Synthesis of Zeolite-X Supported on Kapok Fiber for CO2 Capture Material: Variation of Immersion Time during Fiber Activation

https://doi.org/10.22146/ijc.25162

Mada Mariana Lakapu(1), Nurul Widiastuti(2*)

(1) Department of Chemistry, Institut Teknologi Sepuluh Nopember (ITS), Jl. Arif Rahman Hakim, Surabaya 60111, Indonesia
(2) Department of Chemistry, Institut Teknologi Sepuluh Nopember (ITS), Jl. Arif Rahman Hakim, Surabaya 60111, Indonesia
(*) Corresponding Author

Abstract


Zeolite-X is a potential material for CO2 adsorption. To increase the performance of zeolite-X, kapok fiber was used as a support material. The growth of zeolite-X on the surface of kapok was affected by activation of the surface. This research aims to optimize the immersion time of kapok fiber using NaOH in order to achieve high crystallinity of the zeolite-X. The Zeolite-X supported on kapok fiber was synthesized by the simple hydrothermal method at immersion time variation of 12 to 36 h. XRD results show that zeolite-X on kapok surface has the highest crystallinity at immersion time of 24 h. The topography of kapok surface from AFM indicates that the surface was damaged due to peeling reaction of NaOH. SEM results show that zeolite-X has grown on the kapok surface in considerable amounts. From TGA analysis, it was shown that the thermal stability of zeolite-X supported on kapok surface was up to 300 °C. Adsorption of CO2 measured by gravimetric method shows that CO2 adsorption capacitywas up to 15.097 wt.% at room temperature.

Keywords


zeolite-X; kapok fiber; CO2 capture; adsorption

Full Text:

Full Text PDF


References

[1] Herzog, H., Meldon, J., and Hatton, A., 2009, "An RD&D "Pipeline" for Advanced Post-Combustion CO2 Capture Technologies" in Coal Without Carbon, An Investment Plan for Federal Action, Clean Air Task Force, Boston-MA, 37–58.

[2] Leung, D.Y.C., Caramanna, G., and Maroto-Valer, M.M., 2014, An overview of current status of carbon dioxide capture and storage technologies, Renewable Sustainable Energy Rev., 39, 426–443.

[3] Kumar, G.S., Viswandham, M., Gupta, A.V.S.S.K.S, Kumar, G.S., 2013, A review of pre-combustion CO2 capture in IGCC, Int. J. Res. Eng. Technol., 2 (5), 847–853.

[4] Songolzadeh, M., Ravanchi, M.T., and Soleimani, M., 2012, Carbon dioxide capture and storage: a general review on adsorbents, World Acad. Sci. Eng. Technol., 70, 225–232.

[5] Hedin, N., Andersson, L., Bergström, L., and Yan, J., 2013, Adsorbents for the post-combustion capture of CO2 using rapid temperature swing or vacuum swing adsorption, Appl. Energy, 104, 418–433.

[6] Wang, M., Lawal, A., Stephenson, P., Sidders, J., and Ramshaw, C., 2011, Post-combustion CO2 capture with chemical absorption: A state-of-the-art review, Chem. Eng. Res. Des., 89 (9), 1609–1624.

[7] Yu, L., Gong J., Zeng, C., and Zhang, L., 2013, Synthesis of binderless zeolite X microspheres and their CO2 adsorption properties, Sep. Purif. Technol., 118, 188–195.

[8] Siriwardane, R., Shen, M., Fisher, E., Poston, J. and Shamsi, A,. 2001, Adsorption and desorption of CO2 solid sorbents, J. Energy Environ. Res., 1 (1), 19–22.

[9] Deng, H., Yi, H., Tang, X., Yu, Q., Ning P., and Yang, L., 2012, Adsorption equilibrium for sulfur dioxide, nitric oxide, carbon dioxide, nitrogen on 13X and 5A zeolites, Chem. Eng. J., 188, 77–85.

[10] Hardie, S.M.L., Garnett, M.H., Fallick, A.E, Rowland, A.P., and Ostle, N.J., 2005, Carbon dioxide capture using a zeolite molecular sieve sampling system for isotopic (13C and 14C) studies of respiration, Radiocarbon, 47 (3), 441–451.

[11] Liu, W., Misra, M., Askeland, P., Drzal, L.T., and Mohanty, A.K., 2005, ‘Green’ composites from soy based plastic and pineapple leaf fiber: Fabrication and properties evaluation, Polymer, 46 (8), 2710–2721.

[12] Liu, J., Jiang, G., Liu, Y., Di, J., Wang, Y., Zhao, Z., Sun, Q., Xu, C., Gao, J., Duan, A., Liu, J., Wei, Y., Zhao, Y., and Jiang, L., 2014, Hierarchical macro-meso-microporous ZSM-5 zeolite hollow fibers with highly efficient catalytic cracking capability, Sci. Rep., 4, 7276.

[13] Kabir, M.M., Wang, H., Aravinthan, T., Cardona, F., and Lau, K.T., 2011, Effects of natural fibre surface on composite properties: A review, Proceedings of the 1st International Postgraduate Conference on Engineering, Designing and Developing the Built Environment for Sustainable Wellbeing (EDDBE2011), Queensland University of Technology, 94–99.

[14] Prachayawarakorn, J., Chaiwatyothin, S., Mueangta, S., and Hanchana, A., 2013, Effect of jute and kapok fibers on properties of thermoplastic cassava starch composites, Mater. Des., 47, 309–315.

[15] Zheng, Y., Wang, J., Zhu, Y., and Wang, A., 2015, Research and application of kapok fiber as an absorbing material: A mini review, J. Environ. Sci., 27, 21–32.

[16] Liu, J., and Wang, F., 2011, Influence of mercerization on micro-structure and properties of kapok blended yarns with different blending ratios, J. Eng. Fibers Fabr., 6 (3), 63–68.

[17] Witono, K., Irawan, Y.S., Soenoko, R., and Suryanto, H., 2013, Pengaruh perlakuan alkali (NaOH) terhadap morfologi dan kekuatan tarik serat mendong, Jurnal Rekayasa Mesin, 4 (3), 227–234

[18] Pejic, B.M., Kostic, M.M., Skundric, P.D., and Praskalo, J.Z., 2008, The effects of hemicelluloses and lignin removal on water uptake behavior of hemp fibers, Bioresour. Technol., 99 (15), 7152–7159.

[19] Pothan, L.A., George, J., and Thomas, S., 2002, Effect of fiber surface treatments on the fiber–matrix interaction in banana fiber reinforced polyester composites, Compos. Interfaces, 9 (4), 335–353.

[20] Mangal, R., Saxena, N.S., Sreekala, M.S., Thomson, S., and Singh, K., 2003, Thermal properties of pineapple leaf fiber reinforced composites, Mater. Sci. Eng., A, 339 (1-2), 281–285.



DOI: https://doi.org/10.22146/ijc.25162

Article Metrics

Abstract views : 3735 | views : 2381


Copyright (c) 2017 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 

Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web Analytics View The Statistics of Indones. J. Chem.