Adsorption of Methylene Blue on the Composite Sorbent Based on Bentonite-Like Clay and Hydroxyapatite

Alexandr Ivanovich Vezentsev(1), Dang Minh Thuy(2*), Lidia Fedotovna Goldovskaya-Peristaya(3), Nadezhda Alexandrovna Glukhareva(4)

(1) Belgorod State National Research University, 85 Pobedy St., Belgorod 308015, Russia
(2) Belgorod State National Research University, 85 Pobedy St., Belgorod 308015, Russia
(3) Belgorod State National Research University, 85 Pobedy St., Belgorod 308015, Russia
(4) Belgorod State National Research University, 85 Pobedy St., Belgorod 308015, Russia
(*) Corresponding Author


The adsorption of methylene blue from model aqueous solutions on bentonite-like clay, hydroxyapatite, and a composite sorbent has been investigated. The kinetic and thermodynamic parameters of adsorption in the temperature range 298–333 К have been calculated. The process is found to obey Langmuir isotherm equation. It is spontaneous but slightly endothermic. The maximal sorption capacity of the composite sorbent toward methylene blue is 175.4 mg/g at 25 °С that is 1.3 times more than that for bentonite-like clay and 17.8 times more than that for hydroxyapatite. Kinetics of the process is due to the combination of external and internal diffusion and can be described better by the model of pseudo-second order reaction.


adsorption; thermodynamics; methylene blue; composite sorbent

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[1] Zhang, F., Zhao, Z., Tan, R., Guo, Y., Cao, L., Chen, L., Li, J., Xu, W., Yang, Y., and Song, W., 2012, Selective and effective adsorption of methyl blue by barium phosphate nano-flake, J. Colloid Interface Sci., 386 (1), 277–284.

[2] Hao, O.J., Kim, H., and Chiang, P.C., 2000, Decolorization of wastewater, Crit. Rev. Environ. Sci. Technol., 30 (4), 449–505.

[3] Gupta, N., Kushwaha, A.K., and Chattopadhyaya, M.C., 2012, Adsorption studies of cationic dyes onto Ashoka (Saraca asoca) leaf powder, J. Taiwan Inst. Chem. Eng., 43 (4), 604–613.

[4] Brown, M.A., and DeVito, S.C., 1993, Predicting azo dye toxicity, Crit. Rev. Environ. Sci. Technol., 23 (3), 249–324.

[5] Kapdan, I.K., and Kargi, F., 2002, Simultaneous biodegradation and adsorption of textile dyestuff in an activated sludge unit, Process Biochem., 37 (9), 973–981.

[6] Prasad, R.K., 2009, Color removal from distillery spent wash through coagulation using Moringa oleifera seeds: Use of optimum response surface methodology, J. Hazard. Mater., 165 (1-3), 804–811.

[7] Solozhenko, E.G., Soboleva, N.M., and Goncharuk, V. V., 1995, Decolourization of azodye solutions by Fenton’s oxidation, Water Res., 29 (9), 2206–2210.

[8] Buckley, C.A., 1992, Membrane technology for the treatment of dyehouse effluents, Water Sci. Technol., 25 (10), 203–209.

[9] Panizza, M., Barbucci, A., Ricotti, R., and Cerisola, G., 2007, Electrochemical degradation of methylene blue, Sep. Purif. Technol., 54 (3), 382–387.

[10] Ngapa, Y.D., Sugiarti, S., and Abidin, Z., 2016, Hydrothermal transformation of natural zeolite from Ende-NTT and its application as adsorbent of cationic dye, Indones. J. Chem., 16 (2), 138–143.

[11] Zhang, J., Ping, Q., Niu, M., Shi, H., and Li, N., 2013, Kinetics and equilibrium studies from the methylene blue adsorption on diatomite treated with sodium hydroxide, Appl. Clay Sci., 83-84, 12–16.

[12] Akar, T., Anilan, B., Gorgulu, A., and Akar, S.T., 2009, Assessment of cationic dye biosorption characteristics of untreated and non-conventional biomass: Pyracantha coccinea berries, J. Hazard. Mater., 168 (2-3), 1302–1309.

[13] Ciobanu, G., Ilisei, S., Harja, M., and Luca, C., 2013, Removal of Reactive Blue 204 dye from aqueous solutions by adsorption onto nanohydroxyapatite, Sci. Adv. Mater., 5 (8), 1090–1096.

[14] Wei, W., Yang, L., Zhong, W.H., Li, S.Y., Cui, J., and Wei, Z.G., 2015, Fast removal of methylene blue from aqueous solution by adsorption onto poorly crystalline hydroxyapatite nanoparticles, Dig. J. Nanomater. Biostruct., 10 (4), 1343–1363.

[15] Muzakky, and Supriyanto, C., 2016, Modification of three types of bentonite with zirconium oxide chloride (ZOC) of local products using intercalation process, Indones. J. Chem., 16 (1), 14–19.

[16] Scheckel, K.G., Diamond, G.L., Burgess, M.F., Klotzbach, J.M., Maddaloni, M., Miller, B.W., Partridge, C.R., and Serda, S.M., 2013, Amending soils with phosphate as means to mitigate soil lead hazard: A critical review of the state of the science, J. Toxicol. Environ. Health Part B, 16 (6), 337–380.

[17] Sunarso, Sutarno, Tsuru, K., Ana, I.D., and Ishikawa, K., 2011, Effect of crosslinking to the mechanical property of apatite gelatin hybrid for bone substitution purposes, Indones. J. Chem., 11 (3), 267–272.

[18] Wang, Y., Chen, N., Wei, W., Cui, J., and Wei, Z., 2011, Enhanced adsorption of fluoride from aqueous solution onto nanosized hydroxyapatite by low-molecular-weight organic acids, Desalination., 276 (1-3), 161–168.

[19] Dong, L., Zhu, Z., Qiu, Y., and Zhao, J., 2010, Removal of lead from aqueous solution by hydroxyapatite/magnetite composite adsorbent, Chem. Eng. J., 165 (3), 827–834.

[20] Jang, S.H., Jeong, Y.G., Min, B.G., Lyoo, W.S., and Lee, S.C., 2008, Preparation and lead ion removal property of hydroxyapatite/polyacrylamide composite hydrogels, J. Hazard. Mater., 159 (2-3), 294–299.

[21] Jang, S.H., Min, B.G., Jeong, Y.G., Lyoo, W.S., and Lee, S.C., 2008, Removal of lead ions in aqueous solution by hydroxyapatite/polyurethane composite foams, J. Hazard. Mater., 152 (3), 1285–1292.

[22] Hou, H., Zhou, R., Wu, P., and Wu, L., 2012, Removal of Congo red dye from aqueous solution with hydroxyapatite/chitosan composite, Chem. Eng. J., 212-213, 336–342.

[23] Choi, S., and Jeong, Y., 2008, The removal of heavy metals in aqueous solution by hydroxyapatite/cellulose composite, Fibers Polym., 9 (3), 267–270.

[24] Vezentsev, A.I., Peristaya, F.L., Glukhareva, N.A., and Thuy, D.M., 2018, A composite sorbent based on bentonite-like clay and hydroxyapatite, J. Fundam. Appl. Sci., 10 (4S), 1099–1111.

[25] Tarasevich, Y.I., Shkutkova, E.V., and Janusz, W., 2012, Sorption of ions of heavy metals from aqueous solutions on hydroxylapatite, J. Water Chem. Technol., 34 (3), 125–132.

[26]Sokolova, T.A., and Trofimov, S.Ya., 2009, Sorption Properties of Soils. Adsorption. Cation Exchange, eds., Chukov, S.N., and Pinski, D.L., Tula, Moskva, 172.

[27] Tahir, S.S., and Rauf, N., 2006, Removal of a cationic dye from aqueous solutions by adsorption onto bentonite clay, Chemosphere, 63 (11), 1842–1848.

[28] Weng, C.H., and Pan, Y.F., 2007, Adsorption of a cationic dye (methylene blue) onto spent activated clay, J. Hazard. Mater., 144 (1-2), 355–362.

[29] Kumar, K.V., Ramamurthi, V., and Sivanesan, S., 2005, Modeling the mechanism involved during the sorption of methylene blue onto fly ash, J. Colloid Interface Sci., 284 (1), 14–21.

[30] Porkodi, K., and Kumar, V., 2007, Equilibrium, kinetics and mechanism modeling and simulation of basic and acid dyes sorption onto jute fiber carbon: Eosin yellow, malachite green and crystal violet single component systems, J. Hazard. Mater., 143 (1-2), 311–327.

[31] Wang, S., and Li, H., 2007, Kinetic modelling and mechanism of dye adsorption on unburned carbon, Dyes Pigm., 72, 308–314.

[32] Chandrasekhar, S., and Pramada, P.N., 2006, Rice husk ash as an adsorbent for methylene blue-effect of ashing temperature, Adsorption, 12, 27–43.

[33] Zhou, X., and Zhou, X., 2014, The unit problem in the thermodynamic calculation of adsorption using the Langmuir equation, Chem. Eng. Commun., 201 (11), 1459–1467.

[34] Hong, S., Wen, C., He, J., Gan, F., and Ho, Y.S., 2009, Adsorption thermodynamics of Methylene Blue onto bentonite, J. Hazard. Mater., 167 (1-3), 630–633.

[35] Almeida, C.A.P., Debacher, N.A., Downs, A.J., Cottet, L., and Mello, C.A.D., 2009, Removal of methylene blue from colored effluents by adsorption on montmorillonite clay, J. Colloid Interface Sci., 332 (1), 46–53.


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