Synthesis of Fe Ionic-Imprinted Polyeugenol Using Polyethylene Glycol Diglycidilether as Cross-Linking Agent for Sorption of Fe(III)

Muhammad Cholid Djunaidi(1*), Jumina Jumina(2), Dwi Siswanta(3), Mathias Ulbricht(4)

(1) Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. H. Soedarto, S.H., Tembalang, Semarang 50275
(2) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(3) Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO BOX BLS 21 Yogyakarta 55281
(4) Lehrstuhl für Technische Chemie II, Fakultätfür Chemie, Universität Duisburg-Essen, 45117 Essen
(*) Corresponding Author


Fe-Ionic Imprinted Polymer (IIP) from polyeugenol as base polymer and polyethylene glycol diglycidyl ether (PEGDE) as cross-linking agent had been synthesized to adsorb Fe(III) from aqueous media. The non-imprinting material (NIP) and polyeugenol were used in the adsorption study as control. Synthesis work included polymerization, template uploading, crosslinking and template removal, optimized for different template ion upload pH and concentrations. The polymers were characterized by FTIR spectroscopy, XRD and SEM-EDX, followed by adsorption test to study the adsorption kinetics and isotherms for all adsorbents. Selective adsorption study of IIP was carried out using binary mixtures of Fe(III) and Cr(III), Pb(II), Cd(II). Experimental results showed that the optimum conditions for the synthesis was template upload pH of 3, Fe/polyeugenol ratio of 1 mg/g, while the optimum adsorption pH was 3. The adsorption mechanism of Fe(III) on all adsorbents was dominated by hydrogen bond formation. The adsorption kinetics followed the pseudo-second-order model while the equilibrium data was best explained by the Langmuir isotherm model. The adsorption capacity of Fe(III) on the IIP was 12.73 mg/g, higher than that of the other adsorbents. Results also show that IIP-Fe was more selective toward Fe than NIP by 2.69 (Cd), 1.66 (Cr) and 1.6 (Pb) fold, respectively.


polyeugenol; ionic imprinted Fe adsorbent; selective adsorption; PEGDE

Full Text:

Full Text Pdf


[1] Khalil, M.M.H., Al-Wakeel, K.Z., El Rehim, S.S.A., and El Monem, H.A., 2013, J. Environ. Chem. Eng., 1 (3), 566–573.

[2] Fan, H-T., and Sun, T., 2012, Korean J. Chem. Eng., 29 (6), 798–803.

[3] Chang, X., Jiang, N., Zheng, H., He, Q., Hu, Z., Zhai, Y., and Chui, Y., 2007, Talanta, 71 (1), 38–43.

[4] Xie, F., Liu, G., Wu, F., Guo, G., and Li, G., 2012, Chem. Eng. J., 183, 372–380.

[5] Sölener, M., Tunali, S., Özcan, A.S., Özcan, A., and Gedikbey, T., 2008, Desalination, 223 (1-3), 308–322.

[6] Guibal, E., 2004, Sep. Purif. Technol., 38 (1), 43–74.

[7] Copello, G.J., Varela, F., Vivot, M., and Díaz, L.E., 2008, Bioresour. Technol., 99 (14), 6538–6544.

[8] Miretzky, P., and Cirelli, A.F., 2009, J. Hazard. Mater., 167 (1-3), 10–23.

[9] Harimu, L, Matsjeh, S., Siswanta, D., and Santosa, S.J., 2009, Indones. J. Chem., 9 (2), 261–266.

[10] Djunaidi, M.C., Khabibi, and Trisna, D., 2010, Jurnal Kimia Sains dan Aplikasi, 13, 2, 16–24

[11] Djunaidi, M.C., Lusiana, R.A., Wibowa, P.J., Siswanta, D., and Jumina, 2007, Alchemy, 6, 40–49.

[12] Buhani, Narsito, Nuryono, and Kunarti, E.S., 2010, Desalination, 251 (1-3), 83–89.

[13] Nakayama, F.S., and Bucks, D.A., 1991, Irrig. Sci., 12 (4), 187–192.

[14] Merle, G., Hosseiny, S.S., Wessling, M., and Nijmeijer, K., 2012, J. Membr. Sci., 409-410, 191–199.

[15] Santoso, U.T., Nurmasari, R., Umaningrum, D., Santosa, S.J., Rusdiarso, B., and Siswanta, D., 2012, Indones. J. Chem., 12 (1), 35–42.

[16] Lodeiro, P., Fuentes, A., Herrero, R., and de Vicente, M.E.S., 2008, Environ. Chem., 5 (5), 355–365.

[17] Owens, G.S., Southard, G.E., Van Houten, K.A., and Murray, G.M., 2005, Sep. Sci. Technol., 40 (11), 2205–2211.

[18] Singh, D.K., and Mishra, S., 2010, J. Sci. Ind. Res., 69 (10), 767–772.

[19] Baes, F.C., and Mesmer, R.E., 1976, The Hydrolisis of Cations, John Wiley, NewYork.

[20] Chen, J.H., Li, G.P., Liu, Q.L., Ni, J.C., Wu, W.B., and Lin, J.M., 2010, Chem. Eng. J. 165 (2), 465–473.

[21] Chen, J.H., Lin, H., Luo, Z.H., He, Y.S., and Li, G.P., 2011, Desalination, 277 (1-3), 265–273.

[22] Karthikeyan, G., Andal, N.M., and Anbalagan, K., 2005, J. Chem. Sci., 117 (6), 663–672.

[23] Qiu, H., Lu, L.V., Pan, B.C., Zang, Q.J., Zhang, W.M., and Zhang, Q.X., 2009, J. Zhejiang Univ. Sci., A, 10 (5), 716–724.

[24] Ho, Y.S., and McKay, G., 1999, Process Biochem., 34 (5), 451–465.

[25] Masykur, A., Santosa, S.J., Siswanta, D., and Jumina, 2014, Indones. J. Chem., 14 (2), 152–159.

[26] Wang, L., Li, Q., and Wang, A., 2010, Polym. Bull., 65 (9), 961–975.


Article Metrics

Abstract views : 1732 | views : 2121

Copyright (c) 2015 Indonesian Journal of Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.


Indonesian Journal of Chemistry (ISSN 1411-9420 / 2460-1578) - Chemistry Department, Universitas Gadjah Mada, Indonesia.

Analytics View The Statistics of Indones. J. Chem.