Skip to main navigation menu Skip to main content Skip to site footer
Page Header Logo

Research article

Vol 18 No 3 (2024): Volume 18, Number 3, 2024

Extraction of manganese from Indonesian manganese ore using sugarcane bagasse-acid reductive leaching

DOI
https://doi.org/10.22146/jrekpros.17591
Submitted
November 11, 2024
Published
December 31, 2024

Abstract

In this study, sugarcane bagasse was used as a reducing agent in manganese leaching from manganese ore from Way Kanan, Lampung under acidic conditions using sulfuric acid as a leaching reagent. Bagasse is an agricultural waste from the cane sugar manufacturing industry which is commonly found in Lampung Province. This agricultural waste has the potential to become a reducing agent in manganese leaching because it contains carbon in the form of cellulose and sugar. The optimization of the leaching conditions has been investigated with the parameters of H2SO4 concentration, temperature, and pulp density. The highest manganese leaching recovery was obtained under the following optimized conditions: 1 M H2SO4 concentration, 14 g sugarcane bagasse/20 g MnO2, 50 g/L pulp density, 80 °C leaching temperature, 200 rpm stirring rate, and 4 hours of reaction time. The present process therefore deals with achieving the effective recovery of value-added products from low-grade manganese ore using agriculture waste as reducing agent.

References

  1. Anggraeni RD, Prasetya A, Petrus HTBM, Cahyono RB, Sumardi S, Astuti W. 2019. Performance of kulon progo low grade manganese ore leaching using acetic acid and its selectivity. IOP Conference Series: Materials Science and Engineering. 478:012008. doi:10.1088/1757- 899x/478/1/012008.
  2. Astuti W, Mufakhir FR, Prasetyo E, Sumardi S, Yuda APT, Nurjaman F, Supriyatna YI, Handoko AS. 2019. Reductiveatmospheric leaching of manganese from pyrolusite ore using various reducing agents. AIP Conference Proceedings. Volume 2097. Author(s). p. 030117. doi:10.1063/1.50 98292.
  3. Cheng X, Guo G, Cheng Y, Liu M, Ji J. 2022. Effect of hydrogen peroxide on the recovery of valuable metals from spent lini0.6co0.2mn0.2o2 batteries. Energy Technology. 10(4). doi:10.1002/ente.202200039.
  4. Deng L, Qu B, Su SJ, Ding SL, Sun WY. 2018. Extraction of iron and manganese from pyrolusite absorption residue by ammonium sulphate roasting–leaching process. Metals. 8(1):38. doi:10.3390/met8010038.
  5. Du J, Zhang Y, Lu J, Chen J, Gao L, Guo S, Omran M, Chen G. 2023. Mechanism of enhanced enrichment manganese from manganese ore-pyrite under microwave heating: Process optimization and kinetic studies. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 656:130534. doi:10.1016/j.colsurfa.2022.130534.
  6. Ma Y, Zhou X, Tang J, Liu X, Gan H, Yang J. 2021. Reaction mechanism of antibiotic bacteria residues as a green reductantforhighlyefficientrecyclingofspentlithium-ion batteries. Journal of Hazardous Materials. 417:126032. doi:10.1016/j.jhazmat.2021.126032.
  7. Okonkwo EG, Wheatley G, He Y. 2021. The role of organic compounds in the recovery of valuable metals from primary and secondary sources: a mini-review. Resources, Conservation and Recycling. 174:105813. doi:10.1016/j.rescon rec.2021.105813.
  8. Prasetyo E, Purwaningsih E, Astuti W. 2019. Selectivereductive leaching of manganese from low-grade manganese ore using tannic acid as reductant. Mining, Metallurgy & Exploration. 36(5):1003–1012. doi:10.1007/s424 61-019-00115-6.
  9. Raj T, Chandrasekhar K, Kumar AN, Sharma P, Pandey A, Jang M, Jeon BH, Varjani S, Kim SH. 2022. Recycling of cathode material from spent lithium-ion batteries: Challenges and future perspectives. Journal of Hazardous Materials. 429:128312. doi:10.1016/j.jhazmat.2022.128312.
  10. Sinha MK, Purcell W. 2019. Reducing agents in the leaching of manganese ores: A comprehensive review. Hydrometallurgy. 187:168–186. doi:10.1016/j.hydromet.2019.05.021.
  11. Sinha MK, Purcell W, Van Der Westhuizen WA. 2020. Recovery of manganese from ferruginous manganese ore using ascorbic acid as reducing agent. Minerals Engineering. 154:106406. doi:10.1016/j.mineng.2020.106406.
  12. Sun Y, Fu G, Jiang L. 2017. Kinetic study of the leaching of lowgrade manganese ores by using pretreated sawdust as reductant. Minerals. 7(5):83. doi:10.3390/min7050083.
  13. Wang Y, Jin S, Lv Y, Zhang Y, Su H. 2017. Hydrometallurgical process and kinetics of leaching manganese from semioxidized manganese ores with sucrose. Minerals. 7(2):27. doi:10.3390/min7020027.
  14. Wu Ff, Zhong H, Wang S, Lai Sf. 2014. Kinetics of reductive leaching of manganese oxide ore using cellulose as reductant. Journal of Central South University. 21(5):1763– 1770. doi:10.1007/s11771-014-2122-1.
  15. Wu H, Feng Y, Li H, Wang H, Ju J. 2020. Co-recovery of manganese from pyrolusite and gold from carbonaceous gold ore using fluidized roasting coupling technology. Chemical Engineering and Processing - Process Intensification. 147:107742. doi:10.1016/j.cep.2019.107742.
  16. Xiong S, Li X, Liu P, Hao S, Hao F, Yin Z, Liu J. 2018. Recovery of manganese from low-grade pyrolusite ore by reductively acid leaching process using lignin as a low cost reductant. Minerals Engineering. 125:126–132. doi:10.1016/j.mineng .2018.06.003.
  17. Xue J, Zhong H, Wang S, Li C, Li J, Wu F. 2016. Kinetics of reduction leaching of manganese dioxide ore with phytolacca americana in sulfuric acid solution. Journal of Saudi Chemical Society. 20(4):437–442. doi:10.1016/j.jscs .2014.09.011.
  18. Yang Y, Okonkwo EG, Huang G, Xu S, Sun W, He Y. 2021. On the sustainability of lithium ion battery industry – a review and perspective. Energy Storage Materials. 36:186– 212. doi:10.1016/j.ensm.2020.12.019.
  19. You Z, Li G, Dang J, Yu W, Lv X. 2018. The mechanism on reducing manganese oxide ore with elemental sulfur. Powder Technology. 330:310–316. doi:10.1016/j.powtec.2018.02.0 35.
  20. Zhang C, Wang S, Cao Zf, Zhong H. 2018. Two-stage leaching of manganese and silver from manganese–silver ores by reduction with calcium sulfide and oxidation with copper(ii). Hydrometallurgy. 175:240–249. doi:10.1016/j.hy dromet.2017.12.002.
  21. Zhang T, Wang H, Wang J, Zhao P. 2017. Process for reduction leaching pyrolusite using hull. IOP Conference Series: Earth and Environmental Science. 94:012187. doi: 10.1088/1755-1315/94/1/012187.
  22. Zhou X, Ma Y, Liu X, Tang J, Zhou C, Guo L, Yang J. 2021. Synergistic leaching mechanism of chloride ions for extracting manganese completely from manganese carbonate ores. Journal of Environmental Chemical Engineering. 9(1):104918. doi:10.1016/j.jece.2020.104918.
  23. Zou Q, Zeng H, Wang L, Liu Z, Liu B, Li J, Xiong L, Wu X, Xiang Y. 2023. Efficient recycling of electrolytic manganese anode mud for the preparation of cathode materials for aqueous zinc ion batteries. Journal of Electroanalytical Chemistry. 928:117044. doi:10.1016/j.jelechem.2022.1170 44.