Hydrotreating of Sunan Candlenut (Reutealis trisperma Airy Shaw) Oil by Using NiMo-γAl2O3 as Renewable Energy

https://doi.org/10.22146/ijc.27274

Daliya Indra Setiawan(1*), Tun Tedja Irawadi(2), Zainal Alim Mas’ud(3)

(1) Research and Development Center Oil and Gas Technology “PPPTMGB LEMIGAS”, Ministry of Energy and Mineral Resources, Jl. Ciledug Raya Kav 109, Cipulir, Kebayoran Lama, Jakarta Selatan 12230, Indonesia
(2) Department of Chemistry, Bogor Agricultural University, Jl. Tanjung Kampus IPB Darmaga, Bogor 16680, West Java, Indonesia
(3) Department of Chemistry, Bogor Agricultural University, Jl. Tanjung Kampus IPB Darmaga, Bogor 16680, West Java, Indonesia
(*) Corresponding Author

Abstract


Hydrotreating process of Sunan candlenut oil by using NiMo-γAl2O3 catalyst has been successfully investigated. Preparation of NiMo-γAl2O3 catalyst by using dipping impregnation method generated catalyst used for hydrotreating process. This method consists of three stages: support activation, impregnation, and calcination. This factors influencing the process including temperature, pressure, and the ratio of Sunan candlenut oil to the H2 gas factor were examined. The hydrotreating product of fuel similar to oil was obtained at a minimum temperature of 380 °C, a pressure of 30–60 bar, and the ratio of the sample to H2 gas of 0.5–1. The diesel fuel from physical properties range for the density of 0.82–0.86 g/cm3, and kinematic viscosity of 2–6 cSt have been fulfilled by hydrotreating result. Gasoline, naphtha, diesel oil, and gas oil products of Sunan candlenut oil were obtained by distillation from hydrotreating process. Sunan candlenut oil fuel qualified fuel requirement.

Keywords


NiMo-γAl2O3 catalyst; renewable diesel; Sunan candlenut oil; distillation

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References

[1] Dewan Energi Nasional, 2014, Outlook Energy Indonesia 2014: Energy Development in Supporting Fuel Substitution Program, Pusat Teknologi Pengembangan Sumberdaya Energi (PTPSE), Jakarta, pp.2

[2] Yang, Y., Wang, Q., Zhang, X., Wang, L., and Li, G., 2013, Hydrotreating of C18 fatty acids to hydrocarbons on sulphided NiW/SiO2-Al2O3, Fuel Process. Technol., 116, 165–174.

[3] Aatola, H., Larmi, M., Sarjovaara, T., and Mikkonen, S., 2008, Hydrotreated vegetable oil (HVO) as a renewable diesel fuel: Trade-off between NOx particulate emission, and fuel consumption of a heavy duty engine, SAE Int. J. Engines, 1 (1), 1251–1262.

[4] Kiatkittipong, W., Phimsen, S., Kiatkittipong, K., Wongsakulphasatch, S., Laosiripojana, N., and Assabumrungrat, S., 2013, Diesel-like hydrocarbon production from hydroprocessing of relevant refining palm oil, Fuel Process. Technol., 116, 16–26.

[5] Liu, J., Fan, K., Tian, W., Liu, C., and Rong, L., 2012, Hydroprocessing of jatropha oil over NiMoCe/Al2O3 catalyst, Int. J. Hydrogen Energy, 37 (23), 17731–17737.

[6] Gong, S., Shinozaki, A., Shi, M., and Qian, E.W., 2012, Hydrotreating of jatropha oil over alumina based catalysts, Energy Fuels, 26 (4), 2394–2399.

[7] Krár, M., Kovács, S., Boda, L., Leveles, L., Thernesz, A., Wáhlné, I.H., and Hancsók, J., 2009, Fuel purpose hydrotreating of vegetable oil on NiMo–γAl2O3 catalyst, Hung. J. Ind. Chem., 37 (2), 107–111.

[8] Kovács, S., Kasza, T., Thernesz, A., Horváth I.W., and Hanscók, J., 2011, Fuel production by hydrotreating of triglycerides on NiMo/Al2O3/F catalyst, Chem. Eng. J., 176-177, 237–243.

[9] Kwon, K.C., Mayfield, H., Marolla, T., Nichols, B., and Mashburn, M., 2011, Catalytic deoxygenation of liquid biomass for hydrocarbon fuels, Renewable Energy, 36(3), 907-915.

[10] Pranowo, D., Syakir, M., Prastowo, B., Herman, M., Aunilah, A., and Sumanto, 2014. Pembuatan Biodiesel dari Kemiri Sunan (Reutealis trisperma Airy Shaw) dan Pemanfaatan Hasil Samping, IAARD Press, Jakarta.

[11] Sotelo-Boyás, R., Trejo-Zarrage, F., and Hernandez-Loyo, F.J., 2012, Hydroconversion of Triglycerides into Green Liquid Fuels, IntechOpen.

[12] Susanto, B.H., Nasikin, M., Sukirno, and Wijo, A., 2014, Synthesis of renewable diesel through hydrodeoxygenation using Pd/zeolite catalysts, Procedia Chem., 9, 139–150.

[13] Attanatho, L., 2012, Performance and Kinetic Studies of Hydrotreating of Bio-Oils in Microreactor, Dissertation, Oregon States University, Eugene (US).

[14] Hermida, L., Abdullah, A.Z., and Mohamed, A.R., 2015, Deoxygenation of fatty acid to produce diesel–like hydrocarbon: A review of process conditions, reaction kinetics and mechanism, Renewable Sustainable Energy Rev., 42, 1223–1333.

[15] Sankaranarayanan, T.M., Banu, M., Pandurangan, A., and Sivasanker, S., 2011, Hydroprocessing of sunflowers oil-gas oil blends over sulfide Ni-Mo-Al-zeolite beta composites, Bioresour. Technol., 102 (22), 10717–10723.

[16] Choudhary, T.V., and Phillips, C.B., 2011, Renewable fuels via catalytic hydrodeoxygenation, Appl. Catal., A, 397 (1-2), 1–12.

[17] Egeberg, R., Michaelsen, N., Skyum, L., and Zeuthen, P., 2010, Hydrotreating in the production of green diesel: A novel scheme enables co–processing of light gas oil and tall diesel to produce a renewable diesel meeting EN 590 specifications, http:/www.digitalrefining.com/article/1000156.

[18] Srifa, A., Faungnawakij, K., Itthibenchapong, V., Viriya-empikul, N., Charinpanitkul, T., and Assabumrungrat, S., 2014, Production of bio-hydrogenated diesel by catalytic hydrotreating of palm oil over NiMoS2/γ-Al2O3 catalyst, Bioresour. Technol., 158, 81–90.

[19] Wang, H., Yan, S., Salley, O.S., and Simon, K.Y., 2013, Support effects on hydrotreating of soybean oil over NiMo carbide catalyst, Fuel, 111, 81–87.

[20] Srifa, A., Faungnawakij, K., Itthibenchapong, V., and Assabumrungrat, S., 2015, Roles of monometallic catalysts in hydrodeoxigenation of palm oil to green diesel, Chem. Eng. J., 278, 249–258.

[21] Nasikin, M., and Susanto, B.H., 2010, Katalis Heterogen, UI Press, 18–19.



DOI: https://doi.org/10.22146/ijc.27274

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