Adsorption of Methylene Blue from Aqueous Solutions on Carbon Coated Monolith

  • Darmadi Darmadi Department of Chemical and Environmental Engineering, Universiti of Putra Malaysia and Department of Chemical Engineering, faculty of Engineering, Syiah Kuala University, Banda Aceh
  • Thomas SY Choong Department of Chemical and Environmental Engineering, Universiti of Putra Malaysia
  • Chuah T.G Department of Chemical and Environmental Engineering, Universiti of Putra Malaysia
  • Robiah Yunus Department of Chemical and Environmental Engineering, Universiti of Putra Malaysia
  • Y.H Taufiq Yap Department of Chemistry, Faculty of Science, Universiti Putra Malaysia
Keywords: adsorption, carbon coated monilith, methylene blue

Abstract

Carbon coated monolith was used as adsorbent to remove methylene blue from aqueous solution. Adsorption rate and equilibrium parameters of methylene blue were investigated in a batch system. Equilibrium adsorption data were predicted by two isotherms, i.e. the Langmuir and the Freundlich isotherms. The best fit to the data was obtained with the Langmuir isotherm with maximum monolayer adsorption capacity of 191.307 mg/g. Kinetics of adsorption with respect to the initial concentration of dye was described by using both the pseudo-first-order and pseudo-second-order models. It was found that kinetic data fitted well with the pseudo-first-order model.

References

1. Aguedach, A., Brosillon, S., Morvan, J., and Lhadi, E. K. (2008). “Influence of ionic strength in the adsorption and during photocatalysis of reactive black 5 azo dye on TiO2 coated on non woven paper with SiO2 as a binder,” J. Hazard. Mater., 150, 250–256.
2. Al-Degs, Y., Khraisheh, M. A. M., and Tutunji, F. (2001). “Sorption of lead ions on diatomite and manganese oxides modified diatomite,” Wat. Res., 35, 3724-3728.
3. Al Duri, B., and McKay, G. (1988). “Basic dye adsorption on carbon using a solid-phase diffusion model,” Chem. Eng. J., 38, 23-31.
4. Aksu, Z., and Tezer, S. (2005). “Biosorption of reactive dye on the green alga,” Chlorella Vulgaris Process Biochem., 40, 1347-1361.
5. Basar, C. A. (2006). “Applicability of the various adsorption models of three dyes adsorption onto activated carbon
6. Darmadi, Thomas S.Y. Choong, T.G Chuah, Robiah Yunus, Y.H. Taufiq Yap 37 prepared from waste apricot,” J. Hazard. Mater., B135, 232–241.
7. Batzias, F. A., and Sidiras, D. K. (2007). “Simulation of dye adsorption by beech sawdust as affected by pH,” J. Hazard. Mater., 141, 668-679.
8. Boki, K., Tanada, S., Matsui, T., Kuwahara, T., Kotani, A., Arai, K. et al. (1981). “Intraparticle diffusivity of methylene blue into porous activated carbon,” Bull. Environm. Contam. Toxicol., 27, 610-655.
9. Chiou, M. S., and Li, H.Y. (2003). “Adsorption behavior of reactive dye in aqueous solution on chemical cross-linked chitosan beads,” Chemosphere, 50, 1095-1105.
10. Crini, G., and Badot, P. M. (2008). “Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature,” Prog. Polym. Sci., 33, 399-447.
11. Doğan, M., and Alkan, M. (2003). “Adsorption kinetics of methyl violet onto perlite,” Chemosphere, 50, 517-528.
12. Faust, S. D., and Aly, O. M. (1998). Chemistry of water treatment, 2nd ed., Lewis Publisher Incorporated, Boca Raton, Florida, U.S.A.
13. Hameed, B. H., and El-Khaiary, M. I. (2008). “Batch removal of malachite green from aqueous solutions by adsorption on oil palm trunk fibre: Equilibrium isotherms and kinetic studies,” J. Hazard. Mater., 15, 237-244.
14. Ho, Y. S., Ng, J. C. Y., and McKay, G. (2000). “Kinetics of pollutant sorption by biosorbents: Review,” Separation and Purification Methods, 29, 189-232.
15. Inbaraj, B. S., Chiu, C. P., Ho, G. H., Yang. J., and Chen, B. H. (2008). “Effects of temperature and pH on adsorption of basic brown 1 by the bacterial biopolymer poly(γ-glutamic acid),” Bioresource Technol., 99, 1026-1035.
16. Irandoust, S., and Andersson, B. (1998). “Liquid film in Taylor flow through a capillary,” Ind. Eng. Chem. Res., 28, 1684–1688.
17. Kapteijn, F., Heiszwolf, J. J., Nijhuis, T.A., and Moulijn, J. A. (1999). “Monoliths in multiphase catalytic processes-aspects and prospects,” Cattech., 3, 24-41.
18. Liu, H. L., and Chiou, Y. R. (2005). “Optimal decolorization efficiency of Reactive Red 239 by UV/TiO2 photocatalytic process coupled with response surface methodology,” Chem. Eng. J., 112, 173–179.
19. Lozano-Castello, D., Cazorla-Amoros, D., and Linares-Solano, A. (2004). “Usefulness of CO2 adsorption at 273 K for the characterization of porous carbons,” Carbon, 42, 1233-1242.
20. Mittal, A., Gupta, V. K., Malviya, A., and Mittal, J. (2008). “Process development for the batch and bulk removal and recovery of a hazardous, water soluble azo dye (Metanil Yellow) by adsorption over waste materials (Bottom Ash and De-Oiled soya),” J. Hazard. Mater., 151, 821-832.
21. Noll, K.E., Gounaris, V., and Hou, W.S. (1992). Adsorption Technology for Air and Water Pollution control, Lewis Publisher Incorporated, Chelsea, Michigan, U.S.A.
22. Ofomaja, A. E. (2008). “Kinetic study and sorption mechanism of methylene blue and methyl violet onto mansonia (Mansonia altissima) wood sawdust,” Chem. Eng. J., 143, 85-95.
23. Onal, Y. (2006). “Kinetics of adsorption of dyes from aqueous solution using activated carbon prepared from waste apricot,” J. Hazard. Mater., B137, 1719–1728.
24. Tanada, S., Boki, K., Kita, T., Matsui, S., Nakamura, T., Takahashi, H., Zushi, W., et al. (1983). “Intraparticle diffusivity of methylene blue into pores of activated carbon and pyrolysis ash derived from organic surplus sludge,” Bull. Environm. Contam. Toxicol., 30, 141-146.
25. Uzun, I. (2006). “Kinetics of the adsorption of reactive dyes by chitosan,” Dyes Pigm. 70, 76-83.
26. Wang, S., Zhu, Z. H., Coomes, A., Haghseresht, F., and Lu, G. Q. (2005). “The physical and 38 Adsorption of Methylene Blue from Aqueous Solutions on Carbon Coated Monolith surface chemical characteristics of activated carbons and the adsorption of methylene blue from waste water,” J. Colloid Interface Sci., 284, 440–446.
27. Weber, W. J. Jr. (1972). Physicochemical Processes for Water Quality Control, John Wiley & Sons., New York, U.S.A. Yener, J., Kopac, T., Dogu, G., and Dogu, T. (2008). “Dynamic analysis of sorption of methylene blue dye on granular and powdered activated carbon,” Chem. Eng. J.,144, 400-406.
Published
2008-12-31
How to Cite
Darmadi, D., Choong, T. S., T.G, C., Yunus, R., & Yap, Y. T. (2008). Adsorption of Methylene Blue from Aqueous Solutions on Carbon Coated Monolith. ASEAN Journal of Chemical Engineering, 8(1), 26-37. Retrieved from https://jurnal.ugm.ac.id/v3/AJChE/article/view/7696
Issue
Vol 8 No 1 (2008)
Section
Articles

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