A Potential Approach for Converting Rubber Waste into a Low-Cost Polymeric Adsorbent for Removing Methylene Blue from Aqueous Solutions

https://doi.org/10.22146/ijc.69674

Muhammad Aliyu(1), Abdul Halim Abdullah(2*), Mohamed Ibrahim bin Mohamed Tahir(3)

(1) Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia; Department of Chemistry, Faculty of Natural and Applied Science, Sule Lamido University, Kafin Hausa, Jigawa State, Nigeria
(2) Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia; Institute of advanced Technology, Universiti Putra Malaysia, 43400 Serdang, Selangor Darul Ehsan Malaysia
(3) Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
(*) Corresponding Author

Abstract


Exploiting waste materials to make cost-effective adsorbents and waste management methods are gaining more attention. In the current study, rubber wastes derived from dipping tank coagulum (DTC) in the glove manufacturing industry were converted into a novel polymeric-adsorbent via a simple sulfonation reaction with concentrated sulphuric acid and was used for the adsorption of methylene blue (MB) dye from aqueous solutions commonly found in contaminated waters. FT-IR, EDX, FESEM, and BET techniques were used to characterize the rubber waste before and after modification. The highest MB removal efficiency of 99.03% was achieved in the condition of initial concentration, adsorbent dosage, pH, contact time, and temperature were 15 mg/L, 30 mg, pH 7, 300 min, and 25 °C, respectively. The adsorption of MB was analyzed using experimental data fitted in a monolayer isotherms model with a maximum adsorption capacity of 119 mg/g. The kinetic model was revealed to agree with the pseudo-second-order kinetic model. Furthermore, SRW retained 90.45% of the removal percentage after four cycles of the repeated adsorption-desorption process. Conclusively, these findings suggest that rubber waste could be a suitable low-cost adsorbent to remove organic dyes from polluted water.


Keywords


methylene blue; adsorption; rubber waste; polymeric materials; environmental remediation

Full Text:

Full Text PDF


References

[1] Nuzaimah, M., Sapuan, S.M., Nadlene, R., and Jawaid, M., 2018, Recycling of waste rubber as fillers: A review, IOP Conf. Ser.: Mater. Sci. Eng., 368, 012016.

[2] Mahapatra, U., Chatterjee, A., Das, C., and Manna, A.K., 2021, Adsorptive removal of hexavalent chromium and methylene blue from simulated solution by activated carbon synthesized from natural rubber industry biosludge, Environ. Technol. Innovation, 22, 101427.

[3] Hirata, Y., Kondo, H., and Ozawa, Y., 2014, “Natural rubber (NR) for the tyre industry” in Chemistry, Manufacture and Applications of Natural Rubber, Woodhead Publishing, Cambridge, UK, 325–352.

[4] Bang-iam, N., Udnan, Y., and Masawat, P., 2013, Design and fabrication of artificial neural network-digital image-based colorimeter for protein assay in natural rubber latex and medical latex gloves, Microchem. J., 106, 270–275.

[5] Mohammadi, M., Man, H.C., Hassan, M.A., and Yee, P.L., 2010, Treatment of wastewater from rubber industry in Malaysia, Afr. J. Biotechnol., 9 (38), 6233–6243.

[6] Chakraborty, T.K., Islam, M.S., Zaman, S., Kabir, A.H.M.E., and Ghosh, G.C., 2020, Jute (Corchorus olitorius) stick charcoal as a low-cost adsorbent for the removal of methylene blue dye from aqueous solution, SN Appl. Sci., 2 (4), 765.

[7] Temel, F., Turkyilmaz, M., and Kucukcongar, S., 2020, Removal of methylene blue from aqueous solutions by silica gel supported calix[4]arene cage: Investigation of adsorption properties, Eur. Polym. J., 125, 109540.

[8] Jantawatchai, K., Jitpluem, S., Kerdlap, W., Phanawadee, P., Warakulwit, C., Chisti, Y., and Hansupalak, N., 2017, Production and characterization of a novel hierarchical porous silica adsorbent for removal of methylene blue dye from wastewaters, Chem. Eng. Commun., 204 (12), 1452–1465.

[9] Saif ur Rehman, M., Kim, I., and Han, J.I., 2012, Adsorption of methylene blue dye from aqueous solution by sugar extracted spent rice biomass, Carbohydr. Polym., 90 (3), 1314–1322.

[10] Olusegun, S.J., de Sousa Lima, L.F., and Mohallem, N.D.S., 2018, Enhancement of adsorption capacity of clay through spray drying and surface modification process for wastewater treatment, Chem. Eng. J., 334.

[11] Kubra, K.T., Salman, M.S., and Hasan, M.N., 2021, Enhanced toxic dye removal from wastewater using biodegradable polymeric natural adsorbent, J. Mol. Liq., 328, 115468.

[12] Huang, X.Y., Bu, H.T., Jiang, G.B., and Zeng, M.H., 2011, Cross-linked succinyl chitosan as an adsorbent for the removal of methylene blue from aqueous solution, Int. J. Biol. Macromol., 49 (4), 643–651.

[13] Karagöz, S., Tay, T., Ucar, S., and Erdem, M., 2008, Activated carbons from waste biomass by sulfuric acid activation and their use on methylene blue adsorption, Bioresour. Technol., 99 (14), 6214–6222.

[14] Islam, M.T., Saenz-Arana, R., Hernandez, C., Guinto, T., Ahsan, M.A., Bragg, D.T., Wang, H., Alvarado-Tenorio, B., and Noveron, J.C., 2018, Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water, J. Environ. Chem. Eng., 6 (2), 3070–3082.

[15] Du, J.J., Yuan, Y.P., Sun, J.X., Peng, F.M., Jiang, X., Qiu, L.G., Xie, A.J., Shen, Y.H., and Zhu, J.F., 2011, New photocatalysts based on MIL-53 metal-organic frameworks for the decolorization of methylene blue dye, J. Hazard. Mater., 190 (1-3), 945–951.

[16] Li, X., and Li, Y., 2019, Adsorptive removal of dyes from aqueous solution by KMnO4-modified rice husk and rice straw, J. Chem., 2019, 8359491.

[17] Hasan, R., Ying, W.J., Cheng, C.C., Jaafar, N.F., Jusoh, R., Jalil, A.A., and Setiabudi, H.D., 2020, Methylene blue adsorption onto cockle shells-treated banana pith: Optimization, isotherm, kinetic, and thermodynamic studies, Indones. J. Chem., 20 (2), 368–378.

[18] Bello, O.S., Adegoke, K.A., Olaniyan, A.A., and Abdulazeez, H., 2015, Dye adsorption using biomass wastes and natural adsorbents: Overview and future prospects, Desalin. Water Treat., 53 (5), 1292–1315.

[19] Hu, Z.P., Gao, Z.M., Liu, X., and Yuan, Z.Y., 2018, High-surface-area activated red mud for efficient removal of methylene blue from wastewater, Adsorpt. Sci. Technol., 36 (1-2), 62–79.

[20] Chan, W.H., Mazlee, M.N., Ahmad, Z.A., Ishak, M.A.M., and Shamsul, J.B., 2017, The development of low-cost adsorbents from clay and waste materials: A review, J. Mater. Cycles Waste Manage., 19 (1), 1–14.

[21] Troca-Torrado, C., Alexandre-Franco, M., Fernández-González, C., Alfaro-Domínguez, M., and Gómez-Serrano, V., 2011, Development of adsorbents from used tire rubber: Their use in the adsorption of organic and inorganic solutes in aqueous solution, Fuel Process. Technol., 92 (2), 206–212.

[22] Nethaji, S., Sivasamy, A., and Mandal, A.B., 2013, Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass, Int. J. Environ. Sci. Technol., 10 (2), 231–242.

[23] Ayodele, O.B., 2013, Effect of phosphoric acid treatment on kaolinite supported ferrioxalate catalyst for the degradation of amoxicillin in batch photo-Fenton process, Appl. Clay Sci., 72, 74–83.

[24] Hameed, B.H., and Ahmad, A.A., 2009, Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass, J. Hazard. Mater., 164 (2-3), 870–875.

[25] Foletto, V.S., Ferreira, A.B., da Cruz Severo, E., Collazzo, G.C., Foletto, E. L., and Dotto, G.L., 2017, Iron-based adsorbent prepared from Litchi peel biomass via pyrolysis process for the removal of pharmaceutical pollutant from synthetic aqueous solution, Environ. Sci. Pollut. Res., 24 (11), 10547–10556.

[26] Jusoh, N.W.C., Choo, T.Y., Masudi, A., and Ali, R.R., 2020, Waste tire carbon adsorbent for active removal of paracetamol in aqueous solution, J. Phys.: Conf. Ser., 1447, 012050.

[27] Dada, A.O., Olalekan, A.P., Olatunya, A.M., and Dada, O., 2012, Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk, IOSR J. Appl. Chem., 3 (1), 38–45.

[28] Polat, K., and Bursalı, E.A., 2019, A promising strategy for the utilization of waste nitrile gloves: Cost-effective adsorbent synthesis, J. Mater. Cycles Waste Manage., 21 (3), 659–665.

[29] Oladipo, A.C., Tella, A.C., Clayton, H.S., Olayemi, V.T., Akpor, O.B., Dembaremba, T.O., Ogunlaja, A.S., Clarkson, G.J., and Walton, R.I., 2021, A zinc-based coordination polymer as adsorbent for removal of trichlorophenol from aqueous solution: Synthesis, sorption and DFT studies, J. Mol. Struct., 1247, 131274.



DOI: https://doi.org/10.22146/ijc.69674

Article Metrics

Abstract views : 2550 | views : 1495


Copyright (c) 2022 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.