* Corresponding Author
MICELLE-MEDIATED EXTRACTION AS A TOOL FOR SEPARATION AND PRECONCENTRATION IN COPPER ANALYSIS
https://doi.org/10.22146/ijc.21669 F. Ahmadia(1*), A. Khanmohammadi(2), A. Malekpour(3)
(1) Chemistry Department, Gachsaran Azad University, Gachsaran, Iran
(2) Young Researchers Club, Gachsaran Azad University, Gachsaran, Iran
(3) Chemistry Department, Gachsaran Azad University, Gachsaran, Iran
(*) Corresponding Author
Abstract
A cloud point extraction method was presented for preconcentration of copper in various samples. After complexation with 4-Amino-2,3-dimethyl-1-phenyl-3-pyrazoline-5-one (ADPP) or N-Benzoyl-N-phenylhydroxylamine (BPA) in water, analyte ions are quantitatively extracted to the phase rich in Triton X-114 after centrifugation. 2.0 mol L-1 HNO3 solution in methanol was added to the surfactant-rich phase prior to its analysis by flame atomic absorption spectrometry (FAAS). The adopted concentrations for ADPP, Triton X-114, HNO3 and parameters such as bath temperature, centrifuge rate and time were optimized. Detection limits (3SDb/m) of 1.3 and 1.9 ng mL-1 for ADPP and BPA along with enrichment factors of 30 and 38 for ADPP and BPA were achieved. The high efficiency of cloud point extraction to carry out the determination of analyte in complex matrices was demonstrated. The proposed method was applied to the analysis of biological, industrial, natural and wastewater, soil and blood samples.
Keywords
Full Text:
Full Text PDFReferences
[1] Sant´Ana, O.D., Jesuíno, L.D., Cassella, R.J., Carvalho, M.B., and Santelli, R.E., 2003, J. Braz. Chem. Soc., 14, 728.
[2] Ghaedi, M., Ahmadi, F., Karimi, H., and Gharaghani, S., 2006, Korean J.Chem., 1 23.
[3] Ghaedi, M., Fathi, M.R., Marahel F., and Ahmadi, F., 2005, Environm. Bull., 14, 1158.
[4] Safavi, A., Abdollahi, H., Nezhad, M.R.H., and Kamali, R., 2004, Spectrochim. Acta, Part A, 60, 2897.
[5] Nascentes, C.C., Arruda, M.A.Z., and Maniasso, N., 2002, Quim. Nova, 25, 483.
[6] Ohashi, A., Tsuguchi, A., Imura, H., and Ohashi, K., 2004, Anal. Sci., 20, 1091.
[7] Pramauro, E., and Prevot, A.B., 1995, Pure Appl. Chem. 4, 551.
[8] Manzoori, J.L., and Nezhad, G.K., 2004, Anal. Chim. Acta., 521, 173.
[9] Manzoori, J.L. and Bavili-Tabrizi, A. 2002, Anal. Chim. Acta, 470, 215.
[10] Kulichenko, S.A., Doroschuk, V.O., and Lelyushok, S.O., 2003, Talanta, 59, 767.
[11] Manzoori, J.L. and Bavili-Tabrizi, A. 2002, Microchem. J. 72, 1.
[12] Silva, M.A.M., Frescura, V.L.A., Aguilera, F.J.N., and Curtius, A.J., 1998, J. Anal. At. Spectrom., 13, 1369.
[13] Silva, M.A.M., Frescura, V.L.A., and Curtius, A., 2000, J. Spectrochim. Acta, 55 B, 803.
[14] Chen, J., and Teo, K.C., 2001, Anal. Chim. Acta, 450, 215.
[15] Tarley, C.R.T., and Arruda, M.A.Z., 2004, Anal. Sci. 20, 961.
[16] Ghaedi, M., Spectrochim. Acta Part A Accepted.
[17] Pinto, C.G., Pavo´n, J.L.P., and Cordero, B.M., 1996, J. Anal. At. Spectrom. 11, 37.
[18] Tani, H., Kamidate, T., and Watanabe, T., 1997, J. Chromatogr. A 780, 229.
[19] Borges, D.L.G., Veiga, M.A.M.S., Frescura, V.L.A., Welz, B., and Curtius, A.J., 2003, J. Anal. At. Spectrom., 18, 501.
[20] Gu, T., and Galera-Go´mez, P.A., 1995, A Physicochem. Eng. Asp., 104, 307.
[21] Nascentes, C.C., and Arruda, M.A.Z., 2003, Talanta, 61, 759.
[22] Komaromy-Hiller, G., Calkins, N., and Wandruszka, R., 1996, Langmuir 12, 916.
[23] Armstrong, J.K., Chowdhry, B.Z., Snowden, M.J., Leharne, S.A., 1998, Langmuir 14, 2004.
[24] Frankewich, R.P., and Hinze, W.L., 1994, Anal. Chem., 66, 944.
DOI: https://doi.org/10.22146/ijc.21669
Article Metrics
Abstract views : 1752
| 
views : 1035
Copyright (c) 2010 Indonesian Journal of Chemistry
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.