Spent Coffee Grounds Biochar Composite Phase Change Material Design Challenges in a Lab-Scale Solar Water Heater System for Thermal Energy Storage

https://doi.org/10.22146/ajche.80081

Raphael Angelo Mondragon(1), Sasipa Boonyubol(2), Shuo Cheng(3), Jeffrey Scott Cross(4*)

(1) Department of Transdisciplinary Science and Engineering, School of Environment and Society, Tokyo Institute of Technology, 2-12-1 S6-10 Ookayama, Meguro-ku, Tokyo, 152-8550, Japan
(2) Department of Transdisciplinary Science and Engineering, School of Environment and Society, Tokyo Institute of Technology, 2-12-1 S6-10 Ookayama, Meguro-ku, Tokyo, 152-8550, Japan
(3) Department of Transdisciplinary Science and Engineering, School of Environment and Society, Tokyo Institute of Technology, 2-12-1 S6-10 Ookayama, Meguro-ku, Tokyo, 152-8550, Japan
(4) Department of Transdisciplinary Science and Engineering, School of Environment and Society, Tokyo Institute of Technology, 2-12-1 S6-10 Ookayama, Meguro-ku, Tokyo, 152-8550, Japan
(*) Corresponding Author

Abstract


Thermal energy storage systems that use composite phase change materials (CPCM), such as paraffin wax and nonbiodegradable high-density polyethylene, are gaining attention in recent years due to the effort to resolve energy issues. There is a need to undertake research and development on how to prepare durable CPCMs from thermo-chemically treated biowastes, a renewable resource. Raw spent coffee grounds (SCG) have been experimented on previously, but more research needs to be conducted on CPCMs prepared from pyrolyzed SCG-biochar (SCGB) for use in a water tank. This research investigated a biodegradable CPCM made from SCGB and carnauba wax in a lab-scale solar water heater system. The carnauba wax loading of 60% was chosen due to the minimized thermal wax leakage from the PCM. Thermal characterization results revealed that the latent heat of SCGB CPCM is 88.47 J/g which was found to be competitive compared to other biodegradable CPCMs reported earlier. The results also show further potential for using SCGB and carnauba wax as a CPCM in a thermal energy storage system.


Keywords


Biochar; Phase Change Material; Spent Coffee Grounds; Carnauba Wax; Solar Water-Heater; Thermal Energy Storage

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References

Al-Kayiem, H.H., and Lin, S.C., 2014. “Performance evaluation of a solar water heater integrated with a PCM nanocomposite TES at various inclinations.” Sol. Energy, 109, 82–92.

Atinafu, D.G., Chang, S.J., Kim, K.-H., and Kim, S., 2020. “Tuning surface functionality of standard biochars and the resulting uplift capacity of loading/energy storage for organic phase change materials.” Chem. Eng., J. 394, 125049.

Ballesteros, L.F., Teixeira, J.A., and Mussatto, S.I., 2014. “Chemical, functional, and structural properties of spent coffee grounds and coffee silverskin.” Food Bioprocess Technol., 7, 3493–3503.

Chen, Y., Cui, Z., Ding, H., Wan, Y., Tang, Z., and Gao, J., 2018. “Cost-effective biochar produced from agricultural residues and its application for preparation of high performance form-stable phase change material via simple method.” Int. J. Mol. Sci., 19, 3055.

Cheng, Q.-Y., An, X.-P., Li, Y.-D., Huang, C.-L., and Zeng, J.-B., 2017. “Sustainable and biodegradable superhydrophobic coating from epoxidized soybean oil and ZnO nanoparticles on cellulosic substrates for efficient oil/water separation.” ACS Sustain. Chem. Eng., 5, 11440–11450.

Craig, R.G., Powers, J.M., and Peyton, F.A., 1971. “Thermogravimetric analysis of waxes.” J. Dent. Res., 50, 450–454.

Das, D., Bordoloi, U., Muigai, H.H., and Kalita, P., 2020. “A novel form stable PCM based bio composite material for solar thermal energy storage applications.” J. Energy Storage, 30, 101403.

Dong, X., Gao, S., Huang, J., Li, S., Zhu, T., Cheng, Y., Zhao, Y., Chen, Z., and Lai, Y., 2019. “A self-roughened and biodegradable superhydrophobic coating with UV shielding, solar-induced self-healing and versatile oil–water separation ability.” J. Mater. Chem. A, 7, 2122–2128.

Ehid, R., and Fleischer, A.S., 2012. “Development and characterization of paraffin-based shape stabilized energy storage materials.” Energy Convers. Manag., 53, 84–91.

Hu, X., Huang, H., Hu, Y., Lu, X., and Qin, Y., 2021. “Novel bio-based composite phase change materials with reduced graphene oxide-functionalized spent coffee grounds for efficient solar-to-thermal energy storage.” Sol. Energy Mater. Sol. Cells, 219, 110790.

Huang, J., Wang, S., and Lyu, S., 2017. “Facile Preparation of a robust and durable superhydrophobic coating using biodegradable lignin-coated cellulose nanocrystal particles.” Materials, 10, 1080.

Jeon, J., Park, J.H., Wi, S., Yang, S., Ok, Y.S., and Kim, S., 2019. “Characterization of biocomposite using coconut oil impregnated biochar as latent heat storage insulation.” Chemosphere, 236, 124269.

Kadohiro, Y., Cheng, S., and Cross, J.S., 2021. “Solar thermoelectric lab-scale system with sensible/latent heat storage for reversible power generation and warm water heating.” J. Energy Storage, 44, 103278.

Kadohiro, Y., Cheng, S., and Cross, J.S., 2020. “All-Day Energy Harvesting Power System Utilizing a Thermoelectric Generator with Water-Based Heat Storage.” Sustainability, 12, 3659.

Kaygusuz, K., and Sari, A., 2007. “High density polyethylene/paraffin composites as form-stable phase change material for thermal energy storage.” Energy Sources Part A, 29, 261–270.

Kenisarin, M., and Mahkamov, K., 2007. “Solar energy storage using phase change materials.” Renew. Sustain. Energy Rev., 11, 1913–1965.

Krishna Mohan, G., Naga Babu, A., Kalpana, K., and Ravindhranath, K., 2019. “Removal of chromium (VI) from water using adsorbent derived from spent coffee grounds.” Int. J. Environ. Sci. Technol., 16, 101–112.

Li, H., Chen, H., Li, X., and Sanjayan, J.G., 2014. “Development of thermal energy storage composites and prevention of PCM leakage.” Appl. Energy, 135, 225–233.

Li, W.H., Lai-Iskandar, S., Tan, D., Simonini, L., Dudon, J.-P., Leong, F.N., Tay, R.Y., Tsang, S.H., Joshi, S.C., and Teo, E.H.T., 2020. “Thermal conductivity enhancement and shape stabilization of phase-change materials using three-dimensional graphene and graphene powder.” Energy Fuels, 34, 2435–2444.

LibreTexts Engineering, 2021. 8.6: Applications of Phase Change Materials for Sustainable Energy — eng.libretexts.org [WWW Document]. URL

Milionis, A., Ruffilli, R., and Bayer, I.S., 2014. “Superhydrophobic nanocomposites from biodegradable thermoplastic starch composites (Mater-Bi®), hydrophobic nano-silica and lycopodium spores.” Rsc Adv., 4, 34395–34404.

Muscat, D., Tobin, M.J., Guo, Q., and Adhikari, B., 2014. “Understanding the distribution of natural wax in starch–wax films using synchrotron-based FTIR (S-FTIR).” Carbohydr. Polym., 102, 125–135.

Nguyen, D.M., Nhung, V.T., Le Do, T.C., Ha-Thuc, C.N., and Perre, P., 2022. “Effective synergistic effect of treatment and modification on spent coffee grounds for sustainable biobased composites.” Waste Biomass Valorization, 13, 1339–1348.

Qu, Y., Wang, S., Tian, Y., and Zhou, D., 2019. “Comprehensive evaluation of Paraffin-HDPE shape stabilized PCM with hybrid carbon nano-additives.” Appl. Therm. Eng., 163, 114404.

Robertson, D., van Reenen, A., and Duveskog, H., 2020. “A comprehensive investigation into the structure-property relationship of wax and how it influences the properties of hot melt adhesives.” Int. J. Adhes. Adhes., 99, 102559.

Sarbu, I., and Sebarchievici, C., 2018. “A comprehensive review of thermal energy storage.” Sustainability, 10, 191.

Sharma, A., Tyagi, V.V., Chen, C.R., and Buddhi, D., 2009. “Review on thermal energy storage with phase change materials and applications.” Renew. Sustain. Energy Rev., 13, 318–345.

Tan, Z., Zou, J., Zhang, L., and Huang, Q., 2018. “Morphology, pore size distribution, and nutrient characteristics in biochars under different pyrolysis temperatures and atmospheres.” J. Mater. Cycles Waste Manag., 20, 1036–1049.

Van Ruijven, B.J., De Cian, E., and Sue Wing, I., 2019. “Amplification of future energy demand growth due to climate change.” Nat. Commun., 10, 1–12.

Wan, Y., Chen, Y., Cui, Z., Ding, H., Gao, S., Han, Z., and Gao, J., 2019. “A promising form-stable phase change material prepared using cost effective pinecone biochar as the matrix of palmitic acid for thermal energy storage.” Sci. Rep., 9, 1–10.

Wei, D., Wu, C., Jiang, G., Sheng, X., and Xie, Y., 2021. “Lignin-assisted construction of well-defined 3D graphene aerogel/PEG form-stable phase change composites towards efficient solar thermal energy storage.” Sol. Energy Mater. Sol. Cells, 224, 111013.

Wu, H., Li, S., Shao, Y., Jin, X., Qi, X., Yang, J., Zhou, Z., and Wang, Y., 2020. “Melamine foam/reduced graphene oxide supported form-stable phase change materials with simultaneous shape memory property and light-to-thermal energy storage capability.” Chem. Eng. J., 379, 122373.

Wu, W., Dai, S., Liu, Z., Dou, Y., Hua, J., Li, M., Wang, Xinyu, and Wang, Xiaoyu, 2018. “Experimental study on the performance of a novel solar water heating system with and without PCM.” Sol. Energy, 171, 604–612.

Xu, B., and Li, Z., 2013. “Paraffin/diatomite composite phase change material incorporated cement-based composite for thermal energy storage.” Appl. Energy, 105, 229–237.

Yang, H., Wang, S., Wang, X., Chao, W., Wang, N., Ding, X., Liu, F., Yu, Q., Yang, T., Yang, Z., and others, 2020. “Wood-based composite phase change materials with self-cleaning superhydrophobic surface for thermal energy storage.” Appl. Energy, 261, 114481.

Yasser, T.M., 2022. Fatty Acid Extraction from Pyrolyzed Spent Coffee Ground Bio-oil (Master Thesis). Tokyo Institute of Technology, Tokyo, Japan.

Yoo, J., Chang, S.J., Wi, S., and Kim, S., 2019. “Spent coffee grounds as supporting materials to produce bio-composite PCM with natural waxes.” Chemosphere, 235, 626–635.



DOI: https://doi.org/10.22146/ajche.80081

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ASEAN Journal of Chemical Engineering  (print ISSN 1655-4418; online ISSN 2655-5409) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada.