Adsorption of Remazol Brilliant Blue R Using Amino-Functionalized Organosilane in Aqueous Solution

Ozi Adi Saputra; Alifia Harista Rachma; Desi Suci Handayani

doi:10.22146/ijc.25097

Adsorption of Remazol Brilliant Blue R Using Amino-Functionalized Organosilane in Aqueous Solution

https://doi.org/10.22146/ijc.25097

Ozi Adi Saputra⁽¹⁾, Alifia Harista Rachma⁽²⁾, Desi Suci Handayani^(3*)

(1) Department of Chemistry, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta, Indonesia
(2) Department of Chemistry, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta, Indonesia
(3) Department of Chemistry, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta, Indonesia
(*) Corresponding Author

Abstract

Synthesis of amino functionalized organosilane (AFOS) via UV-irradiation method has been conducted. In this research, the precursors for synthesizing AFOS are 3-glycydiloxypropyl trimethoxysilane (GPTMS) and ethylene diamine. Synthesis of amino functionalized organosilane was performed for 16 h monitored by Infra-red spectroscopy technique. The morphological structure of AFOS was observed by scanning electron microscopy. The adsorption process was conducted in the batch method using Remazol Brilliant Blue R (RBBR) as anionic dye model. In this study, the pH, contact time and dyes concentration were varied to determine the optimum pH, kinetic and isotherm adsorption. Based on the calculation, the kinetic rate of the RBBR adsorbed onto AFOS was determined by k₂ (pseudo second-order). Moreover, the isotherm study showed that the Langmuir model fitted for the adsorption of RBBR onto AFOS with Q_m by 21.3 mg g^-1.

Keywords

adsorption; dye removal; organosilane; Remazol Brilliant Blue R

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DOI: https://doi.org/10.22146/ijc.25097