Solar Based Photocatalytic Decolorization of Four Commercial Reactive Dyes Utilizing Bound TiO2-Fe3O4 Nanocomposite

Yoanes Maria Vianney(1*), Ivana Rosalyn(2), Stephanie Angela(3)

(1) Department of Biology, Faculty of Biotechnology, University of Surabaya, Jl. Kalirungkut, Surabaya 60292, East Java, Indonesia
(2) Department of Chemical Engineering, Faculty of Engineering, University of Surabaya, Jl. Kalirungkut, Surabaya 60292, East Java, Indonesia
(3) Department of Chemical Engineering, Faculty of Engineering, University of Surabaya, Jl. Kalirungkut, Surabaya 60292, East Java, Indonesia
(*) Corresponding Author


Dye effluent is one of the most prominent source of water contamination. This study investigated the solar based photocatalytic decolorization of four commercial reactive dyes, which are Reactive Turquoise Blue G 133, Reactive Yellow M4g, Reactive Bordeaux B, and Reactive Red M8b using immobilized TiO2-Fe3O4 on three kind of binders as the support, specifically cyanoacrylate glue, oil-based paint, and white Portland cement on PVC plate. TiO2-Fe3O4 was synthesized using sol-gel method and placed in muffle furnace at 773 K. The composite of TiO2-Fe3O4 was characterized using SEM-EDX and XRD. White cement emerged as the best binder in term of the color removal efficiency of all four dyes compared to other binders, which were more than 90% color removal after 3 h of solar irradiation. Moreover, there was significant enhancement on color removal using immobilized photocatalyst on white cement compared to mobile photocatalyst. The kinetic of the decolorization performance followed the pseudo-first-order reaction. The apparent reaction rate constant was found to decrease along with the increase of the dye concentration. The photodecolorization kinetics fitted the Langmuir-Hinshelwood model. These protocols and results can be applied into textile industrial primary wastewater treatment using solar as a sustainable light and energy source.


decolorization; reactive dye; solar energy; TiO2-Fe3O4 photocatalyst

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[1] Ajmal, A., Majeed, I., Malik, R.N., Idriss, H., and Nadeem, M.A., 2014, Principles and mechanisms of photocatalytic dye degradation on TiO2 based photocatalysts: A comparative overview, RSC Adv., 4 (70), 37003–37026.

[2] Kore, U.B., and Shukla, S.R., 2017, Ionic‐liquid‐assisted mixed alkali system for reactive dye fixation in a batch process–optimisation through response surface methodology, Color. Technol., 133 (4), 325–333.

[3] Tabassum, A., Bhatti, H.N., Nouren, S., and Zahid, M., 2015, Catalytic potential of gourd peel peroxidase for biodegradation of synthetic recalcitrant dyes fuchsin acid and crystal violet, J. Anim. Plant Sci., 25 (3), 777–783.

[4] Solano, A.M.S., Martínez-Huitle, C.A., Garcia-Segura, S., El-Ghenymy, A., and Brillas, E., 2016, Application of electrochemical advanced oxidation processes with a boron-doped diamond anode to degrade acidic solutions of Reactive Blue 15 (Turquoise Blue) dye, Electrochim. Acta, 197, 210–220.

[5] Khatri, A., Peerzada, M.H., Mohsin, M., and White, M., 2015, A review on developments in dyeing cotton fabrics with reactive dyes for reducing effluent pollution, J. Cleaner Prod., 87, 50–57.

[6] Saravanan, R., Karthikeyan, S., Gupta, V.K., Sekaran, G., Narayanan, V., and Stephen, A., 2013, Enhanced photocatalytic activity of ZnO/CuO nanocomposite for the degradation of textile dye on visible light illumination, Mater. Sci. Eng., C, 33 (1), 91–98.

[7] Holkar, C.R., Jadhav, A.J., Pinjari, D.V., Mahamuni, N.M., and Pandit, A.B., 2016, A critical review on textile wastewater treatments: Possible approaches, J. Environ. Manage., 182, 351-366.

[8] Chung, K.T., 2016, Azo dyes and human health: A review, J. Environ. Sci. Health. Part C Environ. Carcinog. Ecotoxicol. Rev., 34 (4), 233–261.

[9] Chen, W., Xiao, H., Xu, H., Ding, T., and Gu, Y., 2015, Photodegradation of methylene blue by TiO2-Fe3O4-bentonite magnetic nanocomposite, Int. J. Photoenergy, 2015, 591428.

[10] Yanto, D.H.Y., Tachibana, S., and Itoh, K., 2014, Biodecolorization and biodegradation of textile dyes by the newly isolated saline-pH tolerant fungus Pestalotiopsis sp., J. Environ. Sci. Technol., 7 (1), 44–55.

[11] Gottlieb, A., Shaw, C., Smith, A., Wheatley, A., and Forsythe, S., 2003, The toxicity of textile reactive azo dyes after hydrolysis and decolourisation, J. Biotechnol., 101 (1), 49–56.

[12] Wang, Y.Z., 2000, Solar photocatalytic degradation of eight commercial dyes in TiO2 suspension, Water Res., 34 (3), 990–994.

[13] Aguedach, A., Brosillon, S., Morvan, J., and Lhadi, E.K., 2005, Photocatalytic degradation of azo-dyes reactive black 5 and reactive yellow 145 in water over a newly deposited titanium dioxide, Appl. Catal., B, 57 (1), 55–62.

[14] Jafari, H., and Afshar, S., 2016, Improved photodegradation of organic contaminants using nano‐TiO2 and TiO2–SiO2 deposited on Portland cement concrete blocks, Photochem. Photobiol., 92 (1), 87–101.

[15] Konstantinou, I.K., and Albanis, T.A., 2004, TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: A review, Appl. Catal., B, 49 (1), 1–14.

[16] Kansal, S.K., Singh, M., and Sud, D., 2007, Studies on photodegradation of two commercial dyes in aqueous phase using different photocatalysts, J. Hazard. Mater., 141 (3), 581–590.

[17] Xavier, S., Gandhimathi, R., Nidheesh, P.V., and Ramesh, S.T., 2015, Comparison of homogeneous and heterogeneous Fenton processes for the removal of reactive dye Magenta MB from aqueous solution, Desalin. Water Treat., 53 (1), 109–118.

[18] Soon, A.N., and Hameed, B.H., 2011, Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process, Desalination, 269 (1-3), 1–16.

[19] Rossi, A.F., Amaral-Silva, N., Martins, R.C., and Quinta-Ferreira, R.M., 2012, Heterogeneous Fenton using ceria based catalysts: Effects of the calcination temperature in the process efficiency, Appl. Catal., B, 111-112, 254–263.

[20] Zhang, J., Zhou, P., Liu, J., and Yu, J., 2014, New understanding of the difference of photocatalytic activity among anatase, rutile and brookite TiO2, Phys. Chem. Chem. Phys., 16 (38), 20382–20386.

[21] Syafei, D., Sugiarti, S., Darmawan, N., and Khotib, M, 2017, Synthesis and characterization of TiO2/carbon nanoparticle (C-Dot) composites and their application as photocatalysts to degrade of persistent organic pollutant, Indones. J. Chem., 17 (1), 37–42.

[22] Cai, A., Guo, A., and Ma, Z., 2017, Immobilization of TiO2 nanoparticles on Chlorella pyrenoidosa cells for enhanced visible-light-driven photocatalysis, Materials, 10 (5), 541.

[23] Malato, S., Blanco, J., Vidal, A., and Richter, C., 2002, Photocatalysis with solar energy at a pilot-plant scale: An overview, App. Catal., B, 37 (1), 1–15.

[24] Bandala, E.R., and Estrada, C., 2007, Comparison of solar collection geometries for application to photocatalytic degradation of organic contaminants, J. Sol. Energy Eng., 129 (1), 22–26.

[25] Muruganandham, M., and Swaminathan, M., 2004, Solar photocatalytic degradation of a reactive azo dye in TiO2-suspension, Sol. Energy Mater. Sol. Cells, 81 (4), 439–457.

[26] Daghrir, R., Drogui, P., and Robert, D., 2013, Modified TiO2 for environmental photocatalytic applications: A review, Ind. Eng. Chem. Res., 52 (10), 3581–3599.

[27] Yang, S., Yang, L., Liu, X., Xie, J., Zhang, X., Yu, B., Wu, R., Li, H., Chen, L., and Liu, J, 2015, TiO2-doped Fe3O4 nanoparticles as high-performance Fenton-like catalyst for dye decoloration, Sci. China Technol. Sci., 58 (5), 858–863.

[28] Koesnarpadi, S., Santosa, S.J., Siswanta, D., and Rusdiarso, B, 2017, Humic acid coated Fe3O4 nanoparticle for phenol sorption, Indones. J. Chem., 17 (2), 274–283.

[29] El Ghandoor, H., Zidan, H.M., Khalil, M.M., and Ismail, M.I.M., 2012, Synthesis and some physical properties of magnetite (Fe3O4) nanoparticles, Int. J. Electrochem. Sci., 7, 5734–5745.

[30] Neppolian, B., Kanel, S.R., Choi, H.C., Shankar, M.V., Arabindoo, B., and Murugesan, V., 2003, Photocatalytic degradation of reactive yellow 17 dye in aqueous solution in the presence of TiO2 with cement binder, Int. J. Photoenergy, 5 (2), 45–49.

[31] Matthews, R.W., 1991, Photooxidative degradation of coloured organics in water using supported catalysts TiO2 on sand, Water Res., 25 (10), 1169–1176.

[32] Määttä, J., Piispanen, M., Kymäläinen, H.R., Uusi-Rauva, A., Hurme, K.R., Areva, S., Sjoberg, A.M., and Hupa, L., 2007, Effects of UV-radiation on the cleanability of titanium dioxide-coated glazed ceramic tiles, J. Eur. Ceram. Soc., 27 (16), 4569–4574.

[33] Gao, Y., and Liu, H., 2005, Preparation and catalytic property study of a novel kind of suspended photocatalyst of TiO2-activated carbon immobilized on silicone rubber film, Mater. Chem. Phys., 92 (2-3), 604–608.

[34] Khataee, A.R., Amani-Ghadim, A.R., Farajzade, M.R., and Ourang, O.V., 2011, Photocatalytic activity of nanostructured TiO2‐modified white cement, J. Exp. Nanosci., 6 (2), 138–148.

[35] Agustina, T.E., Arsyad, F.S., and Abdullah M., 2013, Photocatalytic degradation of C.I. Reactive Red 2 using TiO2-coated PET plastic under solar irradiation, Adv. Mater. Res., 789, 180–188.

[36] Sahoo, C., Gupta, A.K., and Sasidharan-Pillai, I.M., 2012, Photocatalytic degradation of methylene blue dye from aqueous solution using silver ion-doped TiO2 and its application to the degradation of real textile wastewater, J. Environ. Sci. Health. Part A Toxic/Hazard. Subst. Environ. Eng., 47 (10), 1428–1438.

[37] Sun, Z., Chen, Y., Ke, Q., Yang, Y., and Yuan, J., 2002, Photocatalytic degradation of a cationic azo dye by TiO2/bentonite nanocomposite, J. Photochem. Photobiol., A, 149 (1-3), 169–174.

[38] Muruganandham, M., and Swaminathan, M, 2006, Photocatalytic decolourisation and degradation of Reactive Orange 4 by TiO2-UV process, Dyes Pigm., 68 (2-3), 133–142.

[39] Kazeminezhad, I., and Sadollahkhani, A., 2014, Photocatalytic degradation of Eriochrome black-T dye using ZnO nanoparticles, Mater. Lett., 120, 267–270.

[40] Ollis, D., Silva, C.G., and Faria, J., 2015, Simultaneous photochemical and photocatalyzed liquid phase reactions: Dye decolorization kinetics, Catal. Today, 240, 80–85.

[41] Liang, X., Zhong, Y., Zhu, S., Ma, L., Yuan, P., Zhu, J., He, H., and Jiang, Z, 2012, The contribution of vanadium and titanium on improving methylene blue decolorization through heterogeneous UV-Fenton reaction catalyzed by their co-doped magnetite, J. Hazard. Mater., 199-200, 247–254.

[42] Rauf, M.A., Bukallah, S.B., Hamadi, A., Sulaiman, A., and Hammadi, F., 2007, The effect of operational parameters on the photoinduced decoloration of dyes using a hybrid catalyst V2O5/TiO2, Chem. Eng. J., 129 (1), 167–172.

[43] Hanifehpour, Y., Soltani, B., Amani-Ghadim, A.R., Hedayati, B., Khomami, B., and Joo, S.W., 2016, Praseodymium-doped ZnS nanomaterials: Hydrothermal synthesis and characterization with enhanced visible light photocatalytic activity, J. Ind. Eng. Chem., 34, 41–50.

[44] Song, L., Zhang, S., Wu, X., and Wei, Q., 2012, Synthesis of porous and trigonal TiO2 nanoflake, its high activity for sonocatalytic degradation of rhodamine B and kinetic analysis, Ultrason. Sonochem., 19 (6), 1169–1173.

[45] Maruyama, I., Sakamoto, N., Matsui, K., and Igarashi, G., 2017, Microstructural changes in white Portland cement paste under the first drying process evaluated by WAXS, SAXS, and USAXS, Cem. Concr. Res., 91, 24–32.

[46] Zhang, Y.R., Kong, X.M., Lu, Z.B., Lu, Z.C., and Hou, S.S., 2015, Effects of the charge characteristics of polycarboxylate superplasticizers on the adsorption and the retardation in cement pastes, Cem. Concr. Res., 67, 184–196.

[47] Cárdenas, C., Tobón, J.I., García, C., and Vila, J., 2012, Functionalized building materials: Photocatalytic abatement of NOx by cement pastes blended with TiO2 nanoparticles, Constr. Build. Mater., 36, 820–825.

[48] Águia, C., Ângelo, J., Madeira, L.M., and Mendes, A., 2011, Photo-oxidation of NO using an exterior paint–screening of various commercial titania in powder pressed and paint films, J. Environ. Manage., 92 (7), 1724–1732.

[49] Águia, C., Ângelo, J., Madeira, L.M., and Mendes, A., 2011, Influence of paint components on photoactivity of P25 titania toward NO abatement, Polym. Degrad. Stab., 96 (5), 898–906.

[50] Matsumura, H., and Nakabayashi, N., 1988, Adhesive 4-META/MMA-TBB opaque resin with poly (methyl methacrylate)-coated titanium dioxide, J. Dent. Res., 67 (1), 29–32.

[51] Neppolian, B., Choi, H.C., Sakthivel, S., Arabindoo, B., and Murugesan, V., 2002, Solar/UV-induced photocatalytic degradation of three commercial textile dyes, J. Hazard. Mater., 89 (2-3), 303–317.

[52] Sahoo, C., and Gupta, A.K., 2015, Photocatalytic degradation of methyl blue by silver ion-doped titania: Identification of degradation products by GC-MS and IC analysis, J. Environ. Sci. Health. Part A Toxic/Hazard. Subst. Environ. Eng., 50 (13), 1333–1341.

[53] Kang, M.G., Park, H.S., and Kim, K.J., 2002, Effect of improved crystallinity of titanium silicalite-2 on photodecomposition of simple aromatic hydrocarbons, J. Photochem. Photobiol., A, 149 (1-3), 175–181.

[54] Marchis, T., Avetta, P., Bianco-Prevot, A., Fabbri, D., Viscardi, G., and Laurenti, E., 2011, Oxidative degradation of Remazol Turquoise Blue G 133 by soybean peroxidase, J. Inorg. Biochem., 105 (2), 321–327.

[55] Petrella, A., Boghetich, G., Petrella, M., Mastrorilli, P., Petruzzelli, V., and Petruzzelli, D., 2014, Photocatalytic degradation of azo dyes. Pilot plant investigation, Ind. Eng. Chem. Res., 53 (7), 2566–2571.


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