Characteristics of Trace Elements in Volcanic ash of Kelud Eruption in East Java, Indonesia

https://doi.org/10.22146/ijc.26876

Diah Dwiana Lestiani(1*), Revi Apryani(2), Linda Lestari(3), Muhayatun Santoso(4), Eko Prabowo Hadisantoso(5), Syukria Kurniawati(6)

(1) Center for Applied Nuclear Science and Technology, National Nuclear Energy Agency, Jl. Tamansari 71, Bandung 40132, Indonesia
(2) Faculty of Natural Sciences and Mathematics, National Islamic University of Sunan Gunung Djati, Jl. AH Nasution 105, Bandung 40614, Indonesia
(3) Faculty of Natural Sciences and Mathematics, National Islamic University of Sunan Gunung Djati, Jl. AH Nasution 105, Bandung 40614, Indonesia
(4) Center for Applied Nuclear Science and Technology, National Nuclear Energy Agency, Jl. Tamansari 71, Bandung 40132, Indonesia
(5) Faculty of Natural Sciences and Mathematics, National Islamic University of Sunan Gunung Djati, Jl. AH Nasution 105, Bandung 40614, Indonesia
(6) Center for Applied Nuclear Science and Technology, National Nuclear Energy Agency, Jl. Tamansari 71, Bandung 40132, Indonesia
(*) Corresponding Author

Abstract


The eruption of Mount Kelud that occurred on February 13, 2014, ejected a huge plume of ash and sand exceeding 26 km into the air which moved west over the island. The elements content in volcanic ash is important information for further study such as the possibility to utilize the ash. In this study, the volcanic ashes collected from four affected areas in Java were analyzed using neutron activation analysis (NAA) with HPGe detector and X-ray fluorescence. Method validation was applied using the standard reference material SRM NIST 2711a Montana Soil with recovery and accuracy in a good agreement for all elements. The analysis results of volcanic ashes showed a wide range of elements, major elements Al, Ca, Fe, K, Mg, Mn, Na, Si and Ti, trace elements As, Cd, Cu, Co, Cr, V, Zn, Hf, Th and U, and rare earth elements were identified. The results showed heavy metals As, Cd, Cu, Co, Cr, and Pb were ranged 3.23–4.42, 17.63–24.09, 49.26–77.10, 10.86–16.03, 11.19–17.79 and 31.4–42.7 mg/kg, respectively, while rare earth elements such as Ce, Eu, La, and Sm were 9.84–18.43, 0.73–1.02, 2.25–5.66 and 1.34–2.63 mg/kg respectively. Comparison with other volcanic ashes from Indonesia such as Merapi and Sinabung and world volcanic ashes were applied. The results of the characteristic of elements in Kelud volcanic ash would be valuable information as reference data for their potential utilization.

Keywords


neutron activation analysis; X-ray fluorescence; volcanic ash; Kelud Volcano

Full Text:

Full Text PDF


References

[1] Kelud Volcano, http://www.ulb.ac.be/sciences/cvl/DKIPART2.pdf, accessed on April 2015

[2] Kristiansen, N.I., Prata, A.J., Stohl, A., and Carn, S.A., 2015, Stratospheric volcanic ash emissions from the 13 February 2014 Kelut eruption, Geophys. Res. Lett., 42 (2), 588–596.

[3] Global Volcanism Program, 2014, "Report on Kelut (Indonesia)", in Bulletin of the Global Volcanism Network, Wunderman, R., (ed.), Smithsonian Institution, Washington, D.C., 39 (2), 8-21.

[4] Ruggieri, F., Fernandez-Turiel, J.L., Saavedra, J., Gimeno, D., Polanco, E., Amigo, A., Galindo, G., and Caselli, A., 2012, Contribution of volcanic ashes to the regional geochemical balance: The 2008 eruption of Chaitén volcano, Southern Chile, Sci. Total Environ., 425, 75–88.

[5] Kusmartini, I., Syahfitri, W.Y.N., Kurniawati, S., Lestiani, D.D., and Santoso, M., 2017, Elemental characterization of Mt. Sinabung volcanic ash, Indonesia by neutron activation analysis, J. Phys. Conf. Ser., 860 (1), 12005.

[6] Horwell, C.J., and Baxter, P.J., 2006, The respiratory health hazards of volcanic ash: A review for volcanic health risk mitigation, Bull. Volcanol., 69 (1), 1–24.

[7] Fiantis, D., Nelson, M., Shamshuddin, J., Goh, T.B., and Van Ranst, E., 2011, Changes in the chemical and mineralogical properties of Mt. Talang volcanic ash in West Sumatra during the initial weathering phase, Commun. Soil Sci. Plant Anal., 42 (5), 569–585.

[8] Canion, B., Jacques, C., Landsberger. S., and Taftazani, A., 2012, Trace analysis of Indonesian volcanic ash using thermal and epithermal neutron activation analysis, Nukleonika, 57 (4), 585–589.

[9] Bourdier, J.L., Pratomo, I., Thouret, J.C., Boudon, G., and Vincent, P.M., 1997, Observation, stratigraphy, and eruptive processes of the 1990 eruption of Kelut volcano Indonesia, J. Volcanol. Geotherm. Res., 79 (3–4), 181–203.

[10] Greenberg, R.R., 2008, Pushing the limits of NAA: Accuracy, uncertainty and detection limits, J. Radioanal. Nucl. Chem., 278 (2), 231–240.

[11] Glascock, M.D., 2004, Overview of Neutron Activation Analysis, University of Missouri Research Reactor (MURR). Columbia, MO. http://archaeometry.missouri.edu/naa_overview.html, accessed on 7 Nov 2008.

[12] Watson, J.G., Chow, J.C., and Frazier, C.A., 1999, “X-ray Fluorescence Analysis of Ambient Air Analysis, in Handbook of Elemental Analysis of Airborne Particles, Landsberger, S., (ed.), Gordon and Breach Science Publisher, Amsterdam.

[13] Brouwer, P., 2006, Theory of XRF, 2nd ed., PANalytical BV, Almelo, Amsterdam.

[14] Syukria, K., Indah, K., Natalia, A., and Diah, D.L., 2012, Applicability of ED-XRF spectrometer for sediment analysis, Proceeding of Nuclear Analytical Technique, 152–158.

[15] Lestiani, D.D., Muhayatun, M., and Adventini, N., 2009, Application of neutron activation analysis in characterization of environmental SRM samples, Indones. J. Chem., 9 (2), 231–235.

[16] Oreščanin, V., Mikelić, I.L., Mikelić, L., and Lulić, S., 2008, Applicability of minipal 4 compact EDXRF spectrometer for soil and sediment analysis. X-Ray Spectrom., 37 (5), 508–511.

[17] Förster, J., 1996, Patterns of roof runoff contamination and their potential implications on practice and regulation of treatment and local infiltration, Water Sci. Technol., 33 (6),39–48.

[18] Liao, Z., Hu, W., Cao, J., Wang, X., Yao, S., Wu, H., and Wan, Y., 2016, Heterogeneous volcanism across the Permian–Triassic Boundary in South China and implications for the Latest Permian Mass Extinction: New evidence from volcanic ash layers in the Lower Yangtze Region, J. Asian Earth Sci., 127, 197–210.

[19] Ruggieri, F., Fernandez-Turiel, J.L., Saavedra, J., Gimeno, D., Valenzuela, E.P., and Naranjo, J.A., 2011, Environmental geochemistry of recent volcanic ashes from Southern Andes, Environ. Chem., 8 (3), 236–247.

[20] Nakagawa, M., and Ohba, T., 2003, Minerals in volcanic ash 1: Primary minerals and volcanic glass, Global Environ. Res., 6 (2), 41–51.

[21] Rahman, M., Sunaryo, S., and Susilo, A., 2014, Pendugaan struktur bawah permukaan 2½ dimensi di kawasan gunung api Kelud berdasarkan survei gravitasi, Natural B, 2 (3), 221–228.

[22] Characteristics of magma. http://www.tulane.edu/~sanelson/Natural_Disasters/volcan&magma.htm, accessed on 5 Sept 2015

[23] Daga, R., Guevara, S.R., Poire, D.G., and Arribére, M., 2014, Characterization of tephras dispersed by the recent eruptions of volcanoes Calbuco (1961), Chaitén (2008) and Cordón Caulle Complex (1961 and 2011), in Northern Patagonia, J. South Am. Earth Sci., 49, 1–14.

[24] Ruggieri, F., Saavedra, J., Fernandes-Turiel, J.L., Gimeno, D., and Garcia-Valles, M., 2010, Environmental geochemistry of ancient volcanic ashes, J. Hazard. Mater., 183 (1-3), 353–365.

[25] Tchounwou, P.B., Yedjou, C.G., Patlolla, A.K., and Sutton, D.J., 2012, Heavy metals toxicity and the environment, EXS, 101, 133–164.

[26] Ruggieri, F., Fernandez-Turiel, J., Saavedra, J., Gimeno, D., Valenzuela, E.P., Amigo, A., Galindo, G., and Caselli, A.T., 2012, Contribution of volcanic ashes to the regional geochemical balance: The 2008 eruption of Chaitén volcano, Southern Chile, Sci. Total Environ., 425, 75–88.

[27] Boynton, W.V., 1984, Chapter 3: Cosmochemistry of the rare earth elements: Meteorite studies, Dev. Geochem., 2, 63–114



DOI: https://doi.org/10.22146/ijc.26876

Article Metrics

Abstract views : 3484 | views : 3632


Copyright (c) 2018 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 

Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web Analytics View The Statistics of Indones. J. Chem.