Preparation of MWCNTS/Cr2O3-NiO Nanocomposite for Adsorption and Photocatalytic Removal of Bismarck Brown G Dye from Aqueous Solution

https://doi.org/10.22146/ijc.43429

Emman Jassim Mohammad(1), Mohanad Mousa Kareem(2), Abbas Jasim Atiyah Lafta(3*)

(1) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(2) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(3) Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq
(*) Corresponding Author

Abstract


This work describes the synthesis of nanocomposites of multiwall carbon nanotubes (MWCNTs) with co-oxide nanocomposite (MWCNTs)/MO. These nanocomposites were prepared using a simple evaporation and drying process. The obtained composites were characterized using X-ray diffraction (XRD), Atomic force microscopy (AFM), Fourier Transform Infrared Spectroscopy (FTIR), and scanning electron microscopy (SEM). The activity of the prepared composites was investigated by following the removal of Bismarck brown G dye (BBG) from aqueous solution via adsorption processes and photocatalytic reactions. Different reaction parameters were performed such as the effect of dosage of the used nanocomposite, pH value, and effect of temperature. In addition to that adsorption isotherms and reaction kinetics were investigated. The efficiency of photocatalytic dye removal over the prepared composites was 99.9% after one hour of reaction at the optimal conditions which were mass dosage (0.03 g), pH (5), and temperature (303 K). The adsorption isotherm data were fitted with Langmuir isotherm and the kinetic data were fitted with the pseudo-second-order kinetic model.

Keywords


dyes removal; Bismarck brown G; carbon nanotubes; nanocomposite

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References

[1] Xu, A.Z., Yang, M.S., Wu, Q., Hu, X.M., and Jiang, L., 2005, Flow field induced steady alignment of oxidized multi-walled carbon nanotubes, Chin. Chem. Lett., 16 (6), 849–852.

[2] Iijima, S., and Ichihashi, T., 1993, Single-shell carbon nanotubes of 1-nm diameter, Nature, 363, 603–605.

[3] Ijima, S., 1991, Helical microtubules of graphitic carbon, Nature, 354 (7), 56–58.

[4] Wepasnick, K.A., Smith, B.A., Bitter, J.L., and Fairbrother, D.H., 2010, Chemical and structural characterization of carbon nanotube surfaces, Anal. Bioanal. Chem., 396 (3), 1003–1014.

[5] Iijima, S., and Ichihashi, T., 1993, Single-shell carbon nanotubes of 1-nm diameter, Nature, 363, 603-605.

[6] Jishi, R.A., Venkataraman, L., Dresselhaus, M.S., and Dresselhaus, G., 1993, Phonon modes in carbon nanotubules, Chem. Phys. Lett., 209 (1-2), 77–82.

[7] Wang, N., Tang, Z.K., Li, G.D., and Chen, J.S., 2000, Materials science: Single walled 4Å carbon nanotube arrays, Nature, 408 (6808), 50–51.

[8] Liu, X., Huber, T.A., Kopac, M.C., and Pickup, P.G., 2009, Ru oxide/carbon nanotube composites for supercapacitors prepared by spontaneous reduction of Ru(VI) and Ru(VII), Electrochim. Acta, 54 (27), 7141–7147.

[9] Leonov, A.A., Khasanov, A.O., Danchenko, V.A., and Khasanov, O.L., 2017, Spark plasma sintering of ceramic matrix composite based on alumina, reinforced by carbon nanotubes, IOP Conf. Ser.: Mater. Sci. Eng., 286, 012034.

[10] Keshri, A.K., Huang, J., Singh, V., Choi, W., Seal, S., and Agarwal, A., 2010, Synthesis of aluminum oxide coating with carbon nanotube reinforcement produced by chemical vapor deposition for improved fracture and wear resistance, Carbon, 48 (2), 431–442.

[11] Bandow, S., Asaka, S., Saito, Y., Rao, A.M., Grigorian, L., Richter, E., and Eklund, P.C., 1998, Importance of transmission electron microscopy for carbon nanomaterials, Phys. Rev. Lett., 80 (17), 3779–3782.

[12] Koval’chuk, A.A., Shevchenko, V.G., Shchegolikhin, A.N., Nedorezova, P.M., Klyamkina, A.N., and Aladyshev, A.M., 2008, Effect of carbon nanotube functionalization on the structural and mechanical properties of polypropylene/MWCNT composites, Macromolecules, 41 (20), 7536–7542.

[13] Amiri, A., Maghrebi, M., Baniadam, M., and Zeinali Heris, S.Z., 2011, One-pot, efficient functionalization of multi-walled carbon nanotubes with diamines by microwave method, Appl. Surf. Sci., 257 (23), 10261–10266.

[14] Cuentas-Gallegos, A.K., Martínez-Rosales, R., Rincón, M.E., Hirata, G.A., and Orozco, G., 2006, Design of hybrid materials based on carbon nanotubes and polyoxometalates, Opt. Mater., 29 (1), 126–133.

[15] Hojati-Talemi, P., and Simon, G., 2009, Microwave-based treatments for multi-walled carbon nanotubes, Phys. Status Solidi C, 6 (10), 2170–2173.

[16] Smith, B., Wepasnick, K., Schrote, K.E., Cho, H.H., Ball, W.P., and Fairbrother, D.H., 2009, Influence of surface oxides on the colloidal stability of multi-walled carbon nanotubes: A structure-property relationship, Langmuir, 25 (17), 9767–9776.

[17] Lu, C., and Chiu, H., 2008, Chemical modification of multiwalled carbon nanotubes for sorption of Zn2+ from aqueous solution, Chem. Eng. J., 139 (3), 462–468.

[18] Morales-Lara, F., Pérez-Mendoza, M.J., Altmajer-Vaz, D., García-Román, M., Melguizo, M., López-Garzón, F.J., and Domingo-García, M., 2013, Functionalization of multiwall carbon nanotubes by ozone at basic pH. Comparison with oxygen plasma and ozone in gas phase, J. Phys. Chem. C, 117 (22), 11647–11655.

[19] Eder, D., 2010, Carbon nanotube− inorganic hybrids, Chem. Rev., 110 (3), 1348–1385.

[20] Fu, K., Huang, W., Lin, Y., Riddle, L.A., Carroll, D.L., and Sun, Y.P., 2001, Defunctionalization of functionalized carbon nanotubes, Nano Lett., 1 (8), 439–441.

[21] Sun, Y., Wilson, S.R., and Schuster, D.I., 2001, High dissolution and strong light emission of carbon nanotubes in aromatic amine solvents, J. Am. Chem. Soc., 123 (22), 5348–5349.

[22] Gupta, V.K., Agarwal, S., and Saleh, T.A., 2011, Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal, J. Hazard. Mater., 185 (1), 17–23.

[23] Wang, S., Shi, X., Shao, G., Duan, X., Yang, H., and Wang, T., 2008, Preparation, characterization and photocatalytic activity of multi-walled carbon nanotube-supported tungsten trioxide composites, J. Phys. Chem. Solids, 69 (10), 2396–2400.

[24] Mitróová, Z., Tomašovičová, N., Lancz, G., Kováč, J., Vávra, I., and Kopčanský, P., 2010, Preparation and characterization of carbon nanotubes functionalized by magnetite nanoparticles, Proceeding of the 2nd NANOCON International Conference, Olomouc, Czech Republic, 12–14 October 2010.

[25] Xu, Y.J., Zhuang, Y., and Fu, X., 2010, New insight for the enhanced photocatalytic activity of TiO2 by doping carbon nanotubes: A case study on degradation of benzene and methyl orange, J. Phys. Chem. C, 114 (6), 2669–2676.

[26] Yu, Y., Yu, J.C., Yu, J.G., Kwok, Y.C., Che, Y.K., Zhao, J.C., Ding, L., Ge, W.K., and Wong, P.K., 2005, Enhancement of photocatalytic activity of mesoporous TiO2 by using carbon nanotubes, Appl. Catal., A, 289 (2), 186–196.

[27] Yudasaka, M., Kikuchi, R., Matsui, T., Ohki, Y., Yoshimura, S., and Ota, E., 1995, Specific conditions for Ni catalyzed carbon nanotube growth by chemical vapor deposition, Appl. Phys. Lett., 67 (17), 2477–2479.

[28] Yukasaka, M., Kikuchi, R., Ohki, Y., Ota, E., and Yoshimura, S., 1997, Behavior of Ni in carbon nanotube nucleation, Appl. Phys. Lett., 70 (14), 1817–1818.

[29] Skoog, D.A., Holler, F.J., and Crouch, S.R., 2007, Principles of Instrumental Analysis, Principles of Instrumental Analysis, 6th Ed., Thomson Brooks/Cole, Belmont, CA, USA.

[30] Wu, X., Hong, X., Luo, Z., Hui, K.S., Chen, H., Wu, J., Hui, K.N. Li, L., Nan, J., and Zang, Q., 2013, The effects of surface modification on the supercapacitive behaviors of novel mesoporous carbon derived from rod-like hydroxyapatite template, Electrochim. Acta, 89, 400–406.

[31] Pilehvar, S., Rather, J.A., Dardenne, F., Robbens, J., Blust, R., and De Wael, K., 2013, Carbon nanotubes based electrochemical detection of hydroxylated polychlorinated biphenyl in human blood aptasensing platform for the serum, Biosens. Bioelectron., 54, 78–84.

[32] Fadaei, S., Moghadam, F.N., Hashemi, M., and Pourzamani, H., 2017, BTEX removal from aqueous solution by modified multi-walled carbon nanotubes with ozone, Anuário IGEO, 40 (1), 235–242.

[33] Yıldrım, A., and Seçkin, T., 2014, In situ preparation of polyether amine functionalized MWCNT nanofiller as reinforcing agents, Adv. Mat. Sci. Eng., 2014, 356920.

[34] Kim, S.K., and Park, H.S., 2014, Multiwalled carbon nanotubes coated with a thin carbon layer for use as composite electrodes in supercapacitors, RSC Adv., 4 (88), 47827–47832.

[35] Hayat, K., Gondal, M.A., Khaled, M.M., and Ahmed, S., 2010, Kinetic study of laser-induced photocatalytic degradation of dye (alizarin yellow) from wastewater using nanostructured ZnO, J. Environ. Sci. Health., Part A Toxic/Hazard. Subst. Environ. Eng., 45 (11), 1413–1420.

[36] Mohammad, E.J., Lafta, A.J., and Kahdim, S.H., 2016, Photocatalytic removal of reactive yellow 145 dye from simulated textile wastewaters over supported (Co, Ni)3O4/Al2O3 co-catalyst, Pol. J. Chem. Technol., 18 (3), 1–9.

[37] Mohammad, E.J., Kareem, M.M., and Atiyah, A.J., 2018, Removal of dye Bismarck brown G by photocatalytic reaction over prepared co-oxide Cr2O3-NiO: A kinetic study, Asian J. Chem., 30 (11), 2527–2532.

[38] Soares, E.T., Lansarin, M.A., and Moro, C.C., 2007, A study of process variables for the photocatalytic degradation of rhodamine B, Braz. J. Chem. Eng., 24 (1), 29–36.

[39] Lagergren, S., 1898, About the theory of so-called adsorption of soluble substances, K. Sven. Vetensk.Akad. Handl., 24 (4), 1–39.



DOI: https://doi.org/10.22146/ijc.43429

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