Fabrication of Superhydrophobic Film on the Surface of Indonesian Bamboo Timber by TiO2 Deposition and Using Octadecyltrichlorosilane as a Surface Modifier Agent

https://doi.org/10.22146/ijc.46740

Diana Vanda Wellia(1*), Wulandari Wulandari(2), Arifah Mustaqimah(3), Nurul Pratiwi(4), Yulia Eka Putri(5)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Campus Unand Limau Manis, Padang 25163, West Sumatra, Indonesia
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Campus Unand Limau Manis, Padang 25163, West Sumatra, Indonesia
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Campus Unand Limau Manis, Padang 25163, West Sumatra, Indonesia
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Campus Unand Limau Manis, Padang 25163, West Sumatra, Indonesia
(5) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Campus Unand Limau Manis, Padang 25163, West Sumatra, Indonesia
(*) Corresponding Author

Abstract


The tropical bamboo has been widely used in modern society as a potential material for various applications. It is well known that bamboo has low durability due to its hydrophilic properties. To overcome this problem, the superhydrophobic surface on Indonesian bamboo timber had been successfully fabricated via hydrothermal deposition of an anatase TiO2 and solution immersion of octadecyltrichlorosilane (ODTS), which exhibited a maximum water contact angle (WCA) of 155°. The as-fabricated superhydrophobic bamboo timber not only showed high mechanical resistance against the abrasion of SiC sandpaper but had also been proven to possess high chemical stability after immersion in acidic and basic aqueous solutions. Moreover, the superhydrophobic bamboo timber also demonstrated excellent self-cleaning and flame-resistance properties, in comparison to pure bamboo timber. It is believed that the strategy offered in this study can increase the utilization of bamboo timber for various purposes, especially as a self-cleaning material.

Keywords


superhydrophobic; TiO2; bamboo; octadecyltrichlorosilane; self-cleaning material

Full Text:

Full Text PDF


References

[1] Canavan, S., Richardson, D.M., Visser, V., Le Roux, J.J., Vorontsova, M.S., and Wilson, J.R.U., 2016, The global distribution of bamboos: assessing correlates of introduction and invasion, AoB Plants, 9 (1), plw078.

[2] Yeasmin, L., Ali, M.N., Gantait, S., and Chakraborty, S., 2015, Bamboo: An overview on its genetic diversity and characterization, 3 Biotech, 5 (1), 1–11.

[3] Yen, T.M., Ji, Y.J., and Lee, J.S., 2010, Estimating biomass production and carbon storage for a fast-growing makino bamboo (Phyllostachys makinoi) plant based on the diameter distribution model, For. Ecol. Manage., 260 (3), 339–344.

[4] He, C., Cui, K., Zhang, J., Duan, A., and Zeng, Y., 2013, Next-generation sequencing-based mRNA and microRNA expression profiling analysis revealed pathways involved in the rapid growth of developing culms in moso bamboo, BMC Plant Biol., 13, 119.

[5] Sharma, B., Gatóo, A., Bock, M., and Ramage, M., 2015, Engineered bamboo for structural applications, Constr. Build. Mater., 81, 66–73.

[6] Li, Z., Jiang, Z., Fei, B., Cai, Z., and Pan, X., 2014, Comparison of bamboo green, timber and yellow in sulfite, sulfuric acid and sodium hydroxide pretreatments for enzymatic saccharification, Bioresour. Technol., 151, 91–99.

[7] Suprapti, S., 2010, Decay resistance of five Indonesian bamboo species against fungi, J. Trop. For. Sci., 22 (3), 287–294.

[8] Park, S.H., Jang, J.H., Wistara, N.J., Hidayat, W., Lee, M., and Febrianto, F., 2018, Anatomical and physical properties of Indonesian bamboos carbonized at different temperatures, J. Korean Wood Sci. Technol., 46 (6), 656–669.

[9] Liese, W., and Tang, T.K.H., 2015, “Properties of the bamboo culm” in Bamboo. Tropical Forestry, Vol. 10, Eds. Liese, W., and Köhl, M., Springer International Publishing, Cham, Switzerland, 227–256.

[10] Li, J., Sun, Q., Fan, B., Zheng, H., Yan, C., and Jin, C., 2015, Fabrication of biomimetic superhydrophobic plate-like CaCO3 coating on the surface of bamboo timber inspired from the biomineralization of nacre in seawater, Nano Rep., 1 (1), 9–14.

[11] Jin, C., Li, J., Han, S., Wang, J., and Sun, Q., 2014, A durable, superhydrophobic, superoleophobic and corrosion-resistant coating with rose-like ZnO nanoflowers on a bamboo surface, Appl. Surf. Sci., 320, 322–327.

[12] Li, J., Lu, Y., Wu, Z., Bao, Y., Xiao, R., Yu, H., and Chen, Y., 2016, Durable, self-cleaning and superhydrophobic bamboo timber surfaces based on TiO2 films combined with fluoroalkylsilane, Ceram. Int., 42 (8), 9621–9629.

[13] Wellia, D.V., Mustaqimah, A., Wulandari, W., Zulhadjri, Z., Syukri, S., and Pratiwi, N., 2018, Fabrication of hydrophobic Indonesia bamboo modified by octa fluoro 1-pentanol (OFP) based on TiO2 thin film for self-cleaning application, J. Pure Appl. Chem. Res., 7 (2), 149–159.

[14] Li, J., Zheng, H., Sun, Q., Han, S., Fan, B., Yao, Q., Yan, C., and Jin, C., 2015, Fabrication of superhydrophobic bamboo timber based on an anatase TiO2 film for acid rain protection and flame retardancy, RSC Adv., 5 (76), 62265–62272.

[15] Parkin, I.P., and Palgrave, R.G., 2005, Self-cleaning coatings, J. Mater. Chem., 15 (17), 1689–1695.

[16] Li, J., Sun, Q., Yao, Q., Wang, J., Han, S., and Jin, C., 2015, Fabrication of robust superhydrophobic bamboo based on ZnO nanosheet networks with improved water-, UV-, and fire-resistant properties, J. Nanomater., 2015, 431426.

[17] Wang, F., Li, S., and Wang, L., 2017, Fabrication of artificial super-hydrophobic lotus-leaf-like bamboo surfaces through soft lithography, Colloids Surf., A, 513, 389–395.

[18] Li, X., Sun, C., Zhou, B., and He, Y., 2015, Determination of hemicellulose, cellulose and lignin in moso bamboo by near infrared spectroscopy, Sci. Rep., 5, 17210.

[19] Bao, W., Liang, D., Zhang, M., Jiao, Y., Wang, L., Cai, L., and Li, J., 2017, Durable, high conductivity, superhydrophobicity bamboo timber surface for nanoimprint stamps, Prog. Nat. Sci. Mater. Int., 27 (6), 669–673.

[20] Chibac, A.L., Buruiana, T., Melinte, V., and Buruiana, E.C., 2017, Photocatalysis applications of some hybrid polymeric composites incorporating TiO2 nanoparticles and their combinations with SiO2/Fe2O3, Beilstein J. Nanotechnol., 8, 272–286.

[21] Li, J., Sun, Q., Jin, C., and Li, J., 2015, Comprehensive studies of the hydrothermal growth of ZnO nanocrystals on the surface of bamboo, Ceram. Int., 41 (1, Part B), 921–929.



DOI: https://doi.org/10.22146/ijc.46740

Article Metrics

Abstract views : 3480 | views : 2385


Copyright (c) 2020 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 

Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web Analytics View The Statistics of Indones. J. Chem.