Adsorption Study of Rhodamine B and Methylene Blue Dyes with ZSM-5 Directly Synthesized from Bangka Kaolin without Organic Template

https://doi.org/10.22146/ijc.41369

Ani Iryani(1), Hadi Nur(2), Mardi Santoso(3), Djoko Hartanto(4*)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Pakuan, Jl. Pakuan, Tegallega, Bogor 16143, Indonesia; Department of Chemistry, Faculty of Science, Institut Teknologi Sepuluh Nopember, Keputih, Surabaya 60111, Indonesia
(2) Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, Johor, Malaysia
(3) Department of Chemistry, Faculty of Science, Institut Teknologi Sepuluh Nopember, Keputih, Surabaya 60111, Indonesia
(4) Department of Chemistry, Faculty of Science, Institut Teknologi Sepuluh Nopember, Keputih, Surabaya 60111, Indonesia
(*) Corresponding Author

Abstract


Rhodamine B (RB) and Methylene Blue (MB) dyes adsorption using adsorbent ZSM-5 synthesized from Bangka kaolin were investigated in this study. The effects of the initial concentration, contact time and temperature on the adsorption process were also analyzed. The effect of the initial concentration and contact time played an important role in the adsorption process; however, the effect differs significantly in both dyes. The temperature plays little role in the dye adsorption process. The results showed the adsorption process occurred in ZSM-5 adhere to Langmuir isothermal adsorption model showing that the adsorption process occurred to be monolayer. Based on the kinetics studies, the pseudo-first-order kinetic model represents the adsorption kinetics that occurs for both dyes onto the synthesized ZSM-5. Thermodynamic parameters namely Gibbs free energy (ΔG°), standard entropy changes (ΔS°) and standard enthalpy (ΔH°) reveal that the adsorption process onto ZSM-5 for both dyes was spontaneous and exothermic.

Keywords


Bangka kaolin; dyes; isotherm adsorption; kinetics; thermodynamics; ZSM-5

Full Text:

Full Text PDF


References

[1] Rafatullah, M., Sulaiman, O., Hashim, R., and Ahmad, A., 2010, Adsorption of methylene blue on low-cost adsorbents: A review, J. Hazard. Mater., 177 (1-3), 70–80.

[2] Ip, A.W.M., Barford, J.P., and McKay, G., 2009, Reactive Black dye adsorption/desorption onto different adsorbents: Effect of salt, surface chemistry, pore size and surface area, J. Colloid Interface Sci., 337 (1), 32–38.

[3] Cardoso, N.F., Pinto, R.B., Lima, E.C., Calvete, T., Amavisca, C.V., Royer, B., Cunha, M.L., Fernandes, T.H.M., and Pinto, I.S., 2011, Removal of remazol black B textile dye from aqueous solution by adsorption, Desalination, 269 (1-3), 92–103.

[4] Gupta, V.K., Suhas, Ali, I., and Saini, V.K., 2004, Removal of rhodamine B, fast green, and methylene blue from wastewater using red mud, an aluminum industry waste, Ind. Eng. Chem. Res., 43 (7), 1740–1747.

[5] Rochkind, M., Pasternak, S., and Paz, Y., 2014, Using dyes for evaluating photocatalytic properties: a critical review, Molecules, 20 (1), 88–110.

[6] Inyinbor, A.A., Adekola, F.A., and Olatunji, G.A., 2015, Adsorption of Rhodamine B dye from aqueous solution on Irvingia gabonensis biomass: Kinetics and thermodynamics studies, S. Afr. J. Chem., 68, 115–125.

[7] Gillman, P.K., 2011, CNS toxicity involving methylene blue: The exemplar for understanding and predicting drug interactions that precipitate serotonin toxicity, J. Psychopharmacol., 25 (3), 429–436.

[8] Abbasi, M., and Asl, N.R., 2008, Sonochemical degradation of Basic Blue 41 dye assisted by nanoTiO2 and H2O2, J. Hazard. Mater., 153 (3), 942–947.

[9] Gupta, V.K., Jain, R., Mittal, A., Mathur, M., and Sikarwar, S., 2007, Photochemical degradation of the hazardous dye Safranin-T using TiO2 catalyst, J. Colloid Interface Sci., 309 (2), 464–469.

[10] Fan, L., Zhou, Y., Yang, W., Chen, G., and Yang, F., 2008, Electrochemical degradation of aqueous solution of Amaranth azo dye on ACF under potentiostatic model, Dyes Pigm., 76 (2), 440–446.

[11] Sachdeva, S., and Kumar, A., 2009, Preparation of nanoporous composite carbon membrane for separation of rhodamine B dye, J. Membr. Sci., 329 (1-2), 2–10.

[12] Ding, L., Zou, B., Gao, W., Liu, Q., Wang, Z., Guo, Y., Wang, X., and Liu, Y., 2014, Adsorption of Rhodamine-B from aqueous solution using treated rice husk-based activated carbon, Colloids Surf., A, 446, 1–7.

[13] Malik, P., and Saha, S., 2003, Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst, Sep. Purif. Technol., 31 (3), 241–250.

[14] Brião, G.V., Jahn, S.L., Foletto, E.L., and Dotto, G.L., 2017, Adsorption of crystal violet dye onto a mesoporous ZSM-5 zeolite synthetized using chitin as template, J. Colloid Interface Sci., 508, 313–322.

[15] Heibati, B., Rodriguez-Couto, S., Amrane, A., Rafatullah, M., Hawari, A., and Al-Ghouti, M.A., 2014, Uptake of Reactive Black 5 by pumice and walnut activated carbon: Chemistry and adsorption mechanisms, J. Ind. Eng. Chem., 20 (5), 2939–2947.

[16] Hammed, A.K., Dewayanto, N., Du, D., Ab Rahim, M.H., and Nordin, M.R., 2016, Novel modified ZSM-5 as an efficient adsorbent for methylene blue removal, J. Environ. Chem. Eng., 4 (3), 2607–2616.

[17] Lamia, M., Fatiha, D., Bouchekara, B., and Ayada, D., 2016, Adsorption of Methyl Green onto Zeolite ZSM-5(pyrr.) in aqueous solution, Orient. J. Chem., 32 (1), 171–180.

[18] Nejad-Darzi, S.K.H., Samadi-Maybodi, A., and Ghobakhluo, M., 2013, Synthesis and characterization of modified ZSM-5 nanozeolite and their applications in adsorption of Acridine Orange dye from aqueous solution, J. Porous Mater., 20 (4), 909–916.

[19] Jin, H., Ansari, M.B., Jeong, E.Y., and Park, S.E., 2012, Effect of mesoporosity on selective benzylation of aromatics with benzyl alcohol over mesoporous ZSM-5, J. Catal., 291, 55–62.

[20] Sabarish, R., and Unnikrishnan, G., 2017, Synthesis, characterization and catalytic activity of hierarchical ZSM-5 templated by carboxymethyl cellulose, Powder Technol., 320, 412–419.

[21] Yue, Y., Gu, L., Zhou, Y., Liu, H., Yuan, P., Zhu, H., Bai, Z., and Bao, X., 2017, Template-free synthesis and catalytic applications of microporous and hierarchical ZSM-5 zeolites from natural aluminosilicate minerals, Ind. Eng. Chem. Res., 56 (36), 10069–10077.

[22] Holmes, S.M., Khoo, S.H., and Kovo, A.S., 2011, The direct conversion of impure natural kaolin into pure zeolite catalysts, Green Chem., 13 (5), 1152–1154.

[23] Damiyine, B., Guenbour, A., and Boussen, R., 2017, Rhodamine B adsorption on natural and modified Moroccan clay with cetyltrimethylammonium bromide: Kinetics, equilibrium and thermodynamics, J. Mater. Environ. Sci., 12 (3), 860–871.

[24] Ngapa, Y.D., Sugiarti, S., and Abidin, Z., 2018, Hydrothermal transformation of natural zeolite from Ende-NTT and its application as adsorbent of cationic dye, Indones. J. Chem., 16 (2), 138–143.

[25] Vezentsev, A.I., Thuy, D.M., Goldovskaya-Peristaya, L.F., and Glukhareva, N.A., 2018, Adsorption of methylene blue on the composite sorbent based on bentonite-like clay and hydroxyapatite, Indones. J. Chem., 18 (4), 733–741.

[26] Santosa, S.J., Kunarti, E.S., Aprilita, N.H., Wulandari, B., and Bawani, D.N., 2019, Sorption mechanism and performance of peat soil humin for methylene blue and p-nitrophenol, Indones. J. Chem., 19 (1), 198–210.

[27] Hartanto, D., Yuan, L.S., Sari, S.M., Sugiarso, D., Murwani, I.K., Ersam, T., Prasetyoko, D., and Nur, H., 2016, Can kaolin function as source of alumina in the synthesis of ZSM-5 without an organic template using a seeding technique?, Malays. J. Fundam. Appl. Sci., 12, 85-90.

[28] Vijayaraghavan, K., Padmesh, T., Palanivelu, K., and Velan, M., 2006, Biosorption of nickel(II) ions onto Sargassum wightii: Application of two-parameter and three-parameter isotherm models, J. Hazard. Mater., 133 (1-3), 304–308.

[29] Hamdaoui, O., and Naffrechoux, E., 2007, Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon Part I. Two-parameter models and equations allowing determination of thermodynamic parameters, J. Hazard. Mater., 147 (1-2), 381–394.

[30] Prasetyoko, D., Ayunanda, N., Fansuri, H., Hartanto, D., and Ramli, Z., 2012, Phase transformation of rice husk ash in the synthesis of ZSM-5 without organic template, J. Math. Fundam. Sci., 44 (3), 250–262.

[31] Mohamed, R.M., Fouad, O.A., Ismail, A.A., and Ibrahim, I.A., 2005, Influence of crystallization times on the synthesis of nanosized ZSM-5, Mater. Lett., 59 (27), 3441–3444.

[32] Armaroli, T., Simon, L.J., Digne, M., Montanari, T., Bevilacqua, M., Valtchev, V., Patarin, J., and Busca, G., 2006, Effects of crystal size and Si/Al ratio on the surface properties of H-ZSM-5 zeolites, Appl. Catal., A, 306, 78–84.

[33] Cychosz, K.A., and Thommes, M., 2018, Progress in the physisorption characterization of nanoporous gas storage materials, Engineering, 4 (4), 559–566.

[34] Wang, T., Lu, X., and Yan, Y., 2010, Synthesis, characterization and crystallization mechanism of SAPOs from natural kaolinite, Microporous Mesoporous Mater., 136 (1-3), 138–147.

[35] Canning, J., Huyang, G., Ma, M., Beavis, A., Bishop, D., Cook, K., McDonagh, A., Shi, D., Peng, G.D., and Crossley, M., 2014, Percolation diffusion into self-assembled mesoporous silica microfibres, Nanomaterials, 4, 157–174.

[36] Chen, C., Chen, Y., Lu, Z., Qian, M., Xie, H., and Tay, F.R., 2017, The effects of water on degradation of the zirconia-resin bond, J. Dent., 64, 23–29.

[37] Eren, Z., and Acar, F.N., 2006, Adsorption of Reactive Black 5 from an aqueous solution: equilibrium and kinetic studies, Desalination, 194 (1-3), 1–10.

[38] Dada, A.O., Olalekan, A.P., Olatunya, A.M., and Dada, O., 2012, Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk, IOSR J. Appl. Chem., 3 (1), 38–45.

[39] Foo, K.Y., and Hameed, B.H., 2010, Insights into the modeling of adsorption isotherm systems, Chem. Eng. J., 156 (1), 2–10.

[40] Allen, S.J., Mckay, G., and Porter, J.F., 2004, Adsorption isotherm models for basic dye adsorption by peat in single and binary component systems, J. Colloid Interface Sci., 280 (2), 322–333.

[41] Esmaeili, S., Zanjanchi, M.A., Golmojdeh, H., and Mizani, F., 2018, Increasing the adsorption capability of mordenite and Y zeolites via post-synthesis chemical/physical treatments in order to remove cationic dyes from polluted water, Water Environ. J., 0, 1–18.

[42] Selvam, P.P., Preethi, S., Basakaralingam, P., Thinakaran, N., Sivasamy, A., and Sivanesan, S., 2008, Removal of rhodamine B from aqueous solution by adsorption onto sodium montmorillonite, J. Hazard. Mater., 155 (1-2), 39–44.

[43] Largitte, L., and Pasquier, R., 2016, A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon, Chem. Eng. Res. Des., 109, 495–504.

[44] Ip, A.W.M., Barford, J.P., and McKay, G., 2010, A comparative study on the kinetics and mechanisms of removal of Reactive Black 5 by adsorption onto activated carbons and bone char, Chem. Eng. J., 157 (2-3), 434–442.

[45] Qiu, H., Lv, L., Pan, B., Zhang, Q., Zhang, W., and Zhang, Q., 2009, Critical review in adsorption kinetic models, J. Zhejiang Univ. Sci. A, 10 (5), 716–724.



DOI: https://doi.org/10.22146/ijc.41369

Article Metrics

Abstract views : 313 | views : 304


Copyright (c) 2019 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemisty (ISSN 1411-9420 / 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.