Production of Biodiesel from Seed Oil of Nyamplung (Calophyllum inophyllum) by Al-MCM-41 and Its Performance in Diesel Engine

Hendro Juwono(1*), Triyono Triyono(2), Sutarno Sutarno(3), Endang Tri Wahyuni(4), Ita Ulfin(5), Fredy Kurniawan(6),

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada
(5) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember
(6) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember
(*) Corresponding Author


Production of biodiesel from crude nyamplung oil (Calophyllum inophyllum) have been done by transesterification using Al-MCM-41 catalyst. Al-MCM-41 catalyst was obtained from impregnation of MCM-41 by Al. Sodium aluminate was added to MCM-41 until pH 11.5. The mixture was heated until 110 °C for 5 days. The calcination was performed at 500 °C, and then cooled at room temperature. The Al-MCM-41 obtained was characterized using SAXRD. Morphology of the surface was analyzed using SEM. The metals content were measured using XPS. Performance of Al-MCM-41 to adsorp and desorp nitrogen was also monitored by GSA using BET model. Acidity of the Al-MCM-41 was analyzed by FTIR using absorption of pyridine. The catalytic activity was measured using gas chromatography-mass spectrometry (GC-MS). The chromatogram shows that conversion Nyamplung seed oil to biodiesel is 98.15%. The performance of biodiesel obtained was analyzed by use it to diesel engine. The biodiesel obtained was mixed with commercial diesel fuel in various volume ratios (i.e. 0, 10, 20, 30 and 100%) before used. Viscosity, flash point, boiling point, cloud point, and pour point of the mixtures were characterized. These measuring properties increase with the increase of biodiesel concentration. Optimum engine power was achieved by 10% biodiesel. The mixture of 10% biodiesel has similar characteristic to commercial diesel fuel at load until 1800 watt.


Al-MCM-41; transesterification; biodiesel; diesel engine

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 [1] Adam, J., Blazsó, M., Mészáros, E., Stöcker, M., Nilsen, M.H., Bouzga, A., Hustad, J.E., Grønli, M., and Øye, G., 2005; Pyrolysis of biomass in the presence of Al-MCM-41 type catalyst, Fuel, 84 (12-13), 1494–1502.

[2] Alonso-Lemus, I., Verde-Gomes, Y., Aguilar-Elguézabal, A., and Álvarez-Contreras, L., 2010, Metal Nanoparticles supported on Al-MCM-41 via in situ aqueous synthesis, J. Nanomater., 2010, 1–8.

[3] Biswas, S., Majhi, S., Mohanty, P., and Sharmaa, D.K., 2014, Effect of different catalyst on the co cracking of Jatropha oil, vacuum residue and high density polyethylene, Fuel, 133, 96–105.

[4] Boyadjian, C., Lefferts, L., and Seshan, K., 2010, Catalytic oxidative cracking of hexane as a route to olefins, Applied Catal., A, 372, 167–174.

[5] Alípio C. Carmo Jr., A.C., de Souza, L.K.C., da Costa, C.E.F., Longo, E., Zamian, J.R., and da Rocha Filho, G.N., 2009, Production of biodiesel by esterification of palmitic acid over mesoporous aluminosilicate Al-MCM-41, Fuel, 88, 461–468.

[6] Georgogianni, K.G., Katsoulidis, A.P., Pomonis, P.J., and Kontominas, M.G., 2009, Transesterification of soybean frying oil to biodiesel using heterogeneous catalysts, Fuel Process. Technol., 90 (5), 671–676.

[7] Juwono, H., Triyono, Sutarno, and Endang, T.W., 2013, The Influence of Pd impregnation into Al-MCM-41 on the characters and activity biogasoline production by catalytic hydrocracking of FAMEs from nyamplung seed oil (Calophyllum inophyllum), Indones. J.Chem, 13 (2), 171–178.

[8] Basumatary, A.K., Kumar, R.V., Ghoshal, A.K., and Pugazhenthi, G., 2015, Synthesis and characterization of MCM-41-ceramic composite membrane for the separation of chromic acid from aqueous solution, J. Membr. Sci., 475, 521–532.

[9] Gannouni, A., Rozanska, X., Albela, B., Zina, M.S., Delbecq, F., Bonneviot, L., and Ghorbel, A., 2012, Theoretical and experimental investigations on site occupancy for palladium oxidation states in mesoporous Al-MCM-41 materials, J. Catal., 289, 227–237.

[10] Barbaro, P., and Bianchini, C., 2009, Catalysis for Sustainable Energy Production, Wiley-VCH Verlag GmbH & Co. KGaA, 463.

[11] Benito, P., Gregori, M., Andreoli, S., Fornasari, G., Ospitali, F., Millefanti, S., Avila, M.S., Garetto, T.F., and Albonetti, S., 2015, Pd–Cu interaction in PdCu-MCM-41 catalysts: Effect of silica source and metal content, Catal. Today, 246, 108–115.

[12] Ruiz, J.A.C., Fraga, M.A., and Pastore, H.O., 2007, Methane combustion over Pd supported on MCM-41, Appl. Catal., B, 76 (1-2), 115-122.

[13] Roik, N.V., and Belyakova, L.A., 2013, Sol–gel synthesis of MCM-41 silicas and selective vapor-phase modification of their surface, J. Solid State Chem., 207, 194–202.

[14] Atsushi, I., Takanori, W., Hiroyuki, N., and Tadanori, H., 2014, Preparation of amorphous silica-alumina using polyethylene glycol and its role for matrix in catalytic cracking of n-dodecane, Appl. Catal., A, 478, 58–65.

[15] Emeis, C.A., 1993, Determination of integrated molar extinction coefficients for infrared absorption of pyridine adsorbed on solid acid catalysts, J. Catal., 141 (2), 347–354.

[16] Gay, P.L., and Boyes, E.D., 2009, Electron Microscopy in Heterogeneous, 3rd ed., Institute of Physics Publishing, Bristol and Philadelphia, US, 71–74.


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