Synthesis, Characterization and Crystal Structures of Mixed-Ligand Complexes of [Cu(bipy)2N3(ClO4)] and [Cu(5,5’-DiMebipy)2(N3)](ClO4)

https://doi.org/10.22146/ijc.21139

Oluwafunmilayo Florence Adekunle(1*), Ray John Butcher(2), Oladapo Bakare(3), Joseph Anthony Orighomisan Woods(4), Olusegun Ayobami Odunola(5)

(1) Department of Chemistry, Howard University, 525 College Street, Washington DC
(2) Department of Chemistry, Howard University, 525 College Street, Washington DC
(3) Department of Chemistry, Howard University, 525 College Street, Washington DC
(4) Department of Chemistry, University of Ibadan, Ibadan, Oyo-State
(5) Department of Chemistry, Hallmark University, Ijebu-Itele, Ogun-State
(*) Corresponding Author

Abstract


Two mixed –ligand complexes [Cu(bipy)2N3(ClO4)] and [Cu(5,5’-DiMebipy)2(N3)](ClO4) have been prepared and characterized. The compounds were characterized by elemental analyses, IR and UV-Visible spectroscopy, room temperature magnetic susceptibility measurements, and conductivity measurement, while the solid-state structures have been established by single-crystal X-ray diffraction analyses. [Cu(bipy)2N3(ClO4)]crystallizes in the monoclinic space group P21/c with cell constants a = 16.9027(3) Å, b = 7.59087(9) Å, c = 17.2614(3) Å, β = 111.2808(19)° and Z = 4. [Cu(5,5’-DiMebipy)2(N3)](ClO4) also crystallizes in the monoclinic space group P21/c with the cell constants a = 16.0312(11) Å, b = 7.9889(5) Å, c = 20.7167(18) Å, β = 110.285(8)° and Z = 4. The UV-Vis spectra and X-ray determination indicate that [Cu(bipy)2N3(OClO3)] is distorted octahedral ligand field and non-electrolyte in nature while [Cu(5,5’-DiMebipy)2(N3)](ClO4) is a square pyramidal five coordinate complex and a 1:1 electrolyte. The magnetic moments of the two complexes in the range 1.78–1.83 B.M. reveal a single unpaired electron with a slight orbital contribution.

Keywords


monoclinic; electronic spectra; electrolyte; 2,2’-bipyridyl; X-ray structure

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References

[1] Bhattacharjee, C.R., and Nath, A., 2012, Res. J. Pharm. Biol. Chem. Sci., 3 (2), 73–78.

[2] Patil, A.R., Donde, K.J., Raut, S.S., Patil, V.R., and Lokhande, R.S., 2012, J. Chem. Pharm. Res., 4 (2), 1413–1425.

[3] Alimarin, I.P., and Shlenskaya, V.I., 1970, Pure Appl. Chem., 21 (4), 461–478.

[4] Adekunle, F.A.O., and Odunola, O.A., 2013, Chem. Sci. Trans., 2 (2), 491–496.

[5] Lu, L.P., Zhu, M.L., and Yang, P., 2003, J. Inorg. Biochem., 95 (1), 31–36.

[6] Nakai, H., 1971, Bull. Chem. Soc. Jpn., 44, 2412–2415.

[7] Hathaway, B.J., Procter, I.M., Slade, R.C., and Tomlinson, A.A.G., 1969, J. Chem. Soc. A, 2219–2224.

[8] Foley, J., Kennefick, D., Phelan, D., Tyagi, S., and Hathaway, B.J., 1983, J. Chem. Soc., Dalton Trans., 10, 2333–2338.

[9] Foley, J., Tyagi, S., and Hathaway, B.J., 1984, J. Chem. Soc., Dalton Trans., 1, 1–5.

[10] Onawumi, O.O.E., Odunola, O.A., Eringathodi, S., and Paul, P., 2011, Inorg. Chem. Commun., 14 (10), 1626–1631.

[11] Kabesova, M., Boca, R., Melnik, M., Valigura, D., and Dunaj-Jurco, M., 1995, Coord. Chem. Rev., 140, 115–135.

[12] Youngme, S., Phuenghai, P., Pakawatchai, C., Kongsaeree, P., and Chaichit, N., 2008, Acta Crystallogr., Sect. B: Struct. Sci., B64 (3), 318–329.

[13] Chattopadhyay, S., Bhar, K., Khan, S., Mitra, P., Butcher, R.J., and Ghosh, B.K., 2010, J. Mol. Struct., 966 (1-3), 102–106.

[14] Mukherjee, S., Gole, B., Song, Y., and Mukherjee, P.S., 2011, Inorg. Chem., 50 (8), 3621–3631.

[15] Chakraborty, A., Lingampalli, S.R., Kumari, A., Ribas, J., Ribas-Arino, J., and Maji, T.K., 2014, Inorg. Chem., 53 (22), 11991–12001.

[16] Naiya, S., Biswas, C., Drew, M.G.B., Gómez-García, C.J., Clemente-Juan, J.M., and Ghosh, A., 2010, Inorg. Chem., 49 (14), 6616–6627.

[17] Reger, D.L., Pascui, A.E., Smith M.D., Jezierska, J., and Ozarowski, A., 2015, Inorg. Chem., 54 (4), 1487–1500.

[18] Ni, L., You, Z., Zhang, L., Wang, C., and Li, K., 2010, Transition Met. Chem., 35 (1), 13–17.

[19] Mohamadou, A., van Albada, G.A., Mutikainen, I., Turpeinen, U., Marrot, J., and Reedijk, J., 2009, Polyhedron, 28 (14), 2813–2820.

[20] Agilent Technologies, 2012, CrysAlis PRO, Agilent Technologies, Yarnton, England.

[21] Bruker, 2005, APEX2, Bruker AXS Inc., Madison, Wisconsin, USA.

[22] Sheldrick, G.M., 2008, Acta Crystallogr., Sect. A: Found. Crystallogr., A64 (1), 112–122.

[23] Basak, S., Sen, S., Banerjee, S., Mitra, S., Rosair, G., and Rodriguez, M.T.G., 2007, Polyhedron, 26 (7), 5104–5112.

[24] Shaabani, B., Khandar, A.A., Mahmoudi, F., Maestro, M.A., Balula, S.S., and Cunha-Silva, L., 2013, Polyhedron, 57, 118–126.

[25] Roy, P., Dhara, K., Manassero M., and Banerjee, P., 2008, Inorg. Chem. Commun., 11 (3), 265–269.

[26] Neelakantan, M.A., Sundaram, M., and Nair, M.S., 2011, Spectrochim. Acta, Part A, 79 (5), 1693–1703.

[27] Khandar, A.A., Hosseini-Yazdi, S.A., Khatamian, M., McArdle, P., and Zarei, S.A., 2007, Polyhedron, 26 (1), 33–38.

[28] Addison, A.W., Rao, T.N., Reedijk, J., van Rijn, J., and Verschoor, G.C., 1984, J. Chem. Soc., Dalton Trans., 7, 1349–1356.

[29] Adekunle, F.A.O., Semire, B., and Odunola, O.A., 2015, Synth. React. Inorg. Met.-Org. Chem., 45, 1102–1107.

[30] Shee, N.K., Adekunle, F.A.O., Verma, R., Kumar, D., and Datta, D., 2015, Spectrochim. Acta, Part A, 151, 96–99.

[31] Adekunle, F.A.O., Semire, B., and Odunola, O.A., 2013, Elixir Int. J., 61, 17019–17023.

[32] Al-Ayaan, U., and Gabr, I.M., 2007, Spectrochim. Acta, Part A, 67 (1), 263–272.

[33] Emara, A.A.A., Abu-Hussein A.A.A., Taha, A.A., and Mahmoud N.H., 2010, Spectrochim. Acta, Part A, 77 (3), 594–604.

[34] Bhattacharya, S., and Mohanta, S., 2015, Inorg. Chim. Acta, 432, 169–175.

[35] Roy, P., Dhara, K., Manassero, M., and Banerjee, P., 2008, Inorg. Chem. Commun., 11 (3), 265–269.

[36] Raj, K.M., Vivekanand, B., Nagesh, G.Y., and Mruthyunjayaswamy, B.H.M., 2014, J. Mol. Struct., 1059, 280–293.

[37] Shobana, S., Dharmaraja, J., and Selvaraj, S., 2013, Spectrochim. Acta, Part A, 107, 117–132.

[38] Montazerozohori, M., 2013, J. Therm. Anal. Calorim., 111, 121–128.

[39] Dolaz, M., McKee, V., Uruş, S., Demir, N., Sabik, A.E., Gölcü, A., and Tümer, M., 2010, Spectrochim. Acta, Part A, 76 (2), 174–181.

[40] Dolaz, M., McKee, V., Gölcü, A., and Tümer, M., 2009, Spectrochim. Acta, Part A, 71 (6), 1648–1654.

[41] Abd El-halim, H.F., Omar, M.M., and Mohamed G.G., 2011, Spectrochim. Acta, Part A, 78 (1), 36–44.

[42] Patil, R.M., and Prabhu, M.M., 2010, Int. J. Chem. Sci., 8 (1), 52–58.

[43] Babu, M.S.S., Reddy, K.H., and Krishna, P.G., 2007, Polyhedron, 26 (3), 572–580.

[44] Arjmand, F., and Aziz, M., 2009, Eur. J. Med. Chem., 44 (2), 834–844.

[45] Rajendiran, V., Karthik, R., Palaniandavar, M., Stoeckli-Evans, H., Periasamy, V.S., Akbarsha, M.A., Srinag, B.S., and Krishnamurthy, H., 2007, Inorg. Chem., 46 (20), 8208–8221.

[46] Angelusiu, M.V., Barbuceanu, S-F., Draghici, C., and Almajan, G.L., 2010, Eur. J. Med. Chem., 45 (5), 2055–2062.

[47] Elzahany, E.A., Hegab, K.H., Khalil, S.K.H., and Youssef, N.S., 2008, Aust. J. Basic Appl. Sci., 2 (2), 210–220.

[48] Agwara, M.O., Ndifon, P.T., Ndosiri, N.B., Paboudam, A.G., Yufanji, D.M., and Mohamadou, A., 2010, Bull. Chem. Soc. Ethiop., 24 (3), 383–389.

[49] Barve, A., Kumbhar, A., Bhat, M., Joshi, B., Butcher R., Sonawane, U., and Joshi, R., 2009, Inorg. Chem., 48 (19), 9120–9132.

[50] Dong, W.K., He, X.N.,Yan, H.B., Lv, Z.W., Chen, X., Zhao, C.Y., and Tang, X.L., 2009, Polyhedron, 28 (8), 1419–1428.

[51] Efthimiadou, E.K., Katsaros, N., Karaliota, A., and Psomas, G., 2007, Inorg. Chim. Acta, 360, 4093–4102.

[52] Kala, U.L., Suma, S., Kurup, M.R.P., Krishnan, S., and John, R.P., 2007, Polyhedron, 26 (7), 1427–1435.

[53] Yenikaya, C., Poyraz, M., Sari, M., Demirci, F., IIkimen, H., and Büyükgüngör, O., 2009, Polyhedron, 28 (16), 3526–3532.

[54] Dong, W.K., Sun, Y.X., Zhang, Y.P., Li, L., He, X.N., and Tang, X.L., 2009, Inorg. Chim. Acta, 362 (1), 117–124.

[55] Efthimiadou, E.K., Katsaros, N., Karaliota, A., and Psomas, G., 2008, J. Inorg. Biochem., 102 (4), 910–920.

[56] Devereux, M., Shea, D.O., Kellett, A., McCann, M., Walsh, M., Egan, D., Deegan, C., Kędziora, K., Rosair, G., and Müller-Bunz, H., 2007, J. Inorg. Biochem., 101 (6), 881–892.

[57] Montazerozohori, M., Nozarian, K., and Ebrahimi, H.R., 2013, J. Spectro., 2013, 1–9.



DOI: https://doi.org/10.22146/ijc.21139

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