Synthesis of Fluorescence Carbon Nanoparticles from Ascorbic Acid

https://doi.org/10.22146/ijc.21207

Sri Sugiarti(1*), Noviyan Darmawan(2)

(1) Department of Chemistry, Bogor Agricultural University, Jl. Agatis, Kampus IPB Darmaga, Bogor 16680
(2) Department of Chemistry, Bogor Agricultural University, Jl. Agatis, Kampus IPB Darmaga, Bogor 16680
(*) Corresponding Author

Abstract


Carbon nanoparticles (C-dot) are materials that belong to a class of 0-dimensional nanoparticles with a photoluminescence property. C-dot can be synthesized from a variety of organic acids through bottom-up synthetic methods or from other source of inorganic carbons through top-down synthetic methods. Herein, we report a simple and fast synthesis method for the formation of C-dot from ascorbic acid using microwave heating technique. The success of this synthesis was shown by visual analysis, UV-Vis spectroscopy, fluorescence spectroscopy, and transmission electron microscopy (TEM). Visual analysis showed an increased in fluorescence intensity with the addition of urea as a passivation agent. The maximum fluorescence emission of the C-dot was a blue green color at wavelength 500 nm, after the C-dot was excited at a wavelength of 400 nm. The TEM analysis showed that the synthesized C-dot had an average size of 18 nm. We also conducted a preliminary study on the synthesized C-dot as a heavy ion metal sensor and found selective identification of Cr metal.

Keywords


carbon nanoparticles; ascorbic acid; urea; microwave; metal ion sensor

Full Text:

Full Text Pdf


References

[1] Li, H., Kang, Z., Liu, Y., and Lee, S.T., 2012, J. Mater. Chem., 22(46), 24230–24253.

[2] Qu, S., Wang, X., Lu, Q., Liu, X., and Wang, L., 2012, Angew. Chem. Int. Ed., 124(49), 12381–12384

[3] Yang, Z., Li, Z., Xu, M., Ma, Y., Zhang, J., Su, Y., Gao, F., Wei, H., and Zhang, L., 2013, Nano-Micro Lett., 5(4), 247–259.

[4] Zhu, C., Zhai, J., and Dong, S., 2012, Chem. Commun., 48(75), 9367–9369.

[5] Liu, H., Ye, T., and Mao, C., 2007, Angew. Chem. Int. Ed., 46(34), 6473–6475.

[6] Wang, J., Wang, C.F., and Chen, S., 2012, Angew. Chem. Int. Ed., 51(37), 9297–9301.

[7] Pandey, S., Thakur, M., Mewada, A., Anjarlekar, D., Mishra, N., and Sharon, M., 2013, J. Mater. Chem. B, 1(38), 4972–4982.

[8] Prasannan, A., and Imae, T., 2013, Ind. Eng. Chem. Res., 52(44), 15673–15678.

[9] Jiang, J., He, Y., Li, S., and Cui, H., 2012, Chem. Commun., 48(77), 9634–9636.

[10] Hsu, P.C., and Chang, H.T., 2012, Chem. Commun., 48(33), 3984–3986.

[11] Baker, S.N., and Baker, G.A., 2010, Angew. Chem. Int. Ed., 49(38), 6726–6744.

[12] Yan, F., Zou, Y., Wang, M., Mu, X., Yang, N., and Chen, L., 2014, Sens. Actuators, B, 192, 488–495.



DOI: https://doi.org/10.22146/ijc.21207

Article Metrics

Abstract views : 3408 | views : 4415


Copyright (c) 2015 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

 


Indonesian Journal of Chemistry (ISSN 1411-9420 /e-ISSN 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Web
Analytics View The Statistics of Indones. J. Chem.