Synthesis of Silica-Salen Derivative from Rice Husk Ash and its Use for Extraction of Divalent Metal Ions Co(II), Ni(II) and Cu(II)

https://doi.org/10.22146/ijc.38558

Duha Hussien Attol(1), Hayder Hamied Mihsen(2*)

(1) Department of Chemistry, College of Science, University of Kerbala, Karbala 56001, Iraq
(2) Department of Chemistry, College of Science, University of Kerbala, Karbala 56001, Iraq
(*) Corresponding Author

Abstract


Rice husk ash (RHA) was used to prepare sodium silicate, which in turn was functionalized with 3-(chloropropyl)triethoxysilane employing the sol-gel technique to form RHACCl. Chloro group in RHACCl was replaced with iodo group forming RHACI. Ethylenediamine was immobilized on RHACI in order to prepare it for the reaction with salicylaldehyde to form a silica derivative-salen. FT-IR analysis indicated the presence of secondary amine and –NH and C=N absorption bands. XRD analysis revealed the occurrence of the broad diffused peak with maximum intensity at 22–23° (2θ). BET measurements showed also that the surface area of the prepared compound is 274.55 m2/g. Elemental analysis proved the existence of nitrogen in the structure of the prepared compound. The silica derivative-salen showed high potential for extraction and removal of heavy contaminating metal ions Ni(II), Cu(II), and Co(II) from aqueous solutions. The kinetic study demonstrates that the adsorption of the metal ions follows the pseudo-second order.


Keywords


amorphous silica; salicylaldehyde; surface area; preconcentration process; uptake capacity

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References

[1] Bose, S., Ganayee, M.A., Mondal, B., Baidya, A., Chennu, S., Mohanty, J.S., and Pradeep, T., 2018, Synthesis of silicon nanoparticles from rice husk and their use as sustainable fluorophores for white light emission, ACS Sustainable Chem. Eng., 6 (5), 6203–6210.

[2] Shen, Y., 2017, Rice husk silica derived nanomaterials for sustainable applications, Renewable Sustainable Energy Rev., 80, 453–466.

[3] Inba, P.J.K., Annaraj, B., Thalamuthu, S., and Neelakantan, M.A., 2013, Cu(II), Ni(II), and Zn(II) complexes of salan-type ligand containing ester groups : Synthesis, characterization, electrochemical properties, and in vitro biological activities, Bioinorg. Chem. Appl., 2013, 439848.

[4] Tahmasbi, L., Sedaghat, T., Motamedi, H., and Kooti, M., 2018, Mesoporous silica nanoparticles supported copper(II) and nickel(II) Schiff base complexes: Synthesis, characterization, antibacterial activity and enzyme immobilization, J. Solid State Chem., 258, 517–525.

[5] El-Kurd, H.M., El-Nahhal, I.M., and El-Ashgar, N.M., 2005, Synthesis of new polysiloxane-immobilized ligand system di(amidomethyl)aminetetraacetic acid, Phosphorus Sulfur Silicon Relat. Elem., 180 (7), 1657–1671.

[6] El-Nahhal, I.M., and El-Ashgar, N.M., 2007, A review on polysiloxane-immobilized ligand systems: Synthesis, characterization and applications, J. Organomet. Chem., 692 (14), 2861–2886.

[7] El-Ashgar, N.M., El-Nahhal, I.M., Chehimi, M.M., Babonneau, F., and Livage, J., 2010, Extraction of Co, Ni, Cu, Zn and Cd ions using 2-aminophenylaminopropylpolysiloxane, Environ. Chem. Lett., 8 (4), 311–316.

[8] El-Nahhal, I.M., El-Shetary, B.A., Salib, K.A.R., El-Ashgar, N.M., and El-Hashash, A.M., 2001, Uptake of divalent metal ions (Cu2+, Ni2+, and Co2+) by polysiloxane immobilized triamine-thiol and thiol-acetate ligand system, Anal. Lett., 34 (12), 2189–2202.

[9] Hao, S., Verlotta, A., Aprea, P., Pepe, F., Caputo, D., and Zhu, W., 2016, Optimal synthesis of amino-functionalized mesoporous silicas for the adsorption of heavy metal ions, Microporous Mesoporous Mater., 236, 250–259.

[10] Ezzeddine, Z., Batonneau-Gener, I., Pouilloux, Y., Hamad, H., Saad, Z., and Kazpard, V., 2015, Divalent heavy metals adsorption onto different types of EDTA-modified mesoporous materials: Effectiveness and complexation rate, Microporous Mesoporous Mater., 212, 125–136.

[11] Das, T., Roy, A., Uyama, H., Roy, P., and Nandi, M., 2017, 2-Hydroxy-naphthyl functionalized mesoporous silica for fluorescence sensing and removal of aluminum ions, Dalton Trans., 46 (22), 7317–7326.

[12] El-Nahhal, I.M., Zaggout, F.R., and El-Ashgar, N.M., 2000, Uptake of divalent metal ions (Cu, Zn and Cd) by polysiloxane immobilized monoamine ligand system, Anal. Lett., 33 (10), 2031–2053.

[13] Chen, L., Li, B.D., Xu, Q.X., and Liu, D.B., 2013, A silica gel supported cobalt(II) Schiff base complex as efficient and recyclable heterogeneous catalyst for the selective aerobic oxidation of alkyl aromatics, Chin. Chem. Lett., 24 (9), 849–852.

[14] Mihsen, H., and Sobh, H., 2018, Preparation and characterization of thiourea-silica hybrid as heterogenous catalyst, Asian J. Chem., 30 (5), 937–943.

[15] Das, D.D., and Sayari, A., 2007, Applications of pore-expanded mesoporous silica 6. Novel synthesis of monodispersed supported palladium nanoparticles and their catalytic activity for Suzuki reaction, J. Catal., 246 (1), 60–65.

[16] Das, D.D., and Sayari, A., 2007, Amine grafted pore-expanded MCM-41 as base catalysts, Stud. Surf. Sci. Catal., 170, 1197–1204.

[17] Chen, H., Wang, W., Martin, J.C., Oliphant, A.J., Doerr, P.A., Xu, J.F., DeBorn, K.M., Chen, C., and Sun, L., 2013, Extraction of lignocellulose and synthesis of porous silica nanoparticles from rice husks: A comprehensive utilization of rice husk biomass, ACS Sustainable Chem. Eng., 1 (2), 254–259.

[18] Govindarao, V.M.H., 1980, Utilization of rice husk-a preliminary-analysis, J. Sci. Ind. Res., 39 (9), 495–515.

[19] Carmona, V.B., Oliveira, R.M., Silva, W.T.L., Mattoso, L.H.C., and Marconcini, J.M., 2013, Nanosilica from rice husk: Extraction and characterization, Ind. Crops Prod., 43 (1), 291–296.

[20] Leyden, D.E., and Luttrell, G.H., 1975, Preconcentration of trace metals using chelating groups immobilized via silylation, Anal. Chem., 47 (9), 1612–1617.

[21] Leyden, D.E., Steele, M.L., Jablonski, B.B., and Somoano, R.B., 1978, Structural studies of immobilized ethylenediamine as a preconcentrating agent for molybdate and tungstate, Anal. Chim. Acta, 100, 545–554.

[22] El-Nahhal, I.M., Chehimi, M., and Selmane, M., 2017, Synthesis and structural characterization of G-SBA-IDA, G-SBA-EDTA and G-SBA-DTPA modified mesoporous SBA-15 silica and their application for removal of toxic metal ions pollutants, Silicon, 10 (3), 981–993.

[23] El-Ashgar, N.M., Silmi, M.K., El-Nahhal, I.M., Chehimi, M.M., and Babonneau, F., 2015, Template synthesis of iminodiacetic acid polysiloxane immobilized ligand systems and their metal uptake capacity, Silicon, 9 (4), 563–575.

[24] El-Ashgar, N.M., El-Nahhal, I.M., Chehimi, M.M., Babonneau, F., and Livage, J., 2012, Synthesis of polysiloxane-immobilized monoamine, diamine, and triamine ligand systems in the presence of CTAB and their applications, Phosphorus Sulfur Silicon Relat. Elem., 187 (3), 392–402.

[25] Hastuti, S., Nuryono, and Kuncaka, A., 2015, L-arginine-modified silica for adsorption of gold(III), Indones. J. Chem., 15 (2), 108–115.

[26] Ahmed, A.E., and Adam, F., 2007, Indium incorporated silica from rice husk and its catalytic activity, Microporous Mesoporous Mater., 103 (1–3), 284–295.

[27] Adam, F., Osman, H., and Hello, K.M., 2009, The immobilization of 3-(chloropropyl)triethoxysilane onto silica by a simple one-pot synthesis, J. Colloid Interface Sci., 331 (1), 143–147.

[28] Ahmed, I., and Parish, R.V., 1993, Insoluble ligands and their applications: IV. Polysiloxane-bis(2-aminoethyl)amine ligands and some derivatives, J. Organomet. Chem., 452 (1-2), 23–28.

[29] Nandi, M., Roy, P., Uyama, H., and Bhaumik, A., 2011, Functionalized mesoporous silica supported copper(II) and nickel(II) catalysts for liquid phase oxidation of olefins, Dalton Trans., 40 (46), 12510–12518.

[30] Thuadaij, N., and Nuntiya, A., 2008, Synthesis and characterization of nanosilica from rice husk ash prepared by precipitation method, J. Nat. Sci., 7 (1), 59–65.

[31] El-Nahhal, I.M., El-Ashgar, N.M., Chehimi, M.M., Bargiela, P., Maquet, J., Babonneau, F., and Livage, J., 2003, Metal uptake by porous iminobis(N-2-aminoethylacetamide)-modified polysiloxane ligand system, Microporous Mesoporous Mater., 65 (2-3), 299–310.

[32] Hao, S., Zhong, Y., Pepe, F., and Zhu, W., 2012, Adsorption of Pb2+ and Cu2+ on anionic surfactant-templated amino-functionalized mesoporous silicas, Chem. Eng. J., 189-190, 160–167.

[33] Harlick, P.J.E., and Sayari, A., 2007, Applications of pore-expanded mesoporous silica. 5. Triamine grafted material with exceptional CO2 dynamic and equilibrium adsorption performance, Ind. Eng. Chem. Res., 46 (2), 446–458.

[34] Akl, M.A., Kenawy, I.M.M., and Lasheen, R.R., 2004, Organically modified silica gel and flame atomic absorption spectrometry: Employment for separation and preconcentration of nine trace heavy metals for their determination in natural aqueous systems, Microchem. J., 78 (2), 143–156.

[35] Thommes, M., 2010, Physical adsorption characterization of nanoporous materials, Chem. Ing. Tech., 82 (7), 1059–1073.

[36] Samarghandi, M.R., Zarrabi, M., Sepehr, M.N., Panahi, R., and Foroghi, M., 2012, Removal of Acid Red 14 by Pumice Stone as a Low-Cost Adsorbent : Kinetic and Equilibrium Study, Iran. J. Chem. Chem. Eng., 31 (3), 19–27.

[37] Anbalagan, K., Senthil Kumar, P., Sangita Gayatri, K., Shahul Hameed, S., Sindhuja, M., Prabhakaran, C., and Karthikeyan, R., 2015, Removal and recovery of Ni(II) ions from synthetic wastewater using surface modified Strychnos potatorum seeds: Experimental optimization and mechanism, Desalin. Water Treat., 53 (1), 171–182.

[38] Monier, M., Ayad, D.M., Wei, Y., and Sarhan, A.A., 2010, Adsorption of Cu(II), Co(II), and Ni(II) ions by modified magnetic chitosan chelating resin, J. Hazard. Mater., 177 (1-3), 962–970.

[39] Widjonarko, D.M., Jumina, Kartini, I., and Nuryono, 2014, Phosphonate modified silica for adsorption of Co(II), Ni(II), Cu(II) and Zn(II), Indones. J. Chem., 14 (2), 143–151.

[40] Wu, S., Wang, F., Yuan, H., Zhang, L., Mao, S., Liu, X., Alharbi, N.S., Rohani, S., and Lu, J., 2018, Fabrication of xanthate-modified chitosan/poly(N-isopropylacrylamide) composite hydrogel for the selective adsorption of Cu(II), Pb(II) and Ni(II) metal ions, Chem. Eng. Res. Des., 139, 197–210.



DOI: https://doi.org/10.22146/ijc.38558

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