Process Optimization of Carbon Dioxide Adsorption using Nitrogen-Functionalized Graphene Oxide via Response Surface Methodology Approach

  • Fritzie Hannah B. Baldovino Chemical Engineering Department, Gokongwei College of Engineering, De La Salle University, 2401 Taft Avenue, 0922 Manila, Philippines
  • Nathaniel P Dugos Chemical Engineering Department, Gokongwei College of Engineering, De La Salle University, 2401 Taft Avenue, 0922 Manila, Philippines
  • Susan A Roces Chemical Engineering Department, Gokongwei College of Engineering, De La Salle University, 2401 Taft Avenue, 0922 Manila, Philippines
  • Armando T. Quitain Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan
  • Tetsuya Kida Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan
Keywords: carbon dioxide adsorption, graphene oxide, functionalization, ammonia, response surface methodology, nitrogen-functionalized graphene oxide

Abstract

This paper presents a response surface methodology approach in the optimization of the carbon dioxide temperature-programmed adsorption process using a new material referred as nitrogen-functionalized graphene oxide. This material was synthesized by loading nitrogen groups to graphene oxide using aqueous ammonia in supercritical condition. Later on, it was utilized as a sorbent for carbon dioxide adsorption. This process was optimized by implementing a response surface methodology coupled with a Box- Behnken design for the effects of three factors: adsorption temperature, carbon dioxide flow rate, and the amount of adsorbent. In analyzing the response surface, a model equation was generated based on the experimental data by regression analysis. This model equation was then utilized to predict optimum values of response. Furthermore, response optimizer was also conducted in identifying factor combination settings that jointly optimize the best response.

References

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Published
2017-12-31
How to Cite
Baldovino, F. H. B., Dugos, N. P., Roces, S. A., Quitain, A. T., & Kida, T. (2017). Process Optimization of Carbon Dioxide Adsorption using Nitrogen-Functionalized Graphene Oxide via Response Surface Methodology Approach. ASEAN Journal of Chemical Engineering, 17(2), 106-113. Retrieved from https://jurnal.ugm.ac.id/v3/AJChE/article/view/8985
Issue
Vol 17 No 2 (2017)
Section
Articles

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