THE INFLUENCE OF pH TOWARDS MULTIPLE METAL ION ADSORPTION OF Cu(II), Zn(II), Mn(II), AND Fe(II) ON HUMIC ACID

https://doi.org/10.22146/ijc.21771

Buhani Buhani(1*), Suharso Suharso(2)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro, No. 1 Gedung Meneng-Bandar Lampung 35145
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl. Soemantri Brojonegoro, No. 1 Gedung Meneng-Bandar Lampung 35145
(*) Corresponding Author

Abstract


Multiple metal ions adsorption of Cu(II), Zn(II), Mn(II) and Fe(II) on humic acid with a batch method has been carried out at pH interaction of 3, 5, and 6. Concentration of metal ions in solution before and after interaction was analyzed with Atomic Absorption Spectrophotometer (AAS). Result showed that adsorption multiple metal ions of Cu(II), Zn(II), Mn(II), and Fe(II) on humic acid is optimum at pH 5. Adsorption energies of the multiple metal ions Cu(II), Zn(II), Mn(II), and Fe(II) on humic acid at pH 3, 5, and 6 are around 35.0 - 37.6 kJ/mole. In general, capacity of competition adsorption of the multiple metal ions has an order as follows; Cu(II) < Fe(II) < Zn(II) < Mn(II).


Keywords


Humic acid; adsorption; multiple metal

Full Text:

Full Text Pdf


References

[1] Tan, K., 1998, Dasar-dasar Kimia Tanah. Gadjah Mada Press. Yogyakarta

[2] Hayes, M.H.B., MacCarthy, P., Malcolm, R.L., and Switt, R.S., 1989, Humic Substance II: In Search of Structure, John Wiley & Sons, New York.

[3] Stevenson, F.J., 1994, Humus Chemistry, Ganesis, Composition, Reaction, 2nd ed., John Wiley and Sons, New York.

[4] Aiken, G.R., McKnight, D.M., Wershaw, R.L., and MacCarthy, P., 1985, An Introduction to Humic Substance in Soil, Sediment and Water, John Wiley and Sons, New York.

[5] Milne, P.J., 1995, J. Colloid & Interface Sci., 175, 448-460.

[6] Manku, G.S., 1980, Theoretical Principles of Inorganic Chemistry, Mc-Graw Hill Publishing Company, New Delhi.

[7] Jin, X., Bailey, G.W., Yu, Y.S., and Lynch, A.T. 1996, Soil Science, 1(8), 509 –520.

[8] Adamson, A.W., 1990, Physical Chemistry of Surfaces, 5th ed., John Wiley and Sons, New York.

[9] Alimin, 2000, Fraksinasi Asam Humat dan Pengaruhnya pada Kelarutan Ion Zn2+, Cd2+, Mg2+ dan Ca2+, Tesis S2 Kimia, Universitas Gadjah Mada, Yogyakarta.



DOI: https://doi.org/10.22146/ijc.21771

Article Metrics

Abstract views : 1932 | views : 4672


Copyright (c) 2010 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.