Preparation of Peleted Ni-Pt/Zeolite for Conversion of Amyl and Isoamyl Alcohol to Hydrocarbon

https://doi.org/10.22146/ijc.21944

Abdullah Abdullah(1*), Triyono Triyono(2), Bambang Setiaji(3)

(1) Department of Chemistry, Faculty of Mathematic and Natural Sciences, Lambung Mangkurat University
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(*) Corresponding Author

Abstract


Catalysts with Ni and Pt as active metals in peleted zeolite were used for conversion of amyl alcohol, isoamyl alcohol and their mixture to hydrocarbon compounds. The catalysts were prepared by impregnation the peleted zeolite in NiCl2.6H2O and PtCI4 solution, while stirring for 24 hours then followed by oxidation with 02 gas at 350 °C for 2 hours and reduced by hydrogen gas at 400 °C for 1 hour. Ni and Pt in catalysts were determined by MS, specific surface area, total pore volume and gas sorption analyzer NOVA-1000 determined pore radius average. Determination of catalysts acidity was carried out by absorption of ammonia method. The activity of catalysts was evaluated in a micro reactor by flow system. Experimental temperature by varied between 300 and 400 °C with the increment of 25 °C. Products were analyzed by gas chromatographic and mass spectrometric method. The result shows that Ni-Pt/zeolite is more active than Ni/zeolite can be used for converting all of the alcohol. Products for conversion are 2-pentene, 2-methyl-1-butene, 2-methyl-2-butene, cyclopentane, 3-methyl-1-butanaldehide and acetone. The highest conversion was observed on isoamyl alcohol (31.37%) at 400 °C.

Keywords


catalyst; zeolite; alcohol conversion; hydrocarbon

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References

[1] Anderson, J.R., Bodart, M., Catalysis Science and Technology, Springer Verlag, Berlin Heidelberg, New York.

[2] Babu, G.P., Murthy, R.S., Krishnan, V., 1997, Conversion of Isoamil Alcohol over Acid Catalysts: Reaction Dependence on Nature Active Centers, Journal of Catalysis, Academic Press, New York, 166, 111-114.

[3] Campbell, I.M., 1988, Catalysis at Surfaces, Chapman and Hall, London-New York.

[4] Delafosse, D., 1980, Catalysis by Zeolites, Elsevier Scientific Publishing Company, Amsterdam.

[5] Foger, K., 1989, Dispersed Metal Catalyst, CSIRO Division of Material Science Catalyst and Surface Science, Lab. University of Melbourne, Australia.

[6] Gregg, S.J., Sing, K.S.W., 1967, Adsorption, Surface Area and Porosity, National Academic, Washington DC.

[7] Lowell, S., dan Shields, J.E., 1984, Powder Surface Area and Porosity, Chapman and Hall Ltd., New York.

[8] Oudejans, J.C., 1984, Zeolite Catalyst In Some Organic Reactions, supported by The Netherlands Foundation for Chemical Research (SON), Holland.

[9] Somorjai, GA., 1987, The Building of Catalyst: A Molecular Surface Science Approach (Hegedus, L.L., Aris, R., Bell, A.T., Boudart, M., Chen, N.Y., Gate, B.C., Haag, W.O., Somorjai, G.G., Wei, J., editors, Catalyst Design), John Wiley & Sons, New York.

[10] Triyono, 1996, Hidrogenolisis Tetrahidrofuran pada KataRasta,' Platina, Berkala Ilmiah MIPA-UGM, VI, 1;17-26.

[11] Triyono dan Anwar, C., 1997, Enhanced HDO Activity via Wetness Impregnation of Platinum on Oxide Supports, Lemigas Scientific Contribution, Jakarta.

[12] Walling, C., 1950, The Acid Strength of Surfaces, J. Amer. Chem. Soc., 72, 1164.



DOI: https://doi.org/10.22146/ijc.21944

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Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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