STUDY OF LYSINE AND ALANINE DELIVERANCE THROUGH POLYPYRROLE MEMBRANE

https://doi.org/10.22146/ijc.21851

Adhitasari Suratman(1*), Buchari Buchari(2), Indra Noviandri(3), Suryo Gandasasmita(4)

(1) Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta
(2) Chemistry Department, Faculty of Mathematics and Natural Sciences, Institute of Technology Bandung, Bandung
(3) Chemistry Department, Faculty of Mathematics and Natural Sciences, Institute of Technology Bandung, Bandung
(4) Chemistry Department, Faculty of Mathematics and Natural Sciences, Institute of Technology Bandung, Bandung
(*) Corresponding Author

Abstract


Electropolymerization processes of pyrrole and the usage of polypyrrole membrane as lysine and alanine deliverance have been studied by cyclic voltammetry technique. Polypyrrole membrane was prepared by electropolymerization processes of pyrrole in water based solvent containing sodium perchlorate as supporting electrolyte. Electropolymerization processes were carried out within potential range of 0-1100 mV vs Ag/AgCl reference electrode and at the scanning rate of 100 mV/s. In this study, lysine and alanine have been used as molecules which could easily be loaded on and released from polypyrrole membrane. The presence of lysine or alanine during electropolymerization process reduced the rate of electropolymerization of polypyrrole. In lysine or alanine transfer processes into polypyrrole membrane, the interaction between polypyrrole and lysine or alanine showed by the curve of E½ oxidation in respect of - log C. It proved that the E½ oxidation shifted to more positive potential showed by the increasing of concentration of lysine or alanine. Beside that, voltammetric responses of lysine and alanine transfered into polypyrrole membrane were found to be Nernstian. The results indicated that polypyrrole could be used as a sensor of lysine and alanine.


Keywords


Electropolymerization; polypyrrole membrane; voltammetry technique

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References

[1]   Genies, E. M., Bidan, G., and Diaz, A.F., 1983, J. Electroanal. Chem, 149, 101

[2]   Burgmayer, P., and Murray, R.W. 1986, Handbook of Conducting Polymer, Vol. 1, Marcel Dekker, New York, 507

[3]   Kontturi, K., Pentti, P. and Sundholm, G. 1998, J. Electroanal.  Chem, 453, 231-238

[4]   Zinger, B., and Miller, L.L., 1984, J. Am. Chem. Soc, 106, 6861

[5]   Pyo, M.G., Maeder, R.T., and Kennedy, J.R. Reynold, 1994, J. Electroanal. Chem., 368, 329

[6]   Hepel, M., and Mahdavi., 1997, Microchem J., 56,  54

[7]   Wang, J., 1994, Analytical Electrochemistry, VHC Publishers Inc., New York

[8]   Skoog, D.A., West, D.M., and Holler, F.J., 1996, Fundamentals of Analytical Chemistry, 7th edition, Harcourt Brace College Publishers, New York

[9]   Branen, A.L., Davidson, P.M., and Salminen, S.,  1990, Food Additives, Marcel Dekker Inc., New York



DOI: https://doi.org/10.22146/ijc.21851

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Indonesian Journal of Chemistry (ISSN 1411-9420 / 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

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