Steam Influence and Effect of Oxidant Amount on Propane Oxidation over Multi Metal Oxide Catalyst Using High-Throughput Experiment

https://doi.org/10.22146/ijc.23959

Restu Kartiko Widi(1*), Sharifah Bee Abd Hamid(2)

(1) Department of Chemical Engineering, Surabaya University (UBAYA), Jl. Raya Kalirungkut Tenggilis, TG building 5th floor, 60292, Surabaya
(2) Combinatorial Technology and Catalysis Research Centre, COMBICAT, University of Malaya, Kuala Lumpur
(*) Corresponding Author

Abstract


The high-throughput experimentation technique was used to verify the testing conditions due to the effects of catalyst structure modifications and/or due to reaction parameter variation in parallel. In this paper, the design of experiment and catalytic results are discussed in the development of selective oxidation catalyst, to demonstrate the importance and versatility of such technology. It is used for the automated parallel testing of selective oxidation of propane to acrylic acid over some types of multi metal oxide catalysts. The catalysts used for performance test were Mo (molybdenum), cat-1 (unsupported Mo1V0.3Te0.23Nb0.125O), and cat-2 (supported Mo1V0.3Te0.23Nb0.125O). All catalysts were dried using spray drier. The effect of some reaction parameters, such as the amount of oxidant, presence of steam and reaction temperature was also investigated during the test. The configuration of the ‘nanoflow’ is shown to be suitable to screen catalytic performance. The results obtained gave very good reproducibility.

Keywords


catalyst; reactor; catalytic activity; selective oxidation; propane

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References

[1] Mao, S., and Burrows, P.E., 2015, Combinatorial screening of thin film materials: An overview, J. Materiomics, 1 (2), 85–91.

[2] Riznyk, V., 2009, Researches of the combinatorial models for innovative information technologies, Int. J. Comput., 8 (2), 103–108.

[3] Mestl, G., Margitfalvi, J.L., Végvári, L., Szijjártó, G.P., and Tompos, A., 2014, Combinatorial design and preparation of transition metal doped MoVTe catalysts for oxidation of propane to acrylic acid, Appl. Catal., A, 474, 3–9.

[4] Wagner, J.B., Timpe, O., Hamid, F.A., Trunschke, A., Wilda U., Su, D.S., Widi, R.K., Hamid, S.B.A., and Schlogl, R., 2006, Surface texturing of Mo–V–Te–Nb–Ox selective oxidation catalysts, Top. Catal., 38 (1-3), 51–58.

[5] Widi, R.K., Hamid, S.B.A., and Schlogl, R., 2009, Kinetic investigation of propane oxidation on diluted Mo1–V0.3–Te0.23–Nb0.125–Oxmixed-oxide catalysts, React. Kinet. Catal. Lett., 98 (2), 273–288.

[6] Widi, R.K., Hamid, S.B.A., and Schlogl, R., 2008, Effect of diluent and reaction parameter on selective oxidation of propane over MoVTeNb catalyst using nanoflow catalytic reactor, J. Nat. Gas Chem., 17 (2), 130–134.

[7] Widi, R.K, 2010, Kinetic investigation of propane disappearance and propene formation in propane oxidation on diluted and leached MoVTeNb catalyst, Indones. J. Chem., 10 (2), 172–176.

[8] Widi, R.K, 2012, Kinetic investigation of carbon dioxide, acetic acid, acrylic acid formation in propane oxidation on diluted and leached MoVTeNb catalyst, Indones. J. Chem., 12 (2), 131–134.

[9] Lee, J., Xu, Y., and Huber, G.W., 2013, High-throughput screening of monometallic catalysts for aqueous-phase hydrogenation of biomass-derived oxygenates, Appl. Catal., B, 140-141, 98–107.

[10] Qiu, C., Chen, C., Ishikawa, S., Murayama, T., and Ueda, W., 2014, Crystalline Mo-V-W-mixed oxide with orthorhombic and trigonal structures as highly efficient oxidation catalysts of acrolein to acrylic acid, Top. Catal., 57 (14-16), 1163–1170.

[11] Ueda, W., 2013, Establishment of Crystalline Complex Mo–V–Oxides as Selective Oxidation Catalysts, J. Jpn. Pet. Inst., 56 (3), 122–132.

[12] Pyrz, W.D., Blom, D.A., Sadakane, M., Kodato, K., Ueda, W., Vogt, T., and Buttrey, D.J., 2010, Atomic-level imaging of Mo-V-O complex oxide phase intergrowth, grain, boundaries, and defects using HAADF-STEM, Proc. Natl. Acad. Sci. U.S.A., 107 (14), 6152–6157.

[13] Pyrz, W.D., Blom, D.A., Sadakane, M., Kodato, K., Ueda, W., Vogt, T., and Buttrey, D.J., 2010, Atomic-scale investigation of two-component MoVO complex oxide catalysts using aberration-corrected high-angle annular dark-field imaging, Chem. Mater., 22, 2033–2040.

[14] Bedenbaugh, J.E., Kim, S., Sasmaz, E., and Lauterbach, J., 2013, High-throughput investigation of catalysts for JP-8 fuel cracking to liquefied petroleum gas, ACS Comb. Sci., 15 (9), 491–497.

[15] Gregoire, J.M., Xiang, C., Mitrovic, S., Liu, X., Marcin, M., Cornell, E.W., Fan, J., and Jin, J., 2013, Combined catalysis and optical screening for high throughput discovery of solar fuels catalysts, J. Electrochem. Soc., 160 (4), F337–F342.

[16] Lin, M.M., 2001, Selective oxidation of propane to acrylic acid with molecular oxygen, Appl. Catal., A, 207 (1-2), 1–16.



DOI: https://doi.org/10.22146/ijc.23959

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