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Research article

Vol 11 No 1 (2017): Volume 11, Number 1, 2017

Uji validitas model shrinking core terhadap pengaruh konsentrasi asam sitrat dalam proses leaching nikel laterit

DOI
https://doi.org/10.22146/jrekpros.23321
Submitted
November 14, 2023
Published
June 30, 2017

Abstract

Atmospheric pressure acid leaching process is one of nickel laterite processing which has a big potential to be applied in industry. The leaching process is influenced by several factors and one of them is concentration of acid as leachant. The purpose of this present study is to learn the effect of concentration of citric acid  on the use of shrinking core kinetic model. The process was done by varying citric acid concentration at 0.1, 1, and 2 M. The other operation conditions, such as particle size, solid-liquid ratio, temperature, stirring speed, and leaching process were kept constant at 125-150 μm, 0,2 sample mass/volume of acid solution, 85 oC, 200 rpm, and 120 minutes, respectively. The experimental results showed that the higher concentration of citric acid was used, the higher the percentage recovery of nickel was obtained. In addition, the validity test of shrinking core model indicated a positive impact to describe physical phenomenon of leaching process.

References

Agacayak, T., & Zedef, V., 2012, "Dissolution kinetics of a lateritic nickel ore in sulfuric acid medium," Ročnik, 17, 33-41.

Astuti, W., Hirajima, T., Sasaki, K., Okibe, N., 2015, "Kinetics of nickel extraction from Indonesian saprolitic ore by citric acid leaching under atmospheric pressure," Minerals & Metallurgical Processing, 32(3), 176-185.

Astuti, W., Hirajima, T., Sasaki, K., Okibe, N., 2016, "Comparison of effectiveness of citric acid and other acids in leaching of low-grade Indonesian saprolitic ores," Minerals Engineering, 85, 1-16.

Ayanda, O., S., Adekola, F., A., Baba, A., A., Fatoki, O., S., Ximba, B., J., 2011, "Comparative Study of the Kinetics of Dissolution of Laterite in some Acidic Media," Journal of Minerals & Materials Characterization & Engineering, 10(15), 1457-1472.

Dalvi, A., D., Bacon, W., G., dan Osborne, R. C., 2004, "The Past and the Future of Nickel Laterites," PDAC 2004 International Convention, Trade Show & Inventors Exchange.

Kusuma, G. D., 2012, "Pengaruh Reduksi Roasting dan Konsentrasi Leaching Asam Sulfat terhadap Recovery Nikel dari Bijih Limonite," Skripsi, Universitas Indonesia.

Kyle, J., 2010, "Nickel laterite processing technologies – Where to next?," ALTA 2010 Nickel/Cobalt/Copper Conference, Australia.

Levenspiel, O., 1999, "Chemical Reaction Engineering," John Wiley & Sons, New York.

McDonald, R., G. dan Whittington, B., I., 2008, "Atmospheric acid leaching of nickel laterites review: Part I. Sulphuric acid technologies," Hydrometallurgy, 91, 35-55.

McDonald, R., G. dan Whittington, B., I., 2008, "Atmospheric acid leaching of nickel laterites review: Part II. Chloride and biotechnologies," Hydrometallurgy, 91, 56-69.

Simate, G., S., Ndlovu, S., Walubita, L., F., 2010, "The fungal and chemolithotrophic leaching of nickel laterites – Challenges and opportunities," Hydrometallurgy, 103, 150-157.

Sukla, L., B., Behera, S., K., dan Pradhan, N., 2014, "Microbial Recovery of Nickel from Lateritic (Oxidic) Nickel Ore: A Review," dalam Geomicrobiology and Biogeochemistry, vol. 39, Springer Berlin Heidelberg, 137-151.

Tzeferis, P., G., 1994, "Leaching of a low-grade hematitic laterite ore using fungi and biologically produced acid metabolites," Int. J. Miner. Process, 42, 267-283.

Wanta, K., C., Perdana, I., Petrus, H., T., B., M., 2016, "Evaluation of shrinking core model in leaching process of Pomalaa nickel laterite using citric acid as leachant at atmospheric conditions," Second International Conference on Chemical Engineering (ICCE) UNPAR, IOP Conf. Series: Materials Science and Engineering, 162, Indonesia.