Eco-friendly Alkyd Resins Based on Vegetable Oil: Review

Okta Amelia; Illah Sailah; Ika Amalia Kartika; Ono Suparno; Yazid Bindar

doi:10.22146/jrekpros.64143

Eco-friendly Alkyd Resins Based on Vegetable Oil: Review

https://doi.org/10.22146/jrekpros.64143

Okta Amelia^(1*), Illah Sailah⁽²⁾, Ika Amalia Kartika⁽³⁾, Ono Suparno⁽⁴⁾, Yazid Bindar⁽⁵⁾

(1) Department of Agro-industrial Technology, IPB University, Bogor, Indonesia, 16680
(2) Department of Agro-industrial Technology, IPB University, Bogor, Indonesia, 16680
(3) Department of Agro-industrial Technology, IPB University, Bogor, Indonesia, 16680
(4) Department of Agro-industrial Technology, IPB University, Bogor, Indonesia, 16680
(5) Department of Bioenergy Engineering and Chemurgy, Faculty of Industrial Technology, Bandung Institute of Technology, Bandung 40116
(*) Corresponding Author

Abstract

The alkyd resin industry currently needs environmentally friendly raw materials, which emphasized the aspect of sustainability. Alkyd resin is a polymer product with oil as raw material which is widely used in the paint, coating, and other industries. The abundant demand for alkyd resin has led to a diversification of the raw material for alkyd resin from vegetable oils. The advantages of vegetable oil include being a renewable energy source for industry, sustainability, biodegradability, and being environmentally friendly as important considerations for the industry in recent times. This paper examines alkyd resins derived from several vegetable oils that are environmentally friendly. Alkyd resin is prepared by alcoholysis and esterification. Based on several studies of alkyd resins, there have been many modifications to the raw materials, technology, and catalysts used which can refer to an environmentally friendly and affordable industry.

Keywords: alkyd resin; biodegradability; environmentally friendly; sustainability; vegetable oil

A B S T R A K

Industri polimer pada masa ini membutuhkan bahan baku yang ramah lingkungan, yang menekankan pada keberlanjutan. Alkid resin adalah salah satu produk berbasis minyak yang banyak digunakan dalam industri cat, coating, dan industri lainnya. Keberlanjutan, biodegradabilitas, dan keramahan terhadap lingkungan menjadi pertimbangan signifikan bagi industri berbasis minyak nabati dalam beberapa waktu terakhir. Di dalam naskah ini, diulas beberapa minyak nabati yang digunakan untuk memproduksi alkid resin dengan cara alkoholisis dan esterifikasi. Berdasarkan berbagai studi yang telah dilakukan, masih terdapat modifikasi dari sisi material, teknologi dan katalis agar tercipta industri yang ramah lingkungan.

Kata kunci: alkid resin; biodegradabilitas; keberlanjutan; minyak nabati; ramah lingkungan

Keywords

alkyd resin; biodegradability; environmentally friendly; sustainability; vegetable oil

Full Text:

PDF

References

Aigbodion, A.I. and Okieimen, F.E., 2001, An investigation of the utilisation of African locustbean seed oil in the preparation of alkyd resins, Ind. Crops Prod., 13 (1), 29–34.

Alam, M., Akram, D., Sharmin, E., Zafar, F. and Ahmad, S., 2014, Vegetable oil based eco-friendly coating materials: A review article, Arab. J. Chem., King Saud University, 7 (4), 469–479.

Anya, A., Jack, I. and Osagie, O., 2016, Synthesis and characterization of oil-modified alkyd resin from epoxidized neem oil, Am. Chem. Sci. J., 15 (2), 1–7.

Chiplunkar, P.P. and Pratap, A.P., 2016, Utilization of sunflower acid oil for synthesis of alkyd resin, Prog. Org. Coatings, Elsevier B.V., 93, 61–67.

Derksen, J.T.P., Cuperus, F.P. and Kolster, P., 1996, Renewable resources in coatings technology: A review, Prog. Org. Coatings, 27 (1–4), 45–53.

Dutta, Karak and Dolui., 2006, Alkyd-epoxy blends as multipurpose coatings, Apll. Polym. Sci., 100, 516–521.

El-Enin, A., Attia, N., El-Ibiari, N., El-Diwani, G. and El-Khatib, K., 2013, In situ transesterification of rapeseed and cost indicators., Renew. Sustain. Energy Rev., 18, 471–477.

Elba, M.E., Abdel Rehim, E.M. and Ashery, R.E., 2018, Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst, Int. J. Chem. Technol., 2 (1), 34–43.

Godfrey, O.O., Ifijen, I.H., Mohammed, F.U., Aigbodion, A.I. and Ikhuoria, E.U., 2019, Alkyd resin from rubber seed oil/linseed oil blend: A comparative study of the physiochemical properties, Heliyon, 5 (5), 0–4.

Haas, M., Scott, K., Marmer, W. and Foglia, T., 2004, In situ alkaline transesterification : an effective method for the production of fatty acids esters from vegetable oils, JAOCS, 81 (1), 83–89.

Haseebuddin, S., Parmar, R., Waghoo, G. and Ghosh, S.K., 2009, Study of hexafunctional polyol in high solids air-drying alkyd: improved film performance, Prog. Org. Coat., 64, 446–453.

Hofland, A., 2012, Alkyd resins: from down and out to alive and kicking., Prog. Org. Coat., 73, 274–282.

Ikhuoria, E.U., Aigbodion, A.I. and Okieimen, F.E., 2007, Enhancing the quality of alkyd resins using methyl esters of rubber seed oil, Trop. J. Pharm. Res., 3 (1), 311–316.

Işeri-Çaǧlar, D., Baştürk, E., Oktay, B. and Kahraman, M.V., 2014, Preparation and evaluation of linseed oil based alkyd paints, Prog. Org. Coatings, 77 (1), 81–86.

Islam, M.R., Beg, M.D.H. and Jamari, S.S., 2014, Development of vegetable-oil-based polymers, J. Appl. Polym. Sci., 131 (18), 9016–9028.

Kildiran, G., Yücel, S.Ö. and Türkay, S., 1996, In situ alcoholysis of soybean oil , J. Am. Oil Chem. Soc., 73 (2), 225–228.

Kyenge, B. a, Anhwange, B. a, Ageh, J.T. and Igbum, G.O., 2012, Comparative analysis of soybean seed oil modified alkyd resin and epoxidized soybean seed oil modified alkyd resin, Int. J. Mod. Org. Chem., 1 (2), 66–71.

Lligadas, G., Ronda, J.C., Galià, M. and Cádiz, V., 2013, Renewable polymeric materials from vegetable oils: A perspective, Mater. Today, 16 (9), 337–343.

Mutar, M.A. and Hassan, N.M.A., 2017, Synthesis and characterization of new alkyd resins ( short , medium and long ) based on sunflower oil and linoleic acid as ( short , medium and long ) based on sunflower oil and linoleic acid as binder for paints, J. Chem. Petrochemical Technol., 7 (February), 1–16.

Nurandini, D., Rochmadi and Murachman, B., 2018, Karakterisasi alkyd resin dari gliserol dan asam adipat yang dimodifikasi dengan minyak biji karet sebagai komponen surface coating yang ramah lingkungan, J. GEOSAPTA, 4 (2), 139–142.

Ploeger, R. and Chiantore, O., 2012, Characterization and stability issues of artists ’ alkyd paints, Smithson. Contrib. to Museum Conserv., 3 (November 2010), 89–95.

Salimon, J., Salih, N. and Yousif, E., 2012, Industrial development and applications of plant oils and their biobased oleochemicals, Arab. J. Chem., King Saud University, 5 (2), 135–145.

Selim, M.S., Shenashen, M.A., Elmarakbi, A., Saeed, A.M.E.-, Selimd, M.M. and El-Safty, S.A., 2017, Sunflower oil-based hyperbranched alkyd/spherical ZnO nanocomposite modeling for mechanical and anticorrosive applications, R. Soc. Chem., 7, 21796–21808.

Soucek, M.D. and Salata, R.R., 2014, Alkyd Resin Synthesis, Encycl. Polym. Nanomater., pp. 6–11.

Sutanti, S., Purnavita, S., Sriyana, H.Y. and Pembahasan, H., 2013, Pemanfaatan minyak biji rami (linseed oil) dan gliserol by-product biodiesel, Media Komun. Rekayasa Proses dan Teknol. Tepat Guna, 9 (1), 8–14.

Umeobika UC, Onuegbu TU, Iloamaeke MI and Ekwueme IJ., 2013, Synthesis and evaluation of performance characteristics of rubber seed oil-modified short and medium alkyd resins, Int. J. Sci. Innov. Discov., 3 (1), 86–92.

Uzoh, C.F. and Nwabanne, J.T., 2016, Investigating the effect of catalyst type and concentration on the functional group conversion in castor seed oil alkyd resin production, Adv. Chem. Eng. Sci., 06 (02), 190–200.

Wibowo, H.B., 2013, Karakterisasi dan pengujian resin polyalkyd alami sebagai elastomer, Chem. Prog, 6 (1), 1–5.

Winarsi, D.., 2010, Protein Kedelai dan Kecambah, Kanisius, Yogyakarta.

Xia, Y. and Larock, R.C., 2010, Vegetable oil-based polymeric materials: Synthesis, properties, and applications, Green Chem., 12 (11), 1893–1909

DOI: https://doi.org/10.22146/jrekpros.64143