Risk Assessment of Toxic Metals from Drinking Water of Taluka Ghorābāri, Sindh, Pakistan

https://doi.org/10.22146/ijc.70345

Abdul Raheem Shar(1*), Ghulam Qadir Shar(2), Zulfiqar Ali Jumani(3), Aslam Khan Pathan(4), Zubeda Bhatti(5), Ali Raza Rind(6), Ghulam Mujtaba Jogi(7)

(1) Institute of Chemistry, Shah Abdul Latif University Khairpur, Sindh 66020, Pakistan
(2) Institute of Chemistry, Shah Abdul Latif University Khairpur, Sindh 66020, Pakistan
(3) Institute of Chemistry, Shah Abdul Latif University Khairpur, Sindh 66020, Pakistan
(4) Institute of Chemistry, Shah Abdul Latif University Khairpur, Sindh 66020, Pakistan
(5) Institute of Chemistry, Shah Abdul Latif University Khairpur, Sindh 66020, Pakistan
(6) Institute of Physics, University of Sindh, Jamshoro 76080, Sindh, Pakistan
(7) Institute of Chemistry, Shah Abdul Latif University Khairpur, Sindh 66020, Pakistan
(*) Corresponding Author

Abstract


In the current study, the quality of groundwater used for drinking purposes was assessed in Taluka Ghorābāri, Sindh, Pakistan. Twenty-five sampling locations were selected for the collection of groundwater. Samples were analyzed for physicochemical and heavy metal analysis, followed by standard methods. Detection of heavy metals was conducted using Atomic Absorption Spectrophotometer. Heavy metals which exceeded the WHO safe limit included Cr (28%), Fe (16%), Mn (48%), and Ni (16%) from the drinking water of the study area. The Cu and Zn were found within the safe limit in all drinking water samples of the study area. The Daily Intake of heavy Metals (DIM) and Health Risk Indexes (HRI) Assessments were calculated to determine risk assessments; the order of mean DIM values was observed as Ni > Cu > Fe > Zn > Cr while HRI was observed in the order of Cu > Mn > Zn > Fe > Cr. The HRI values were observed less than one for both adults and children, which shows the lack of possible health hazards for the people of the study area.

Keywords


heavy metals; WHO; DIM; HRI; risk assessments

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References

[1] Cherfi, A., Achour, M., Cherfi, M., Otmani, S., and Morsli, A., 2015, Health risk assessment of heavy metals through consumption of vegetables irrigated with reclaimed urban wastewater in Algeria, Process Saf. Environ. Prot., 98, 245–252.

[2] Matta, G., and Kumar, A., 2017, Health risk, water hygiene, science and communication, Essence, 8 (1), 179–186.

[3] Patel, P., Raju, N.J., Reddy, B.C.S.R., Suresh, U., Sankar, D.B., and Reddy, T.V.K., 2018, Heavy metal contamination in river water and sediments of the Swarnamukhi River Basin, India: Risk assessment and environmental implications, Environ. Geochem. Health, 40 (2), 609–623.

[4] Riaz, A., Khan, S., Muhammad, S., Liu, C., Shah, M.T., and Tariq, M., 2018, Mercury contamination in selected foodstuffs and potential health risk assessment along the artisanal gold mining, Gilgit-Baltistan, Pakistan, Environ. Geochem. Health, 40 (2), 625–635.

[5] Moynihan, M., 2016, Role of Diet in Heavy Metal Exposure and Toxicity during Prenatal and Peripubertal Periods, Thesis, University of Michigan, US.

[6] Daud, M., Nafees, M., Ali, S., Rizwan, M., Bajwa, R.A., Shakoor, M.B., Arshad, M.U., Chatha, S.A.S., Deeba, F., Murad, W., Malook, I., and Zhu, S.J., 2017, Drinking water quality status and contamination in Pakistan, BioMed. Res. Int., 2017, 7908183.

[7] Khan, A., Khan, S., Khan, M.A., Qamar, Z., and Waqas, M., 2015, The uptake and bioaccumulation of heavy metals by food plants, their effects on plants nutrients, and associated health risk: A review, Environ. Sci. Pollut. Res., 22 (18), 13772–13799.

[8] Rezapour, M., Rezapour, H.A., Chegeni, M., and Khanjani, N., 2021, Exposure to cadmium and head and neck cancers: A meta-analysis of observational studies, Rev. Environ. Health, 36 (4), 577–584.

[9] US-EPA, 2015, Guidelines for Carcinogen Risk Assessment, US Environmental Protection Agency, EPA/630/P-03/001F, Washington, DC.

[10] Jaishankar, M., Mathew, B.B., Shah, M.S., Krishna Murthy, T.P., and Sangeetha Gowda, K.R., 2014, Biosorption of few heavy metal ions using agricultural wastes, J. Environ. Pollut. Hum. Health, 2 (1), 1–6.

[11] Mehmood, A., Mirza, M.A., Choudhary, M.A., Kim, K.H., Raza, W., Raza, N., Lee, S.S., Zhang, M., Lee, J.H., and Sarfraz, M., 2019, Spatial distribution of heavy metals in crops in a wastewater irrigated zone and health risk assessment, Environ. Res., 168, 382–388.

[12] Muhammad, S., Shah, M.T., and Khan, S., 2011, Health risk assessment of heavy metals and their source apportionment in drinking water of Kohistan region, northern Pakistan, Microchem. J., 98 (2), 334–343.

[13] US-EPA, 2011, Exposure Factors Handbook 2011 Edition (Final Report), US Environmental Protection Agency, EPA/600/R-09/052F, Washington, DC.

[14] Nawab, J., Ali, S., Rauf, A., Ur Rehman, U., Khan, A.A., Sajjad, M., and Khan, W., 2015, Health risk associated with heavy metals via consumption of surface and groundwater in district Shangla, Pakistan, J. Himalayan Earth Sci., 48 (2), 62–73.

[15] Shekhawat, K., Chatterjee, S., and Joshi, B., 2015, Chromium toxicity and its health hazards, Int. J Adv. Res., 3 (7), 167–172.

[16] Vincent, J.B., 2015, Is the pharmacological mode of action of chromium (III) as a second messenger?, Biol. Trace Elem. Res., 166 (1), 7–12.

[17] Kamerud, K.L., Hobbie, K.A., and Anderson, K.A., 2013, Stainless steel leaches nickel and chromium into foods during cooking, J. Agric. Food Chem., 61 (39), 9495–9501.

[18] Seetharaman, J., and Sarma, M.S., 2021, Chelation therapy in liver diseases of childhood: Current status and response, World J. Hepatol., 13 (11), 1552–1567.

[19] Greenwood, N.N., and Earnshaw, A., 2012, Chemistry of the Elements, 2nd Ed., Elsevier, Oxford, Massachusetts, US.

[20] Erikson, K.M., and Aschner, M., 2019, Manganese: Its Role in Disease and Health, in Therapeutic Use and Toxicity of Metal Ions in the Clinic, De Gruyter, Berlin.



DOI: https://doi.org/10.22146/ijc.70345

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