Organic 2-Hydroselenoacetamide Derivatives in HCl Medium

Alaa Abdel Khaleq Khalib; Hanan Abdul Jaleel Al-Hazam; Attared Fadhel Hassan

doi:10.22146/ijc.72852

Inhibition of Carbon Steel Corrosion by Some New Organic 2-Hydroselenoacetamide Derivatives in HCl Medium

https://doi.org/10.22146/ijc.72852

Alaa Abdel Khaleq Khalib⁽¹⁾, Hanan Abdul Jaleel Al-Hazam⁽²⁾, Attared Fadhel Hassan^(3*)

(1) Iraqi Cement State Company, Basrah, Iraq
(2) Department of Chemistry, College of Science, University of Basrah, Basrah 61004, Iraq
(3) Department of Chemistry, College of Science, University of Basrah, Basrah 61004, Iraq
(*) Corresponding Author

Abstract

This study aims to prepare 2-hydroselenoacetamide derivatives (5-8) to use some of these compounds as corrosion inhibition for carbon steel in 1 M HCl. The compound C₁₀H₁₀NO₂Cl 1 was prepared by reacting between p-aminoacetophenone with chloroacetyl chloride, and then reacted 1 with substituted benzaldehyde to obtain the corresponding derivatives as C₁₇H₁₃N₂O₄Cl 2, C₁₈H₁₆NO₄Cl 3 and C₁₉H₁₈NO₄Cl 4. The last step in this study was conducted to obtain the organic hydroselenoacetamide such as C₁₀H₁₁NO₂Se 5, C₁₇H₁₄N₂O₄Se 6, C₁₈H₁₇NO₄Se 7, and C₁₉H₁₉NO₄Se 8 by reacting chloroaminochalcone and sodium hydrogen selenide. All compounds were characterized by Fourier Transform Infrared Spectroscopy (FTIR), proton nuclear magnetic resonance (¹H-NMR), and elemental analysis (CHN). The corrosion inhibition activity of C₁₇H₁₄N₂O₄Se 6, C₁₈H₁₇NO₄Se 7 and C₁₉H₁₈NO₄Cl 4 for carbon steel in 1 M HCl solution was investigated by using weight loss methods and electrochemical study. The activation energy of the corrosion reaction was also calculated. The effect of different concentrations and temperatures on inhibition efficiency was investigated. The results showed that the corrosion rate decreased with the increase of the concentration of inhibitors, while the inhibition efficiency and covered area decreased with an increase in the temperature. Polarization studies demonstrated that the inhibitors were of mixed type. The purpose of this study was to prepare, characterize and evaluate the corrosion inhibition activity of hydroselenide compounds for carbon steel in 1 M HCl.

Keywords

corrosion inhibition; 2-hydroselenoacetamide; chalcone

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References

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DOI: https://doi.org/10.22146/ijc.72852