TRANSPORT BEHAVIOR OF Cr(III), Cd(II), Pb(II),  AND Ag(I) IONS THROUGH BULK LIQUID MEMBRANE CONTAINING  p-tert -BUTYLCALIX[4]ARENE–TETRADIETHYLACETAMIDE AS ION CARRIER

Maming Maming; Jumina Jumina; Dwi Siswanta; Hardjono Sastrohamidjojo; Keisuke Ohto

doi:10.22146/ijc.21582

TRANSPORT BEHAVIOR OF Cr(III), Cd(II), Pb(II), AND Ag(I) IONS THROUGH BULK LIQUID MEMBRANE CONTAINING p-tert-BUTYLCALIX[4]ARENE–TETRADIETHYLACETAMIDE AS ION CARRIER

https://doi.org/10.22146/ijc.21582

Maming Maming^(1*), Jumina Jumina⁽²⁾, Dwi Siswanta⁽³⁾, Hardjono Sastrohamidjojo⁽⁴⁾, Keisuke Ohto⁽⁵⁾

(1) Chemistry Department, Faculty of Mathematics and Natural Sciences, Hasanuddin University, Makassar
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281
(5) 3Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo, Saga 840
(*) Corresponding Author

Abstract

The study on the transport behavior of Cr(III), Cd(II), Pb(II), and Ag(I) through bulk liquid membrane using p-tert-butylcalix[4]arene-tetradiethylacetamide as ions carrier has been conducted. The aims of this work are to determine the optimum condition, efficiency, and transport selectivity of the carriers for those ions. Both optimum condition and transport efficiency were obtained by determination of the concentration of transported ions with variation of the source phase pH, ion carrier concentration, the nature of decomplexant agent in the receiving phase, and transport time. The transport selectivity of the ion carrier was obtained from the ions competition transport experiments. The amount of Cr(III), Pb(II), Cd(II), and Ag(I) transported across liquid membrane were 11.6, 25.5, 39.5, and 42.1% respectively. The ion carrier is selective for Cd(II), Pb(II), Ag(I), and strongly depends on the nature of decomplexant agent as well as transport mechanism. The remarkable selectivity was shown by the ion carrier to Ag(I) when the transport process was carry out under high concentration of acid in the source phase.

Keywords

transport; p-tert-butylcalix[4]arene-tetradiethylacetamide; efficiency; selectivity; bulk liquid membrane; heavy metals

Full Text:

Full Text Pdf

References

[1] Harrison, R. M., 1997, Pollution, Causes, Efects, and Control, 3^rd Ed., 139 – 143, Springer, Berlin.

[2] Leon, G. and Guzman, M. A., 2004, Desalination 162, 211 – 215.

[3] Mulder, M., 1996, Basic Principles of Membrane Technology, 2^nd ed, Kluwer Academic Publisher, Netherlands, 1 - 6.

[4] Maming, Jumina, Siswanta, D., and Sastrohamidjojo, 2007, Indo. J. Chem., 7(2), 172 – 179.

[5] Maming, Jumina, Siswanta, D., Firdaus, and Sastrohamidjojo, 2008, Indo. J. Chem., 8(1), 72 – 77.

[6] Tayeb, R., Zaghbani, A., Tingri, S., Seta, P., and Dahbi, M., 2007, Desalination, 204, 234-240.

[7] Cobben, P. L. H. M., Egberink, R. J. M., Bomer, J. G., Bergeveld, P., Verboom, W., and Reinhoudt, D. N., 1992, J. Am. Chem. Soc., 114, 10573 – 10582.

[8] Fanni, S., Armaud, N. F., McKervey, M. A., Sehwing, A. J., and Ziat, K., 1996, Tetrahedron Lett., 37, 7975 – 7978.

[9] Ohto, K., Yamaga, H., Murakami, E., and Inoue, K., 1997, Talanta, 44, 1123 – 1130.

[10] Bohmer, V., 1995, Angew Chem. Int. Ed. Engl, 31, 713 – 745.

[11] Gutsche, C. D., 1998, Calixarenes Revised, The Royal Society of Chemistry (Series Editor : J. Fraser Stoddart, FRS), USA.

[12] Ye, Z. F., Wang, Y. P., Liu, Y. S., Jiang, Z. L., She, X., Zhu, L. G., and Shi, X. F., 1999, J. Memb. Sci., 163, 367 – 372.

[13] Akhond, M. and Tashkhourian, J., 2003, Bull. Corean Chem. Soc., 24, 489 –493.

[14] Abbaspour, A. and Tavakol, F., 1999, Anal. Sci.,, 15, 1005 – 1008.

[15] Bartsch, R. A. and Way, J. D., 1996, Chemical Separation with Liquid Membranes, ACS Symposium Series 642, American Chemical Society, New York.

[16] Huheey, J. E., 1978, Inorganic Chemistry, Principles Structure and Reactivity, 2^nd Ed., 278-288, 348-390, 489-498, Harper International Edition, New York.

DOI: https://doi.org/10.22146/ijc.21582