SYNTHESIS OF TERPINEOL FROM α-PINENE CATALYZED BY TCA/Y-ZEOLITE

https://doi.org/10.22146/ijc.21386

Nanik Wijayati(1*), Harno Dwi Pranowo(2), Jumina Jumina(3), Triyono Triyono(4)

(1) Student of Doctorate Program, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta, Jl. Sekip Utara, Yogyakarta
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta, Jl. Sekip Utara, Yogyakarta
(4) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta, Jl. Sekip Utara, Yogyakarta
(*) Corresponding Author

Abstract


The hydration of a-pinene has been studied in the presence of TCA/Y-Zeolite catalyse. The catalyst was prepared by impregnating trichloroacetic acid (TCA) on support of Y-Zeolite. The TCA/Y-Zeolite catalyst converted a-pinene into hydrocarbons, while the TCA/Y-Zeolite catalyst was active and selective for producing alcohols, with a conversion of 66% and showed 55% selectivity for α-terpineol at 10 min. The reaction taken place in a solid-liquid mode and most of the α-terpineol is extracted out by the organic phase during the course of the reaction. TCA/Y-Zeolite was found as good catalyst for hydration of α-pinene to produce α-terpineol.

Keywords


α–pinene; TCA/Y-Zeolite; terpineol

Full Text:

Full Text PDF


References

[1] Vital, J., Ramos, A.M., Silva, I.F., Valente, H., and Castanheiro, J.E., 2000, Catal. Today, 56, 167–172.

[2] Vital, J., Ramos, A.M., Silva, I.F., Valente, H., and Castanheiro, J.E., 2001, Catal. Today, 67, 217–223

[3] Castanheiro J.E., Foseseca, I.M., Ramos, A.M., Oliveira, R., and Vital, J., 2005, Catal. Today, 104, 296–304.

[4] Mochida T., Ryuichiro O., Naoto H., Yuichi K., Toshio O., 2007, Microporous Mesoporous Mater., 101, 176–183.

[5] Bhatia, S.P., 2008, Food Chem. Toxicol., 46, 5275–5279.

[6] Martino, L.D., Vinzenco, D.F., Carmen, F., Enrico, M., and Felice, S., 2009, Molecules, 14, 2735–2746.

[7] Moreira, M.R., Cruz, G.M.P., Lopes, M.S., Albuquerque, A.A.C., and Cardoso, J.H.L., 2001, J. Med. Biol. Res., 34, 1337–1340.

[8] Bagheri, S.M, Amirhossein, S., Ahmad, R.G., Soodabeth, S., Maryam, M., and Mehrdad, I., 2010, Pharm. Biol., 48, 3, 242–2463.

[9] van der Waal, J.C., Van Bekkum, H., and Vital, J.M., 1996, J. Mol. Catal. A: Chem., 105, 185–192.

[10] Roman-Aguirre, M.R., De la Torre-Sáenz, L., Flores, W.A., Robau-Sánchez, A., and Elguézabal, A., 2005, Catal. Today, 107-108, 310–314.

[11] Avila, M.C., Nora, A.C., Castellon, E.R., and Lopez A.J., 2010, J. Mol. Catal. A: Chem., 322, 1-2 106–112

[12] Robles-Dutenhefner, P.A., da Silva, K.A., Siddiqui, M.R.H., Kozhevnikov, I., and Gusevskaya, E.V., 2001, J. Mol. Catal. A: Chem., 175, 33-42.

[13] Zhang, H., Mahajani, S.M., Sharma, M.M., and Sridhar, T., 2002, Chem. Eng. Sci., 57, 315-322.

[14] Pakdel, H., Sharron, S., and Roy, C., 2001, J. Agric. Food. Chem., 49, 9, 4337–4341.



DOI: https://doi.org/10.22146/ijc.21386

Article Metrics

Abstract views : 2372 | views : 8797


Copyright (c) 2011 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 

Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web Analytics View The Statistics of Indones. J. Chem.