TOTAL HYDROGENATION OF BIOMASS-DERIVED FURFURAL OVER RANEY NICKEL-CLAY NANOCOMPOSITE CATALYSTS

https://doi.org/10.22146/ijc.21291

Rodiansono Rodiansono(1*), Takayoshi Hara(2), Shogo Shimazu(3)

(1) Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Lambung Mangkurat, Jl. A. Yani Km 35.8 Banjarbaru South Kalimantan 70713
(2) Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Chiba, Jl. Yayoi-cho, Inage-ku, Chiba-shi, Chiba Japan 263-8522
(3) Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Chiba, Jl. Yayoi-cho, Inage-ku, Chiba-shi, Chiba Japan 263-8522
(*) Corresponding Author

Abstract


Inexpensive Raney Ni-clay composite (R-Ni/clay) catalysts exhibited excellent activity and reusability in the total hydrogenation of biomass-derived furfural into tetrahydrofurfuryl alcohol under mild conditions. For the Raney Ni-bentonite (R-Ni/BNT) catalysts, the complete reaction was achieved at 393 K, 180 min giving almost 99% yield of tetrahydrofurfuryl alcohol. The R-Ni/BNT catalyst was found to be reusable without any significant loss of activity and selectivity for at least six consecutive runs.

Keywords


Raney Ni; clay-composite; total hydrogenation; furfural; furfuryl alcohol; tetrahydrofurfuryl alcohol

Full Text:

Full Text PDF


References

[1] Huber, G.W., Iborra, S., and Corma A., 2006, Chem. Rev., 106, 9, 4044–4098.

[2] Corma, A., Iborra, S., and Velty, A., 2007, Chem. Rev., 107, 6, 2411–2502.

[3] Montane, D., Salvado, J., Torras, C., and Farriol, X., 2002, Biomass Bioenergy, 22, 4, 295–304.

[4] Xu, W., Wang, H., Liu, X., Ren, J., Wang, Y., and Lu, G., 2011, Chem. Commun., 47, 3924–3926.

[5] Lange, J.P., van de Graaf, W.D., and Haan, R.J., 2009, ChemSusChem, 2, 5, 437–441.

[6] Koso, S., Furikado, I., Shimao, A., Miyazawa, T., Kunimoria, K., and Tomishige, K., 2009, Chem. Commun., 15, 2035–2037.

[7] Li, H., Luo, H., Zhuang, L., Dai, W., and Qiao, M., 2003, J. Mol. Catal. A: Chem., 203, 267–275.

[8] Reddy, B.M., Reddy, G.K., Rao, K.N., Khan, A., and Ganesh, I., 2007, J. Mol. Catal. A: Chem., 265, 1-2, 276–282.

[9] Merat, N., Godawa, C., and Gaset, A., 1990, J. Chem. Technol. Biotechnol., 48, 2,145–159.

[10] Luo, H., Li, H., and Zhuang, L., 2001, Chem. Lett. 404–405.

[11] Li, H., Zhang, S., and Luo, H., 2004, Mater. Lett., 58, 2741–2746.

[12] Baijun, L., Lianhai, L., Bingchun, W., Tianxi, C., and Iwatani, K., 1998, Appl. Catal. A, 171, 1, 117–122.

[13] Hoffer, B.W., Crezee, E., Devred, F., Mooijman, P.R.M., Sloof, W.G., Kooyman, P.J., van Langeveld, A.D., Kapteijn, F., and Moulijn, J.A., 2003, Appl. Catal. A, 253, 2, 437–452.

[14] Hoffer, B.W., Crezee, E., Mooijman, P.R.M, van Langeveld, A.D., Kapteijn, F., and Moulijn, J.A., 2003, Catal. Today, 79-80, 35–41.

[15] Shabaker, J.W., Huber, G.W., and Dumesic, J.A., 2004, J. Catal., 222, 1, 180–191.

[16] Shabaker, J.W., and Dumesic, J.A., 2004, Ind. Eng. Chem. Res., 43, 12, 3105–3112.

[17] Shabaker, J.W., Simonetti, D.A., Cortright, R.D., and Dumesic, J.A., 2005, J. Catal., 231, 1, 67–76.

[18] Huber, G.W., Shabaker, J.W., and Dumesic, J.A., 2003, Science, 300, 5628, 2075–2077.

[19] Petró, J., Bóta, A., László, K., Beyer, H., Kálmán, E., and Dódony, I., 2000, Appl. Catal. A, 190, 1-2, 73–86.

[20] Petró, J., Hegedüs L., and Sajó, I.E., 2006, Appl. Catal. A, 308, 50–55.

[21] Petró, J., US Patent 2000, 6,153–554.

[22] Mahata, N., Cunha, A.F., Órfão, J.J.M., and Figueiredo, J.L., 2008, Appl. Catal. A, 351, 2, 204–209.

[23] Mahata, N., Cunha, A.F., Órfão, J.J.M., and Figueiredo, J.L., 2009, Catal. Commun., 10, 1203–1206.

[24] Mahata, N., Cunha, A.F., Órfão, J.J.M., and Figueiredo, J.L., 2010, ChemCatChem, 2, 3, 330–335.

[25] Lowell, S., Shields, J.E., Thomas, M.A., and Thommes, M., Characterization of porous solids and powders: surface area, pore size and density, Kluwer Academic Publishers, Netherlands, 2004, Chapter 8.

[26] (a) Bartholomew, C.H., Pannel, R.B., and Butler J.L., 1980, J. Catal., 65, 2, 335–347. (b) Bartholomew, C.H., and Pannel, R.B., 1980, J. Catal., 65, 2, 390–401.

[27] Rodiansono, Hara, T., Ichikuni, N., and Shimazu, S., 2012, Chem. Lett., 41, 769–771.

[28] Rodiansono, Hara, T., Ichikuni, N., and Shimazu, S., 2012, Catal. Sci. Technol., 2, 2139–2145.



DOI: https://doi.org/10.22146/ijc.21291

Article Metrics

Abstract views : 1959 | views : 1608


Copyright (c) 2013 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 

Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web Analytics View The Statistics of Indones. J. Chem.